Preface Sustainable agricultural management approaches in the soil environment is the key to sustained food security, soil quality and livelihood security. The damage to soil fertility and depletion of plant nutrient elements in soil has emerged as major threats to the sustainability of diverse agricultural production systems. Therefore, soil and water testing is considered an important tool to assess the essential plant nutrient elements need to formulate crop and site specific nutrient recommendations vis-à-vis climate change strategies. Soil test based nutrient use optimizes economic returns and minimizes risks of environmental pollution. Characterization of soil mineralogical, microbiological or biochemical properties within an experimental area among different treatments or cropping systems it requires the utmost attention to planning details. It is imperative to establish experimental objectives as a prelude to developing the sampling plan. As a component of development of sampling plan, one must begin by evaluating the environment from which samples will come. To accomplish this goal one must determine the physical and chemical features of the experimental area that includes the basic agents of nutrient supply i.e. soil and water. A need, therefore, was felt to bring out a book on “Principles of Soil and Water Analysis” that can helpful to the Soil Chemists, Agriculture Officers, Specialists and research scholars of soil testing laboratories and other laboratory technicians/assistants. The present book is an attempt in that direction. It contains some principles and reactions of chemical analysis, soil sampling and analytical techniques for the determination of physical and chemical parameters of soil and water samples.

Manychemicalreactions innature,particularlyinlivingsystems,occur inaqueous solutions. Reactions are often carried out in the laboratory in aqueoussolution becausethese aregenerallymore rapid in solutionthanwhen puresolid reactions are mixed. Analysisof substancesmaybe qualitative or quantitative in nature. A quantitative analysisis one inwhich the amountor concentrationof a particular species in a sample is determined accurately and precisely. 1.1 Volumetric Analysis Volumetric analysis is a quantitative analysis. It involves the measurement of the volume of a known solution required to bring about the completion of the reaction witha measuredvolume of the unknown solution. The reaction used in volumetric analysis must fulfil the followingconditions;

Advances in analyticalchemistry and instrumentalanalytical chemistry in the pastfew decades have significantlyimproved, makingelemental determinations in soil extracts and water samples easier, faster and less challenging for the analyst. For most of the elemental analysis procedures, the more traditional wet chemistryprocedures havebeenreplaced byvarious analytical instrumental procedures that employ either emission or absorption spectrophotometry. The elemental concentration in prepared soil extracts and water samples can be determined by a number of instrumentalanalyticalprocedures. The trend today is toward greater analytical sophistication, to multielement computer controlled analytical instrumentation, resulting in a less ended understandingof the analytical principlesinvolved, and “black box” concepts of instrument calibration, maintenance, and operation. Preparation of the analyte and suitable adaptation for a method of analysis requires an understanding, by the analyst, of the principle of the method as well as its requirements and limitations. Adequate testing is usually required before putting the method to use, following procedures such as those that have been adapted by the Association of Official Analytical Chemists (AOAC). It is not possible to cover in adequatedetail every method of analysissuitedfor the elemental concentration determination in soil extracts and water samples. Therefore, the objective here is to provide sufficient background information about the instrumentalprinciples to guide the reader.

3.1 Concepts of Soil Sampling Samplinginvolvesthe selection fromthe total populationof a subset ofindividuals upon which measurements will be made. The measurements made on this subset (or sample) will then be used to estimate the properties (or parameters) of the total population.Samplingisinherent toanyfield research programinsoilscience because the measurement of the total population is impossible for any realistic study. Samplingdesign involves theselection of the mostefficient method forchoosing the samples thatwill be used to estimatethe properties of the population. The definition of the population to be sampled is central to the initial formulation of the research study. The sampling design defines how specificelementswill be selected from the population, and these sampled elements form the sample population. Pedogenetic and soilgeomorphic studies focus on determining the processes thatformed the soilproperties or landscapes under study and the environments that controlled the rates of these processes. Pedonscale studies are closely associated with thedevelopmentof soil taxonomic systems andfocus onvertical, intrapedon processes. Soil geomorphic studies are the interface between quaternary geologyand soil science and soil geomorphologistsfocus on lateral transferprocesses and the historical landscape evolution. Hence sampling is difficult for a particular population and is differentfor differentstudy.

The influence of water quality on the soil and plant growth is related to the chemical and physicalproperties of the soil, the salt tolerance of the crop, the climaticregime of the area and the method,frequencyand the amount of irrigation water applied. Irrigation water quality refers to its suitability and sustainability for use in agricultural crops. The problems thatresultfrom the use of a particular irrigation water, vary both in kind and degree, and are modified by soil, climate and crop as well as by the skill and knowledge of the water user. As a result there is no set limiton water quality, rather itssuitability for use is determined by the conditions of use which affects the accumulation of water constituents andwhichmayrestrictcrop yield.The soilproblems mostcommonlyencountered and used as a basisto evaluate water quality are those related to salinity, water infiltrationrate,toxicityanda group of other miscellaneous problems. Numerous guidelines are available for evaluation of water quality. Time to time some of theseguidelines has been updated with modification of some criteria like SAR to Adj. SAR and the Adj. RNa and development of new concepts like water qualityIndex (WQI) whichhave increasedour predictability. Thenewguidelines are relied heavily on old ones.The modified guideline by Ayers and Westcot (1985) was foundto be themost reliabletopredict thewaterqualityforirrigation. Irrigated agriculture is playing a major role in enhancing food and livelihood security of a country. Supply of fresh water which is an importantinput for the sustainable and economic development of agriculture are not enough to meet the requirement of all sectors of economy. Reduced water availability to agriculture from the present share of 85% of country’s water resources to about 70-75% by 2020AD wouldaffect the capacity of the country to meet the food production target, unless supplies are augmented from unconventional sources. For future agriculture there are no alternatives but to rely on non conventional sources for partial alleviation of the forecasted water scarcity. Amongthese sources extraction of marginal quality groundwater and the waste water generatedfromurban and industrial activities have thepotential to augment the water supplies. Many associatedsoil, plant and environmental problems come up when these sources of water are directly used for irrigation. For addressing theseproblems and to get more benefit from thesesourcesof water, the first step is to understand how an irrigation water source affects the soil plantsystem.Thereforeknowledge of irrigationwaterqualityiscriticaltodevelop appropriate site and crop specific comprehensive short term and long term management programs.

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