eChapters

Migration shows the trends of social changes. From the historical viewpoint during the process of industrialisation and economic development, people migrate from farms to industries, from villages to cities, from one city to another and from one country to another. In modern times, technological changes are taking place in Asia, Africa and Latin America due to which these regions are witnessing large-scale migration from rural to urban areas.

Economists are interested in the study of migration because migration affects the supply of skilled and semi-skilled labourers, development of industries and commerce causing changes in the employment structure of the migrated people. Formulation of economic policies has a close relation with the process of migration because migration affects the economic and social development of a country.

In the landscape of social advertising, large-format media like hoardings (billboards) and wall paintings offer unique opportunities to create high-impact, place-based campaigns that can transform urban and rural environments into powerful canvases for social change. These supersized communication platforms command attention through their sheer scale and integration with the physical environment, creating opportunities for messaging that digital and smaller print formats simply cannot match. This chapter explores the distinctive considerations, techniques, and best practices for designing social advertisements specifically for hoardings and wall paintings. We’ll examine how these formats differ from other advertising media, how to leverage their unique characteristics, and how to navigate the practical and creative challenges they present. Whether you’re planning a city-wide campaign using commercial billboards or a grassroots initiative using community wall paintings, understanding the specific demands of these formats is essential for creating effective social messaging.

1. Introduction
As climate change advances, risk of managing soil and atmosphere with regard to emission and pollution is going out of hand. Many researches and reports say that currently the global warming is 1.1°C more than the pre-industrial levels, which is not far behind the target of 1.5°C which was agreed by nations under the Paris agreement in 2015 (Janki M, 2023). Achieving that will likely involve removing carbon dioxide from the atmosphere, according to the Intergovernmental Panel on Climate Change. But strategies like capturing and storing the carbon emissions from biofuel-burning power plants, or planting new forests to absorb carbon, can create their own problems. Recently UN security general said we are shifting to the “Era of global boiling” from global warming. Globally countries are witnessing unbearable heat waves, forest fires, irregular rainfall, flashfloods, coral bleaching and unpredictable weather patterns which often resulting in devastating effects on the coastal and hilly regions of the country. Around nine tipping points have been identified so far globally. Climate tipping points are threshold that when crossed leads to irreversible changes in the climate system and will have a severe impact on the living organisms on the earth. All these variations in climate are driving by increasing greenhouse gas (GHG) emissions and global warming. We cannot change the state of atmosphere to as existed thousands or millions of years ago. Only option left with us is to reduce emissions and prevention of further global warming and climate change. As we are already existing in some level of changed climate, responding to climate change involves a two-pronged approach, reducing emissions of and stabilizing the levels of heat-trapping greenhouse gases in the atmosphere through mitigation and secondly, adapting to the climate change. Because climate change is irreversible process.

Introduction 
Five-membered heterocyclic molecules play a unique function in both natural and synthetic organic chemistry. The chemistry of azoles is currently being continually investigated in pharmaceutical chemistry. One of the most important fields of medicinal chemistry is the study of heterocyclic bioactive molecules containing nitrogen atoms. Triazoles have been found as a potential heterocyclic component in a wide range of drug scaffolds. It has a five-membered nitrogen heterocycle core with three nitrogen atoms and two carbon atoms. In 1885, Bladin coined the word “triazole” to describe the five-membered (Singh et al., 2018). 1,2,3-triazole and 1,2,4-triazole are the two isomeric forms of triazole (Matin et al., 2022). The core has a substantial impact on biological activity. The influences of the nitrogen heteroatom on the reactivity of the lead compound target medication pharmacokinetics and metabolism are affected by interactions between the lead chemical and several target inhibitors. Table 1, shows two tautomers of triazole depending on the hydrogen bonded to the nitrogen ring. Antimicrobial (Patil et al., 2023), anticonvulsants (Guan et al., 2007), antimalarial (Gujjar et al., 2009), antitumor (Al-Soud et al., 2004), antiviral (Al-Soud et al., 2004), antiproliferative (Masood-Ur-Rahman et al., 2017), anticancer (Minjian et al., 2017), antioxidants (Karrouchi et al., 2016), analgesics (Lass-Flörl C. 2011), antifungal (Guan et al., 2007, Lass-Flörl C. 2011), antiplasmodial (Balabadra et al., 2017), antibacterial (Guan et al., 2007, Khaligh et al., 2016), immunostimulants (Lee et al., 2007), and antidiabetic (Wang et al., 2017) are just a few of the numerous medications that demonstrate the pharmacological significance of triazole as a core heterocyclic structural component show in Figure 1.

Introduction

Greenhouse gases (GHGs) are the atmospheric trace gases which absorb and emit infra-red radiation and thereby trapping the heat radiated from the earth surface. The commonly known agriculturally important GHGs are carbon dioxide (CO₂), methane (CH₄) and nitrous oxide (N₂O). The major anthropogenic sources of CO₂ emission in atmosphere are biosphere, burning of fossil fuels and land use changes in tropical forests. The atmospheric concentration of CO₂ has increased from 280 parts per million by volume (ppmv) in 1750 to 394 ppmv in 2012 and is currently increasing at the rate of 1.9 ppmv year-1 (NOAA, 2012). Atmospheric CH₄ concentration has increased from about 715 to 1826 parts per billion by volume (ppbv) in 2012 over the same period and is increasing at the rate of 7 ppbv year-1 (IPCC, 2007; EPA, 2013). Similarly, the atmospheric concentration of N₂O has increased from about 270 ppbv in 1750 to 325 ppbv and is increasing at the rate of 0.8 ppbv year-1 (IPCC, 2007; EPA, 2013).

Globally livestock sector is changing rapidly in response to globalization and increasing demand for quality foods of animal origin. Animal husbandry is the backbone of rural economy of our country. The value of output from livestock sector is about 29 percent of the total value of output (GDP) of the agriculture and allied sectors. The livestock sector has been contributing over 5% to total GDP. India ranks first in milk production which accounts for more than 15 percent of total world output and 40 percent of Asia’s total production. It continues to grow at about 4 percent per annum far exceeding the global average of 1-2 percent. Further, the manure from animals provides a good source of organic matter for improving soil fertility and crop yields. The gobar gas from the dung is used as fuel for domestic purposes. The surplus fodder and agricultural by-products are gainfully utilized for feeding the animals. Almost all draught power for farm operations and transportation is supplied by bullocks. Indian animal husbandry practices are based on minimal use of off-farm inputs and on management practices that restore, maintain and enhance ecological harmony. This principle also holds good for organic farming. The primary goal of organic agriculture is to optimize the health and productivity of interdependent communities of soil life, plants, animals and people (NOSB, 1995). Organic agriculture is an ecological production management system that promotes and enhances biodiversity, biological cycles and soil biological activity.

Abstract

The frictional properties such as coefficient of friction and angle of repose are very important in designing of storage bins, hoppers, chutes, conveyors, harvesters and threshers etc. Angle of repose is the angle made with the horizontal at which the material will stand when piled. The angle of repose is also important in designing the equipment for mass flow and structures for storage. The static angle of repose (b) was determined using an open-ended cylinder of 150 mm diameter and 250 mm height. The higher the moisture content, the higher the cohesion between the seeds. In terms of flow ability, the seeds are heavier and the inertia to move is increased. Coefficient of internal friction is the frictional resistance of seeds with each other. Coefficient of external friction is the frictional resistance between the seeds and the surface. The rolling resistance is directly proportional to the weight of the rolling object and to the coefficient of rolling resistance which is dependent on the rigidity of the supporting surface and indirectly proportional to the effective radius of the rolling object. The air velocity at which an object remains in a suspended state in a vertical pipe under the action of the air current is called terminal velocity of the object.

India is one among the top ten mega-diverse countries of the world in terms of fish diversity (Dudgeon 2003). FishBase (Froese & Pauly 2016) has listed around 917 freshwater fish species (out of 2465 total fish species) as occurring in India. According to National Fisheries Development Board, Hyderabad, inland and marine waters in India possess a rich diversity of ornamental fish, with over 195 indigenous varieties reported from North-East Region and Western Ghats, and nearly 400 fish species from marine ecosystems. There are several other fish species which qualify to be called as ornamental fish. Considering enormous and diverse indigenous fish resources of the country, there is immense scope for India to become a potential candidate and a strong competitor in the international ornamental fish trade. Government of India has recognized ornamental fish sector as one of the thrust areas for generating employment opportunities and augmenting our foreign exchange earnings. It is estimated that the sector is directly and indirectly supporting about 50,000 of house-holds mainly in rural India. Large number of freshwater ornamental fish species is recorded from Indian waters and the majority of the global trade is based on freshwater exotic ornamental fishes including both classified and non-classified types.

Flowers and various parts of the plant have been used for decoration and to commemorate various religious, festive, matrimonial and social gathering events in day to day life. The main drawback of fresh flowers and foliage is being highly perishable and delicate which cannot retain their beauty for longer durations. Moreover fresh flowers are not available round the year which can be overcome by the dehydration and drying techniques. Since ancient times, in Egyptian pyramids, fragrant dried flowers and herb garlands were encased along with mummified bodies. Japanese people created “Oshibana”, the “preserved flower art” of enduring designs to retain the exquisite beauty of the living plants centuries ago.

Later on, this craft making technique spread from Japanese to Victorian England because of their beautiful long lasting appearance. During middle ages monks dried flowers, foliage, and herbs for use in decorative motifs or for colouring their handprinted books.

Dried flower arrangements have been popular in Europe for centuries, and as early as 1700 AD, colonial Americans used dried flowers to brighten their homes, especially during the dark winter months.

Earlier botanists practiced dried flowers in the form of herbarium for the purpose of identification of various plant species. Though drying of flower was well known even in the past but for the first time the flowers were dried commercially in Germany (Sankari and Anand, 2014).

15.1 Introduction

A tsunami is a series of waves created when a body of water, such as an ocean, is rapidly displaced. Earthquakes, mass movements above or below water, volcanic eruptions and other underwater explosions, landslides, large meteorite impacts and testing with nuclear weapons at sea all have the potential to generate a tsunami. The effects of a tsunami can range from unnoticeable to devastating. The term tsunami comes from the Japanese words meaning harbor (“tsu”,) and wave (“nami”,). The term is created by fishermen who returned to port to find the area surrounding their harbor devastated, although they had not been aware of any wave in the open water. Tsunamis are common throughout Japanese history; approximately 195 events in Japan have been recorded.

A tsunami has a much smaller amplitude offshore, and a very long wavelength (often hundreds of kilometers long), which is why they generally pass unnoticed at sea, forming only a passing “hump” in the ocean (Fig. 15.1). Tsunami have been historically referred to as tidal waves because as they approach land, they take on the characteristics of a violent onrushing tide rather than the sort of cresting waves that are formed by wind action upon the ocean (Iwan, W.D., 2006).

The demand of day by day increasing population there is lacking of nutritious food to peoples all around world. Underutilized crops like small or minor millets are having more nutrition and providing calories up to 2000 to 3000 calories per person per day than our staple crops i.e wheat, rice, and maize etc. Small Millets are the most underutilized crop in the world possessing high nutrient-cereal qualities and potential for the improvement of food security, nation income and generate the employment for the rural peoples. Millets are rich in nutrients such as proteins, fibers, carbohydrates, fats, vitamin-B, and minerals like calcium, phosphorus, magnesium, iron, potassium, and zinc etc.They are highly nutritive crop, non-acid forming, glutan free and help in reducing blood sugar level, blood pressure, diabetes and cardiovascular diseases. They also help in preventing asthma and migraines sufferings and fighting malnutrition in children s and adults.S mall millets are considered the forgotten crop species because of lower yield compared to other millets i.e. Sorghum and Pearl millet and cereals i.e. rice, wheat, maize etc. Being a highly nutritive cereal crop, easy to digest, high fibers and low glycine-max content, environment friendly and prevent the human hazards small millets still remained neglected and underutilized crop. Out of 200 underutilized crops identified 29 are small millets species (NAS USA, ICUC). Considering the food demand of common peoples, emerging health consciousness and nutrient demand for food security emerged small millets to limelight because of ecologically sound to climate. Still, the harvest of crop demands combination of computational technologies to full-fill food needs of population. Recognizing the potential of small millets in improving the national income UN-FAO announced the year 2023 as International Year of Millets. This chapter focused on application of climate smart agricultural methods such as artificial intelligence for the improvement of small millets to achieve future food security.

Abstract
 
Opencast mining destroys the original land ecosystem and microbial community due to mining and stockpiling of mine rejects on adjoining land, which is a matter of great environmental concern. Mining creates formation of wastelands, formation of gullies, ravines, overburdens, reduced water infiltration and increased runoff. Reclamation of mined out areas is often difficult due to its chemical, physical and biological traits. Absence of topsoil is the most common feature of the mine spoils dumps. Arbuscular mycorrhizal fungi (AMF), the synonym of VAM fungi, are important microbes of soil that form symbiotic association with most of the terrestrial plants on the earth. Observations led to use of legume microsymbionts as biological substitutes for fertilizers. AMF diversity increases with species diversity of plants as the potential number of association increases. Dominant arbuscular mycorrhizal fungi can prevent the invasion of non-mycorrhizal plants on land where they have established symbiosis and promote their mycorrhizal host.

The following various types of irrigation methods and their systems are used in crop production in greenhouses and plant nurseries.

1.Hand Watering

2.Perimeter Watering System

3.Tube Watering System

4.Drip Irrigation System

5.Overhead Spray System

6.Ebb and Flow System.

1. PRESENCE OF OBJECTIONABLE WEEDS

Objectionable weeds present in the seed crop of the respective species should be removed and destroyed before flowering. They should be verified during field inspection (Table 1). The maximum permitted limit of objectionable weed in seed crop is presented in table 2.

Relationship Between Plant and Water

Water is the most vital component of the living cells and the basis of plant feeding. Water is also characterized with extraordinary physical properties: it has high specific heat, biggest latent heat of vaporization, very high thermal conductivity and greatest surface tension. Large amounts of heat are tied up with water because of very high specific heat, which contribute to both climatic stability and to heat budgets of the plants and other organisms. Water molecules are integral part of living systems being the solvent for metabolites and structural component of proteins and nucleic acids. In fact, biological macro-molecules cannot exist in their complicated secondary folding or spiralled helixes without the support of hydrogen bonding within their water matrix. The water matrix is also critical for metabolic activity because its properties of hydration permit ready reactivity between molecules in solution as well as between enzymes and their substrates, and the biochemical processes are sensitive to tissue hydration. A reduction of only 20-25 per cent below maximum hydration is sufficient to cause metabolic malfunctioning of many enzymes. It is the substrate for photosynthesis and a product of respiration. Water also helps to buffer plant tissue against fluctuations in the external environment. Plant growth including leaf expansion, organ enlargement, reproductive development and stomata function are all clearly associated with moisture status. Hormonal changes (abscisic acid and cytokinins) in plant body occur with brief reduction in water potential. Water is the also major force in shaping the climatic patterns.

Research setting refers to the detailed information of an area where the study was conducted. The study area generally comprises of a particular geographical area viz. a state, district, block, or gram panchayat area selected according to the convenience of the investigator who possess adequate knowledge regarding the location, communication facility etc. of the locality so that he can easily approach each and every corner of the area for data collection. Besides the investigators must also have the basic knowledge about the socio demographic background of the people so as to have an easy understanding of their knowledge, attitude and behavior. This chapter is intended to present a brief description of the area in terms of social, economic, and agricultural aspects where the present study has been conducted.

1. Introduction
Aquaculture is one of the most rapidly expanding sectors in food production, making significant contributions to global food security and the economy. As natural fisheries resources are depleted, aquaculture has become an essential source of protein and employment for millions worldwide. With an increasing demand for seafood, the intensification of aquaculture systems has become necessary. This intensification, characterized by high stocking densities, increased fish production, and automation, has introduced a range of challenges that negatively impact the health and well-being of farmed fish and other aquatic species.
1.1 Stress in Aquaculture Systems
Stress is an inevitable part of aquaculture, particularly in intensive farming systems where fish are exposed to multiple environmental, biological, and anthropogenic stressors. Stress refers to a physiological condition where the normal homeostasis of an organism is disrupted due to external stimuli. In aquaculture, stress can arise from various factors, including changes in water quality parameters (such as dissolved oxygen, temperature, and pH), overcrowding, transportation, handling, and exposure to pathogens. The physiological response to stress can lead to a cascade of negative outcomes, including suppressed immunity, impaired growth, decreased reproductive success, and increased susceptibility to disease. If not adequately managed, stress can cause significant economic losses, affecting the sustainability and profitability of aquaculture operations.

1. Introduction
Chemists have been interested in using light as an energy source to trigger chemical reactions since many years. Under the photochemical conditions, molecules absorb light and get electronically excited. Consequently, in comparison to the ground state, the electronic distribution in the molecules is substantially altered in excited states. The reaction spectrum of a family of compounds is significantly expanded. In many cases, a complete synthesis can be greatly shortened by employing photochemical processes, and simple substrates can often yield complex, polycyclic, or highly functionalized molecules. This opens up new avenues in search of physiologically active compounds by providing new product libraries that are hard to obtain using ground-state reaction pathways. The photochemical reactions proved to be very fruitful for organic synthesis. It is because a large number of compounds having both industrial and academic importance required excited state for their synthesis (Glusac, 2016). The compound exhibits different chemical reactions in photochemically excited state (Oelgemöller & Hoffmann, 2016). The light induced chemistry has become a fascinating research area for last several decades. In 1912, Ciamician in his seminal work prophesied the necessity regarding the conversion of solar energy to chemical energy in future and its impact in future life for renewable energy (Oelgemöller & Hoffmann 2016). The need of photochemistry is of utmost importance for some fascinating reactions anticipated in future like splitting of water into oxygen and hydrogen, artificial photosynthesis and even photocatalysis (Fujishima & Honda, 1972; Chu et al., 2017). The familiar light driven reactions include cyclization of conjugated molecules to polycyclic compounds, photodissociations and both intra- and intermolecular proton transfer reactions (Li et al., 2010; Lan et al., 2005; Devine et al., 2008; Ashfold et al., 2006; Blank, 1994; Szabla et al., 2016). The photodissociation reactions occurs through ps* states, the s* orbital is situated around A-B bond (A and B are respectively a heteroatom and leaving group). However, the proton transfer reactions (PT) occur via charge transfer states. In this book chapter we will explore the synthetic utility and applications of Barton reaction.

Small ruminants are grazing mammals and this group consists of sheep (Ovis aries) and goats (Capra hircus).Advantage of these animals is their low cost, small size and marginal land use, which convert into high quality animal products. Sheep is a grazing animal and goat is a browsing animal. They are generally kept in flock. Therefore flock management is more important than the individual animal. Though, procedure of history taking and physical examination is almost similar to other animals, some peculiarities warrant a separate discussion. Sheep The general methods of history taking and physical examination of sheep are similar to cattle and goat starting from owner’s complaint (history), signalment of the patient, history of the ailing

ABSTRACT

This paper demonstrates the ability of FTIR for analyzing compositional structures of naturally occurring crystals namely gypsum and calcite. As these two crystals occur in a wide variety of geological environments and are susceptible to compositional and structural changes influenced by pressure, temperature, crystallization fluids and so many other factors, these are extensively studied by geoscientists for interpretation of paleoenvironment, modeling diagenesis of sediments and deducing sediment maturity for hydrocarbon exploration, study of these two crystals is important. Naturally occurring gypsum and calcite crystals collected from Cretaceous marine deposits of Ariyalur area were chosen for the present study as extensive occurrences of hydrocarbons are reported from offshore region of Cauvery basin and exploratory works are going on in the onland region. It is observed that the vibrational spectra of studied crystals show specific patterns in terms of stretching patterns of O-H, C-O, C=O, SO₄ and CO₂. As FTIR offers fast, cost-effective, non-destructive method of analyses of natural compounds, as it is proven useful, it can be utilized extensively in academic research and commercial exploration activities by geoscientists.

Keywords : Spectral characterization, calcite, gypsum, diagenesis, paleoclimate, hydrocarbon exploration.