eChapters

The chemical composition and digestibility of feedstuffs influence their nutritive value for animal production. Therefore, assessment of nutritive value of feedstuffs continues to be one of the top priority areas in animal production research. Although traditionally the feedstuffs were evaluated by performance studies and digestion trials, such techniques are expensive and requires more time and labour. Continued search for alternatives to animal feeding experiments have led to the development of feed evaluation systems that are rapid and economical.

In general, there are two kinds of laboratory analyses — Chemical analyses and Biological tests with rumen micro-organisms or purified enzymes. Biological tests give direct estimates of digestibility, but are lengthier and more expensive. Chemical analyses are cheaper and rapid, but do not give direct estimates of nutritive value. The statistical association between the chemical components and quality need to be established to predict the nutritive value.

Preparation and processing of samples for chemical analysis: The preparation of samples depends upon the purpose of analysis and the nature of the constituents that are to be determined. The preparation of samples for analysis is as important as the analytical procedure and hence, it should be done with utmost care. (A) Smpling of wet material: (1) Plant material; (2) Silage; (3) Cattle faeces; (4) Sheep / goat faeces; (5) Poultry excreta; (B) Sampling of air – dry material: (I) Hay or straw; (II) Concentrates.
Small quantities of feed samples are collected from several locations, all sides, in the middle and are mixed well after chaffing. Such mixture is subjected to quarter sampling, by spreading on levelled ground in circular form. This circle is now divided into 4 equal quarters. Any 2 diagonally opposite quarters are selected and other 2 are rejected. Selected portions are mixed properly and again spread on levelled ground in circular form. This mixture is again divided into 4 equal quarters and any 2 diagonally opposite quarters are selected, while remaining 2 are rejected. This procedure is repeated till required quantity of sample is obtained. This representative sample is brought to laboratory as early for drying in a hot air oven. Dried samples are ground to pass through 2 mm sieve in a Willey mill (large samples may be ground through hammer mill), as described in chapter 10. Sample is collected in an airtight plastic bag and stored in desiccator.

Abstract

The use of plants for treating diseases is as old as the human species. Popular observations on theuseandefficacyof medicinal plants significantly contribute to the disclosure of their therapeutic properties, so that they are frequently prescribed, even if their chemical constituents are not always completely known. Medicinal plants have therapeutic potential due to the presence of natural antioxidants functioning as reducing agents, free radical scavengers and quenchers of singlet oxygen. Majority of their antioxidant activity is due to bioactive compounds viz. flavones, isoflavones, flavonoids, anthocyanins, coumarins, lignans, catechins and isocatechins. They have been recognized to possess several medicinal properties (diuretic, expectorant, laxative, anti- bacterial, anti-pyretic etc.) and have been effectively used in the indigenous systems of medicine in India and other countries. Apart from the traditional use, a number of beneficial physiological effects have been identified by extensive studies. Among these are their beneficial effects on lipid metabolism, efficiency as antidiabetics, ability to stimulate digestion and to inhibit platelet aggregation, antioxidant, antilithogenic and anti-inflammatory potential.In this chapter an attempt has made to elucidate and understand the chemical and medicinal properties of Stavar and Safed musli those are using as medicine. These may also use as ingredients for preparation of herbal food products.

Chemistry of vegetable crops

Vegetables play an important role in human nutrition supplying some of the materials, which other food materials are lacking. Vegetables are important in neutralizing the acidity formed during digestion. They also serve as roughages in human nutrition and thus helping digestion.

They are the important sources of minerals like Ca, P and Fe. They also form an important source of vitamins, especially vitamin A. Green and yellow vegetables like carrot, turnip, spinach, beans, etc. contain appreciable amounts of vitamin A. Direct seed of beans, peas, and legumes contain appreciable amounts of proteins. Vegetables also contain sufficient amounts of vitamin C and also appreciable quantities of thiamine, niacin and folic acid. Tomatoes and potatoes contain fairly high amounts of vitamin C.

Life is fundamentally a complex interplay of chemical interactions and reactions. Chemistry examines the composition and properties of matter, the interactions between chemical components, and the mechanisms by which complex structures are formed. Biological chemistry, or Biochemistry, delves into these principles within the context of living systems, highlighting the intricate relationships between molecular structure and function. Understanding fundamental chemistry and its application to anatomy and physiology is crucial because the human body is composed entirely of chemical substances. Basic chemistry encompasses the study of matter, its various states, and energy in all its forms. In order to understand the basic chemistry of living let us start from the scratch of learning and remembering everything that we have learnt so far. Matter and Its Properties Anything with mass and occupying space is referred to as matter. Solid, liquid, and gas are its three main states. Mass, distinct from weight, represents the quantity of matter in an object and remains constant regardless of location. In contrast, weight depends on gravitational force. 

Introduction

Chemical communication between plants and insects is an essential part of mutual relationships, in which both partners benefit from the communication. The role of volatiles in pollination systems provides an excellent model for understanding the ecology and evolution of chemical communication between plants and insects. Infochemical:- A chemical that conveys information in an interaction between two individuals evoking in the receiver a behaviour or physiological response. Chemicals involved in interspecific communications were given the name of Allelochemicals by R. H. Whittaker in 1970. Allelochemicals affect the survival, growth & development of herbivorous insects as well as their natural enemies.

This chapter introduces the chemical composition and nutritional significance of eggs. It examines egg proteins, yolk lipids, triglycerides, phospholipids, cholesterol, vitamins, minerals, trace elements, carbohydrates and pigments. The chapter explains the functional and high-biological-value nature of egg protein and examines bioactive components, digestibility and protein-quality indices. It also considers the relationship between eggs and human health, including the cholesterol debate, amino-acid profile and comparative protein quality. The chapter establishes the nutritional foundation for understanding eggs as an important food resource.

4.1 Introduction

The egg is made up of three primary components: the egg white, the egg yolk, and the egg shell. The calcite crystals of the shell are enmeshed in a protein and carbohydrate complex matrix. About 58% of the weight of an egg is made up of the viscous, colourless liquid termed egg white inside the shell. About 75% of the weight of an egg’s edible component is made up of water, although proteins and lipids make up the majority of its nutritional worth (Table 4.1). There are also trace quantities of minerals, often known as ash, and carbohydrates, which take the form of simple sugars including glucose, sucrose, fructose, lactose, maltose, and galactose.

I. FILL UPS

1. The major storage organ for cereals is _____ .
2. The major storage organ for legumes is _____.
3. The major storage organ in pine is _____.
4. The average protein percent present in soybean is _____.
5. The average oil percent present in oilpalm is _____.

The chemical composition of seeds is basically determined by genetic factors and varies among different species and seed parts (Table 1). However, it is influenced by environmental and cultural practices.

Cell walls mainly consist of cellulose, hemicellulose, and lignin in a 4:3:3 ratio. This ratio differs from sources such as hardwood, softwood, and herbs. Besides these three components, natural lignocellulosic materials contain a small amount of pectin, nitrogenous compounds, and the secret ash.

1. Cellulose

2. Hemicellulose

3. Lignin

Cellulose

Cellulose is a glucan polymer consisting of linear chains of 1,4-ß -bonded anhydroglucose units. Cellulose is the structural component of the primary cell wall of the green plants.About 33% of all plant matter is cellulose (the cellulose content of cotton fiber is 90%, that of wood is 40-50% and that of dried hemp is approximately 45%. Cellulose is a straight chain polymer.The number of sugar units in one molecular chain is referred to as the degree of polymerization (DP).Cellulose is insoluble in most solvents including strong alkali. It is difficult to isolate from wood in pure form because it is intimately associated with the lignin and hemicelluloses.

The volatile oil in the flower determines the odour and flavour of kewda and it has been of particular fascination to the chemists. There are only a few reports on the chemical composition of kewda essential oil (rooh or otto) Dhingra et al. (1954) distilled the kewda flowers collected from five places of Ganjam (Odisha) and Ghazipur (Uttar Pradesh) districts. He found the oil yield to vary from 0.015 to 0.031% and the compounds identified were methyl ether of β- phenyl ethyl alcohol (65.97%), d-linalool (18.70%), dipentene (8.31%), phenyl ethyl acetate (3.48%) and citral (1.82%). The oil was of light to golden yellow in colour having the following physico-chemical properties viz., specific gravity (d20o) 0.932-0.958; refractive index (n20o) 1.485-1.491; optical rotation ([α]D) + 1.350 to + 2.080; acid value 1.4 – 6.7; ester value 15.9 – 40.9 and soluble in equal volume of 80 % alcohol (Deshaprabhu, 1966). Sadgopal (1959) also reported the major constituent of oil as methyl ether of β-phenyl ethyl alcohol (65 – 80%) and minor constituents as dipentene, α-linalool, phenyl ethyl alcohol, citral and some terpene esters.

According to Chandra (1985), the oil contained dipentene (6.0%), d -linalool (19.0%), phenyl ethyl acetate (4.6%), citral (1.8%), caproic acid (0.5%) and stearoptene (0.2%) besides the major constituent methyl ether of β-phenyl ethyl alcohol (67.0%).

4.1 Introduction

Insecticides, biocontrol agents and resistant varieties are the three important pest management tactics in vogue across the globe. Though several biocontrol agents have been recorded on major pests of economically important crops, mass multiplication techniques for most of them are yet to be perfected, and in several instances, the inundative releases of natural enemies are costlier than chemical insecticides. Moreover, unlike perennial crop ecosystems, the annual crop ecosystems like rice, cotton, sugarcane, pulses, etc. are frequently disturbed and hence, inoculative releases of biocontrol agents are often impractical. Above all, in spite of sustained effort from dedicated plant breeders across the globe, the resistant varieties with outstanding yield potential are very limited in numbers. Genetic engineering of crop plants though paved the way for introducing insecticidal genes more precisely and efficiently, the poorly understood ecological and sociological implications of genetically engineered crops in their target environment resist their strong footing in the pest management programmes in most of the crops especially of food crops. In this backdrop, insecticidal interference is inevitable to manage the insect pests, and they are the only weapon whenever the pest population crosses the economic threshold level.

Acid soils occupy about 30 percent of the land area of the world out of which 67% acid soils support forests and wood lands and 18 percent are covered by grassland vegetation. Only 4.2 per cent (179 million hectare) of the acid soils across the globe is used for arable crops.

Soil acidity is a major constraint in crop production. The removal of basic cations especially Ca and Mg by leaching and their replacement by acidic cations, H, Al and Fe on exchange complex leads to soil acidity. Soil developed from granite parent material are more acidic than those developed from basalt, shale or lime stone. In acid soils, low pH leading to toxic concentration of H⁺, Al³⁺, Mn²⁺ influences nutrient availability, organic matter decomposition and microbial activity.

Efficient soil amelioration and nutrient management practices are necessary for crops susceptible to soil acidity.

Chemical ecology is the study of ecological interactions between organisms mediated by chemical produced by those organisms. In short it is considered as the ecological functions of the chemicals. An insect, in various stages of its life history, performs various activities like host plant location, host plant selection,  feeding and oviposition, mating, escape from its natural enemies etc. and the chemicals play a crucial role than visual and audio signals. Chemical ecology encompasses the studies of these chemicals based interactions.

Abstract

Organic farming, the state - of - art technology of the present era in agricultural cultivation, is not new to India. Green revolution in last four decades of Twentieth Century made farmers more dependants on chemical fertilizers and chemical pesticides for harvesting highest crop yield but side by side increased environmental pollution as well as health hazards and reduced soil productivity by increasing nutrient imbalance in soil. Indian farmers have almost forgotten their century old practice of preparation of compost from farm wastes and its use in next cultivation for getting pollution free healthy food materials. This articles deals with the problems of chemical farming in Indian context and their solution through organic farming.

Chemical immobilization of elephants needs an understanding of itís special features as a priority. Lungs are adhered to the chest wall by fibrous tissue and there is no pleural space. This fact must be taken into consideration when the elephant is cast or put into positions that may inhibit respiration.The trunk of the elephant is a vital organ. An injured or paralyzed trunk is a serious problem; if it cannot be corrected, the elephant will starve.

Chemical restraint is a form of animal restraint technique in which a drug or a chemical is used to restrict the movement (walking, running, aggression) of an animal or sometimes just to sedate or to calm down the animal. Chemical restraint is a safe and effective capture method when applied correctly and with due precaution.

Key facts

    
•    Arsenic (As) is a metalloid, with properties intermediate between those of a metal and a non-metal. Arsenic can exit in the environment and biological systems in various inorganic and organic forms (species). These are arsenite - AsIII, arsenate - AsV, monomethyl arsonic acid (MMAA), dimethyl arsinic acid (DMAA), arsenocholine, arsenobetaine and arsenosugars. 
    
•    Arsenicals have a wide range of toxicity. In general, inorganic arsenicals are more toxic than oragnoarsenicals to biota and trivalent arsenic (arsenite) is more acutely toxic than pentavalent (arsenate) form in the following orders:
    
    Arsenous acid (AsIII) ®  arsenic acid (AsV) ® MMAA ®DMAA ® arsenocholine ® arsenobetaine.
    
•    Under oxidizing and aerobic conditions, the predominant form of arsenic (As) in soil and water is arsenate (AsV), whereas under anaerobic and reducing/or waterlogged conditions, arsenite (AsIII) predominates.
    
•    Inorganic AsIII and AsV are the major As species in groundwater, soils, terrestrial plants, whereas the main species found in marine animals is Arsenobetaine (AsB), which is considered to be non-toxic.
    
•    The LD50 values of different arsenicals show that arsenite (AsIII) is most toxic (LD50 range 15-42 mg/kg) and arsenobetaine is least toxic (LD50 > 10,000 mg/kg).

Key facts

Freshwater biotoxins

    
•    Biotoxins are naturally occurring toxic compounds produced by some freshwater cyanobacteria (blue-green algae) and marine algal species (dinoflagellates, diatoms).
    
•    Cyanobacteria are now recognised as a serious water quality problem with regard to drinking water supply and recreational use.
    
•    Environmental conditions that can promote cyanobacterial/blue-green algal blooms are: excessive nutrients (phosphorus and nitrogen); warm water temperatures (15-30OC); sunlight for photosynthesis; and quiescent or stagnant water.
    
•    Outbreak of human poisoning attributed to cyanobacteria are neurotoxins (e.g. anatoxin-a, anatoxin-a(s), saxitoxins) and hepatotoxins (e.g. microcystins, nodularin) produced by some strains of the cyanobacteria including Microcystis, Anabaena, Aphanizomenon spp.