Preface Food processing has been identified as a sunrise sector and going to come up in a big way in time to come. Indian Government has also encouraged establishment of home, cottage and small scale industries especially in rural areas. Food industry on one hand provides diversified processed foods to satisfy the human palate and on the other hand generates huge quantities of the waste rich in organic matter. In the last few decades, there has been a growing health consciousness and concern about environmental pollution which has led to the formation of various laws and regulations all over the world. Discharge of pollutants in excess of established standards into the environment is a punishable offense as per law in many countries. The present goal is to achieve zero discharge of pollutants into water. But achieving it is a formidable, if not impossible task for industries, municipalities and governments. The end-of-the-pipe waste treatment is highly costly and non-productive. Furthermore, we still spend money to clean up our rivers, lakes and groundwater. Naturally, these costs are passed on to the citizens in the form of higher taxes and prices for goods and services. The law says that if an industrial plant continues to discharge pollutants in excess of established standards, it will be fined heavily and possibly put out of business. Since the food industry is comprised of many small-to-medium sized plants, the economics of scale predicts that it is going to cost the smaller plant more to dispose or treat a unit of processing waste than a larger plant. These challenges are being met with development of technologies which moderate the costs of waste treatment and make productive use of wastes. Technologies for reducing the costs of waste treatment and making productive use of wastes are being developed for the last many decades. The traditional approach to use waste water is its land application mostly in irrigation of crops. But, this may also invite long term implications if waste waters contain undesirable compounds. For increasing production efficiency, various food processing modifications have been made and are being devised to increase production efficiency, reduce water consumption, keep solid wastes out of the waste water stream and in many cases conserve energy. Technological developments such as dry caustic peeling reduce water consumption, increase product yields and keep peel waste out of wastewater with the potential for by-product utilization. Dry or steam blanching not only reduces water consumption, but leaches fewer nutrients from the products and conserves energy. More examples are found in various chapters in this book. By-product recovery from solid wastes is another approach for reducing pollution abatement costs. Most end-of-the-pipe waste treatments also offer food processors the potential for by-product recovery. The wastes from the fruit and vegetable processing industries can successfully be converted into pectin, starch, animal feed, bio-colours, alcohol, etc. The shrimp industry generates shell waste, which is a good source of protein and high in calcium and phosphorous and can be used in livestock feed formulations. Shellfish waste is a rich source of chitin yielding up to 35% of the compound on dry weight basis. Chitosan obtained by the deacetylation of chitin has many pharmacological applications (anticoagulant, artificial kidney membrane, sutures, immuno-stimulants and anti-tumour agent). Peptides in the fish hydrolysates have functional role particularly in the aquaculture industry. Gelatin prepared from collagen is useful during encapsulation of thermolabile pharmaceuticals and in coating of photographic paper. Several industrially important enzymes can also be recovered from fish wastes. Similarly, the meat industry also generates a huge quantity of wastes such as offals and digests from the slaughtered animals which could be profitably utilized for production of value added products like Meat-cum-Bone Meal (MBM), Tallow, Bone chips, Pet Foods and methane. The wastes generated from the dairy processing industry can be converted into protein isolates, and other fermentable media. The recent innovations in technologies such as treatment of waste water without using any energy source or electricity and chemicals may open avenues for the generation of biogas (methane), besides cleaning the waste water. The book describes many of such options being employed or developed with respect to different food industries. But none of these, individually, is a complete solution to the environmental pollution problem. Perhaps an integrated approach is needed.

1.1 Introduction Due to the ever increasing world population, the demand for food would also increase. India is one of the largest food producer countries of the world (first in milk production, second largest in fruit and vegetable production and third largest in grains production). It is the seventh-largest country in the world, with a total land area of 3,287,263 square kilometres. India has varied climates of snow covered Himalayas, desserts, oceans, fertile plains and areas receiving the highest rainfall in the world. Name any food item; it can be grown in one or the other part of the country. All these make the production of various types of foods of plant (fruits, vegetables, cereals, pulses, oilseeds, spices etc) as well as animal origin (fish, meat, milk etc.) possible in the country. The annual production of cereals, fruits and vegetables is 260, 57 and 77 million tonnes respectively, besides this, the production of cow and buffalo milk is about 102.1 million tonnes and that of sugarcane and spices are 355.52 and 1.1 million tonnes respectively [15]. Table 1 shows that the production of various food items has increased many folds during the last five decades. On one hand, we feel proud as we produce one of the largest quantities of foods in the world and there has been an enormous rise in the production of various foods in India during the last five decades, on the other hand we should be very much worried being a leading country as far as the wastage of food in the world is concerned. The postharvest losses are huge and only meagre quantity (2%) of the food is processed. Sharma [41] very rightly said that when we do not agree to throw away Rs 4000/-per month out of a salary of Rs 10,000/-per month then why do we accept 40% postproduction losses of food in the country. This would require immediate necessary action to save a major portion of the food that has already been produced.

2.1 Introduction Each step in the food industry system e.g. food production, processing, transportation, storage, distribution and marketing, has some impact on the environment and there is much concern about environmental pollution. Due to the highly diversified nature of the food industry, various food processing, handling and packaging operations create wastes of different quality and quantity, which, if not treated, could lead to increasing disposal problems and severe pollution problems [24]. The preservation of the natural environment from industrial pollution is currently receiving much attention. In food industry, the most important problem is treatment and disposal of large quantities of waste water, a by-product of various processing operations. It is one of the largest industry groups comprising the manufacturing sector of the U.S. economy [47]. Likewise, India is the world’s second largest producer of food next to China, and has the potential of being the largest food processor. The total food production in India is likely to double in the next ten years [22]. Flour and grain; soft drinks and carbonated water; breweries; starch and miscellaneous food products; meat, poultry and fish; tea, coffee and other beverages; fruit juices; animal feed; sugar; distilleries and blending of spirits; cocoa, chocolates and sugar confectioneries; agricultural and food chemicals and industrial packaging are important sub-sectors of the food processing industry. Food processing projects involve the processing and packaging of meat products, fish and shell fish, dairy products, fruit and vegetables, grains and beverages production. It includes refinement, preservation, improvement of product, storage, handling, packaging and canning (Fig. 1). The processing may involve receiving and storing raw or partially processed plant, animal or other food materials, processing the raw materials into finished products, packaging and storing the finished products.

3.1 Introduction The production of food grains in India is around 200 million tonnes and most of the grains are converted to primary products after primary processing such as threshing, dehulling, de-branning. Some of the grains are converted to secondary products such as flour or grits. The yields of primary and secondary products range between 65-80% indicating a wastage of 20-35%. These wastes lead to unclean surroundings and air pollution due to fine dust. Hence, proper waste management/utilization of food grain processing industries has become a societal need for a clean environment. The term ‘waste’ has different meanings to different people. It can be retractions from the main process or less utilizable by-products or undesirable waste material depending on the commodity. All food-processing industries generate wastes and create problems for its management. The best way the food processing industry can treat its waste is to avoid producing it. Much of the waste now being produced or generated in some food processing plants can become a managed resource for producing economic credits. In fact, waste utilization is one of the world’s prominent industries and its activities cut across the normal divisions into which industries are placed. Similarly, there will be wastes from agriculture, animal and meat industries, textile, rubber etc. Even the local governmental activities that collect and dispose the household wastes become apparent in terms of the huge size of it.

4.1 Introduction A huge amount of waste in the form of liquid and solid is produced in the fruit and vegetable processing industry which causes pollution problem if not utilized or disposed off properly. Generally solid waste is dumped in local landfills, eaten and scattered by stray animals, which has now become a major cause of environmental pollution. The waste obtained from fruit processing industry is extremely diverse due to the use of wide variety of fruits and vegetables, the broad range of processes and the multiplicity of the product [79]. The solid waste from fruits and vegetables includes peel, stone, rag, seed, core etc is of economic value and can be used for manufacturing of various by-products [21]. The extent of the waste produced from processing industries of some of the important fruits and vegetables, is given in Table 1. In India, utilization of fruits and vegetables for processing is hardly 1.8% of the total production. There were 5166 processing units till 1st Jan, 2009 of fruits and vegetables products throughout the country. About 90% of these units are small scale units with annual production limit of 50-250 tonnes. These units have no organized methods of waste disposal. In certain places this waste is taken away by farmers for their disposal as cattle feed or field manure.

5.1 Introduction Waste from the dairy processing industry is generated through production of milk products at different stages. With diversification of dairy products, by-products have also gained some importance. Utilization of dairy by- products improves economical and nutritional aspects of milk production and reduces environmental pollution originating from dairy waste. Important dairy by-products include butter milk, ghee residues and whey, the major waste arising from production of cheese, casein, paneer and chhana. Whey arises as a result of protein coagulation/precipitation in the preparation of these products. It is used for manufacture of whey powder, whey drinks and lactose (milk sugar). Whey protein concentrates can be prepared by modern technological methods like ultra-filtration and reverse osmosis. Desi buttermilk is an important domestic beverage since olden days. Ghee residue can be utilized for manufacture of chocolate burfi, samosa filling etc. Hence, utilization of dairy waste particularly whey, butter milk and ghee residues obtained during manufacturing of various main products, has not only increased the availability of nutritional milk foods but has also indicated the profitable method of by products utilization and helped in minimizing the problems of pollution. This chapter focuses on utilization of these dairy industry wastes.

6.1 Introduction The food industry produces large volumes of waste both solid and liquid, starting from the initial step of raw material to the final consumption of processed food. Apart from a loss of valuable biomass and nutrients, the generated waste poses increased disposal and potentially severe pollution problems. Meat and meat industry is no exception where slaughter houses, meat processors, wholesalers and rendering plant generates huge amount of waste [1, 2]. Meat and meat processing industry, is among the least profitable industries despite its immense size and large gross sales. Effective recovery and utilization of by-products and wastes is the lifeline of meat and poultry processing industry. Thus, it becomes imperative that an effort be made to reduce expenses by employing the use of new or modified processing methods and through in-plant treatment, where waste effluents and by-products could be recovered and often upgraded to useful products of higher value. Meat processing wastes have a potential for recycling raw materials or for conversion into useful products of higher value as by-product or even as raw material for other industries or for use as food or feed after biological treatment.

7.1 Introduction Fisheries are emerging as one of the fastest growing food production system all-over the world. The potential for fisheries development world over and especially in India is highly promising in view of physical and biological resources available coupled with technological development. The demand for fish fishery products is ever increasing as the awareness of health benefits are being made available to public at large. The world fish production has not kept pace with demand which means less and less fish is available. Nevertheless, a large fraction of this valuable commodity is wasted due to deterioration after landing or consumer preference. An estimate by FAO [1] indicates nearly 20-25% of the total catches are wasted as postharvest loss. Better utilization of aquatic resources should therefore, aim primarily at reducing this enormous loss by improving preservation of fish and fishery products and upgrading the discarded low value fish to high value fishery products. The processing of fish into different types of products generates considerable waste. Commercially, fish is being processed into fillets, steaks, mince, canned products and a variety of ready-to-eat products. Fish processing plants contributes substantial wastes in the form of skins, bones, offal, exoskeletons from shrimps and nutrients in wash water from surimi plants. Fish processing waste utilization is an important issue for the seafood industry both from a regulatory standpoint as well as one that has potential economic impacts. It is estimated that only 25-50% of the raw material is utilized for primary products (fillets, canned and stabilized mince production). The remaining 50-75% of the raw material is considered processing waste and is utilized for low-value products or disposed-off at sea. A large volume of solid waste is currently processed into fish meal, fish protein hydrolysates, and fertilizers. A small percentage is processed into higher valued items, such as, seafood flavourants, colourants, chitosan, enzymes, etc.

8.1 Introduction Spices are appetizers and hence, esse ntially used in the culinary preparations. They also possess antioxidant, antimicrobial and antibiotic properties. Further, they possess medicinal properties and hence, play an important role in human health. According to International Organization for Standards (ISO), there is no clear cut division between ‘Spices’ & ‘Condiments’ and as such they have been clubbed together. The term ‘Spices’ & ‘condiments’ applies to “such natural plants or vegetable products or mixtures there of, in whole or ground form, which are used for imparting flavour, aroma and piquancy and seasoning of foods”. Spices are divided into different groups based on their plant components such as floral, fruits, berries, seeds, rhizomes, roots, leaves, kernel, aril, bark, bulbs etc. About 70 spices are grown in different parts of the world and a major portion of these are grown in India. Hence, India is called “The home of Spices”. It is well known that spices played a significant role in ancient times, in the development of civilization – the life of the people and trade among the nations of East and West. Spices like ginger, pepper and turmeric have an intense and immediate impact on sensory perceptions and exhibit strong physiological effects as food and medicinal constituents. Some spices and herbs like cardamom, saffron and vanilla, which have less intense but more delicate sensory effects, are well known for their contribution to fragrance and usage as food flavouring agents. The history of spices and their use in food and medicine in ancient India have been reviewed earlier [1-3].

9.1 Introduction Depleting natural resources, regulations on synthetic material, growing environmental awareness and economic considerations today happens to be major driving force for utilization of wastes from the agricultural crops and their residues throughout world [1]. These challenges have led to the introduction of sustainable waste management practices via optimization of processing technologies for minimization and creative conversion of the plant and the processing industries biowastes the world over [2,3,4,5]. Although world prices for sugar and petroleum products have shown spectacular variations during the last few decades, the long term outlook is very likely to be a continuous increase in the price of all fossil fuels and stagnation, at best, for the price of sugar [6]. This gloomy prospect led to the renewed interest in the wastes of the sugarcane industry during the last 50 years and has proved that the optimal use of wastes can provide not only a non-negligible support to the sugarcane industry but will also be able to redress the difficult situation sugar is presently experiencing [7]. Reliable statistics are not available to show the detailed end uses of these wastes on a world basis, but from a very rough picture of their trade, we can say that the wastes from the sugar and jaggery industry serve to be amongst the richest bioresource in this era of recycling of biowastes for renewable wealth generation [8].

10.1 Introduction Edible oil production is a separate sector of the food processing industry. There are several species of plants in the world whose oil can be utilized for human consumption for edible and non-edible uses. Though around 40 oilseeds are known, only around a dozen oilseed crops have become commercially important including ten seed crops and three tree crops. These oil seed crops (mostly annual) of commercial importance are groundnut, rapeseed-mustard, sesame, soybean, sunflower, cottonseed, safflower, niger, castor and linseed. The three major tree oil crops are palm, olive and coconut [63]. Besides these, the kernels of some other tree crops i.e. apricot, almond, walnut, hazelnut, olive (fruits are used), peach, can also be utilized for oil extraction purposes for edible and non-edible uses. Besides oil of the oilseed crops, the oils of tree fruits and kernels are also becoming popular very fast for various food, pharmaceutical and cosmetic industries. Large scale requirement and local shortages of oils for various edible and non-edible uses have prompted the identification of many new sources of oil during the last few decades. They are ricebran, corn, sal, mahua, jatropha, kokum, melia, rubber, mango kernel, kusum, simarouba, neem, karanj, crambe, moringa, tumba, jojoba and tobacco seed etc. Most of these oilseeds and their products have wide utility in the specialty oils sector and are mostly used for non-edible purposes. Soaps and detergents, paint and varnish, lubricants, pesticides and medicines, cosmetics, bio-diesel fuel industry are the major consumers of these non-traditional oilseeds. All the oil crops will gain greater attention in future as they are renewable and biodegradable in nature [63]. List of oil crops have been given in Table 1.

11.1 Introduction Fermented foods are the result of the activity of a few specialized types of micro-organisms among the thousands of species known to mankind. Success of such processes is depended upon the control of environmental conditions ensuring the growth of the desired microbial species and inhibition of others. The fermentation can be broadly defined as the process in which the carbohydrate or like compounds are broken down, under anaerobic or aerobic conditions [171]. The basic role of micro-organisms is to breakdown the organic compounds to get energy for their metabolic activities. From ancient times, people all over the world have developed traditional processes for production of alcoholic beverages (wine) either from natural sugar such as in wine or by degrading the starchy materials (beer). Fruit wines referred to as ‘Soma’ in our ancient scriptures have been part of food of man and were used as medicine, might have originated accidentally (transformation of fruit juice beverages having exhilarating or stimulating properties). Wines are made principally from fruits like grape or extract of other fruits of various types (table wine, sparkling wine, dessert, aperitif or vermouth and pop wines) while the beers are prepared from grains like barley, rice and corn. The principal carbohydrate in grain is starch which can not be fermented directly. This process is brought about by starch splitting enzymes by germinating the grains followed by drying and storage until needed. Distillation of beer produces a variety of liquors (whisky, rum, gin, vodka), while that of wine produces the brandy. Besides, the improvement in the raw material selection, fermentation conditions and techniques, a lot of waste material is generated during fermentation process in the industries. Nevertheless, the food based industries are significant contributors to the economy of the many countries of the world (Fig 1). The global market value of food fermentation based industries is estimated to be around 250 million US dollars. Interestingly, more than 10% of this accounts for alcoholic beverages (Fig 2) with projected increase of US$ 27 billions in 1989 to 40 billions in 1990 [93,123,123,129].

12.1 Introduction Man is the most beautiful of all God’s creations and like man, his environment too is beautiful with rivers to quench his thirst with sweet water, atmosphere to provide him oxygen, land and fire to provide him food. Primitive man ate uncooked food and lived in caves. Soon he learnt the use of firewood for cooking of raw meat and provided the first instance of ‘Pollution from food processing’ in history. As man shifted from one place to another, this sort of living never polluted the environment. But as the man ascended the ladder of civiliz ation, his needs grew in arithmeti c progression but corresponding pollution grew in geometric progression. With increase in agriculture produce, a need was felt to preserve the glut production in the form of processed foods giving rise to massive development of food processing industries all over the world. The rapid industrialization of agriculture and horticulture, increased the pollution load many folds especially the biodegradable waste from food industry [41].The wineries and distilleries (distill wine to make brandy) are no exception. Nevertheless, the waste is a precious source of several useful materials as such or after fermentation [1,31,46,86]. Thus, development and environment are two sides of the same coin. From time immemorial, the biosphere is acting as a sink for all the waste products and recycles them to make good the loss so that every generation finds it the same as one before it. But, of late, this self-cleaning and equilibrium maintenance of biosphere is disastrously disturbed as the waste produced from man’s activities is continuously exceeding the capacity to purify herself. Consequently, our biosphere is becoming more and more poisonous and days are not far away when this planet will become inhabitable.

13.1 Introduction Hospitality industry is the second largest industry in the world. It is well diversified and can be chosen as per the interest. Hospitality management involves planning, organizing, directing and controlling human and other resources within the different segments of hospitality industry i.e. lodging, restaurant, travel and tourism, institutional management, recreational management, meeting and convention planning industries. Although, these all are separate but related segments of the hospitality industry and are interrelated to provide good and efficient services to the guests and users. Hospitality industry provides services which are need oriented and differ in various parts of the world as per regions and the traditional styles. The first building created specifically for hotel was ‘City Hotel’ with 73 rooms at 115 Broadway, New York in 1794. Pallonjee Pestonjee established the very first western-style hotel in India, “The Bristol Hotel” in Mumbai in 1840. According to the report of the department of Tourism, Government of India, at the end of the year 2004, there were 167 Five star hotels with approx. 28,900 rooms, whereas 126 Four star hotels, with 8,831 rooms [2]. To expedite the ongoing process of classification/re-classification of functioning hotels in one to three star categories, five Regional Committees have also been set up in Delhi, Mumbai, Kolkata, Guwahati and Chennai to conduct inspection [3].

14.1 Introduction The increasing human population and changing life styles have resulted in a huge demand for processed and packaged foods. As a result of this demand, large amounts of water, air, electricity and fuel are consumed on a daily basis for food processing, transportation and preservation. Although not one of the most heavily polluting, the food industry does contribute to the increase in volume of waste produced [1]. There is an increasing pressure from regulatory bodies through incentives, legislation and financial penalties to minimize waste generation and encourage adoption of eco-friendly options for waste management. Nanotechnology is a panacea for food waste management.

Index A.parasiticus 202 Abattoir processes 131 Acetic acid 83, 87, 180, 182, 242, 325, 341, 391 Acetic anhydride 243 Acetobacter 83, 341 Acetone 87, 115, 201, 242, 245, 246, 267, 346 Acid 30, 42, 60, 63, 64, 71, 82, 83, 86, 87, 89, 90, 93, 94, 98, 100, 102, 103, 104, 109, 110, 112, 113, 118, 123, 133, 138, 140, 141, 152, 159, 160, 163, 169, 170, 172, 173, 174, 175, 177, 180, 181, 182, 183, 184, 185, 191, 193, 232, 239, 240, 242, 244, 245, 246, 247, 252, 255, 299, 301, 302, 305, 307, 311, 312, 313, 314, 316, 320, 322, 323, 324, 325, 326, 327, 328, 330, 331, 332, 334, 335, 336, 340, 341, 342, 344, 345, 347, 349, 350, 351, 352, 354, 361, 379, 391, 393, 410 Acid hydrolysis 172, 208, 239, 316