eBook Chapters

A. Answer the following question:

1.    What is carbohydrate?

Ans: Literally means hydrates of carbon. Carbohydrates are polyhydroxy (more than one OH group) aldehyde or polyhydroxy ketoneas in monosachharides; their olymers as in oligo and polysaccharides; their reduction products as polyhydric alcohols; oxidation products as aldonic, uronic, sacharic acid; substitution products as amino sugars.

2.    What is sugar?

Ans: The term sugar is generally restricted to those carbohydrates containing less than 10 monosaccharide residues.

3.    What is dextrin?

Ans: It is the intermediate products of the hydrolysis of starch and glycogen.

4.    What is exergonic reaction?

Ans: That portion of energy change during a reaction which is available to do work is termed the free energy change, designated, “G. when “Gis negative the reaction is said to be exergonic.

5.    What is substrate level phosphorylation?

Ans: Whenproductionof ATPfromADPtakesplacedirectlyduring a reaction, the process is known as substrate level phosphorylation.

6.    Why carbohydrate is a metabolically essential?

Consumption of fruit and vegetables has dramatically increased globally during the past a few decades. These are living perishable biological entities which perform a number of metabolic functions and have a short life span. Once the fruit is harvested, respiration and transpiration continue, but only for as long as the fruit can draw on its own food reserves and moisture. It is this limited ability to continue vital metabolic functions which define fruit as perishable. It is also estimated that about 20% of all fruits and vegetables produced are lost each year due to spoilage. The process of the fruit spoilage is just the decomposition of the fruit itself. Once harvested, this begins to deteriorate until eventually it becomes unfit for consumption. This deterioration is known as decay and that leads to spoilage. Latter may be defined as “any sensory change (physical, visual, olfactory or flavour) which the consumer considers to be unacceptable. The gradual changes which cause deterioration and decay in fruits are due to certain organisms and chemicals present in the food and outside the food. Carbohydrates play a major role in the fruit spoilage process (Prasanna et al., 2007) by way of depolymerization leading to decreased molecular size with concomitant increase in the levels of ripening inducing specific enzymes, whose target differ from fruit to fruit. The major classes of cell wall polysaccharides that undergo modifications during ripening are pectins, cellulose, starch, and hemicelluloses (Hallet et al., 2005). The focus of this chapter is to provide information about carbohydrate metabolism during fruit spoilage.

Carbohydrate metabolism in the cell is essentially the metabolism of glucose and other substances related to glucose in their metabolic processes. The chemical reactions involved in carbohydrate metabolism represents complex groups, sequences, and cycles of reactions which integrate at various points with the reactions concerned in the metabolism of lipids and proteins. The major types of chemical processes involved in carbohydrate metabolism may be grouped as follows: a) Anabolism of starch – Photosynthesis, b) Catabolism of starch, c) Catabolism of glucose – 1. Glycolysis and TCA cycle and 2. Oxidative pentose   phosphate pathway.
 
Plant cells “burn “ glucose for energy. Plants also produce sugars through photosynthesis. This is roughly the reverse of the burning process.

Introduction

Carbohydrates are the most common source of energy for all living cells, which, in presence of light, are formed by the green plants from CO₂ and water during photosynthesis. It canbe said that ‘light’ is theultimatesourceof energyrequired for all livingcells.Glucose,a monosaccharide,plays a centralroleincarbohydrate metabolismin all plants, animals and manymicroorganisms. Glucose is derived from the polysaccharides (starch, glycogen) and non-carbohydrate sources (amino acids, glycerols, etc.) during metabolism and ultimately converted either into carbondioxide and water orotherintermediateproducts.Complete oxidation of glucose to CO₂ and water provides ~2,840 kJ/mol energy. The other monosaccharides such as fructose, galactose, mannose, etc. are also important molecules in carbohydrate metabolism.

The most abundantly and commonly available compounds in the plant kingdom are carbohydrates. They comprise saccharides viz.

Monosaccharides - glucose, fructose etc.

Disaccharides - sucrose, lactose, maltose etc.; and

Polysaccharides - starch, cellulose etc.

Cellulose is the major component of plant cell wall.

The active groups in carbohydrates are aldehyde (-CHO) and ketone (=CO). In addition, they contain hydroxyl groups as well. The chemical properties of saccharides vary depending upon the number of hydroxyl groups and the presence or absence of (–CHO) or (=CO) groups.

1. Carbohydrates are primarily composed of the elements
   1. Carbon, hydrogen and oxygen
   2. Hydrogen, oxygen and carbon
   3. Oxygen, carbon and hydrogen
   4. None of these
2. Carbohydrates have an empirical formula
   1. (CH₂O)_n
   2. (CH₂O)_n+₁
   3. (CH₂O)_n-₁
   4. (CH₂O)_n/₂

Carbohydrates are the most abundant biomolecules on earth. They occur in nature as glucose, starch and cellulose etc. Each year, photosynthesis converts more than 100 billion metric tonnes of carbon dioxide and water into starch, cellulose and other plant products. Carbohydrates are polyhydroxy aldehydes or ketones and their derivatives. They provide 4K calories of energy per gram. They promote utilization of lipids and reduce wastage of proteins. They are readily available in roots, tubers, cereal grains, sugarcane and sugar beet.

Carbohydrates are synthesized from CO₂ and H₂O in chlorophyll containing plants during photosynthesis. The term carbohydrate was originally coined for this class of compounds as most of them were hydrates of carbon or could be represented by the general formula C_n(H₂O)n. Not all the carbohydrates however, have this empirical formula, for example deoxyribose (C₅H₁₀O₄) and glucosamine (C₆H₁₃O₅N). Further lactic acid (C₃H₆O₃) formaldehyde (HCHO or CH₂O) and acetic acid (CH₃­.COOH or C₂H₄O₂) with this general formula is not a carbohydrate. Carbohydrates are defined as the compounds having either an aldehyde or a ketone group or a modified aldehyde or ketone group and other carbon atoms with alcoholic (-OH) group. Hence the continued usage of the term carbohydrate is for convenience rather than exactness.

Carbohydrates are the most abundant biomolecules on earth. They occur in nature as glucose, starch and cellulose etc. Each year, photosynthesis converts more than 100 billion metric tonnes of carbon dioxide and water into starch, cellulose and other plant products. Carbohydrates are polyhydroxy aldehydes or ketones and their derivatives. They provide 4k calories energy per gram. They promote utilization of lipids and reduce wastage of proteins. They are readily available in roots, tubers, cereal grains, sugarcane and sugar beet.

Carbohydrates have the general formula C_n( H₂O)n, indicting that they are the hydrates of carbon. Some carbohydrates also contain nitrogen, phosphorous or sulfur. They are characterized by the number of carbon atoms they contain. If n=3, they are trioses, n=4 tetroses, n=5 pentoses, n=6 hexoses and n=7 heptoses. The most common sugars in plants are the hexoses. Two or more simple carbohydrates condense together to form polymer sugars like sucrose, starch and cellulose etc. The basic condensing bond is glycosidic bond.

A carbohydrate is a large biological molecules, or macromolecules, consisting of carbon (C), hydrogen (H), and oxygen (O) atoms, usually with a hydrogen : oxygen atom ratio of 2:1 (as in water); in other words, with the empirical formula C_m(H₂O)_n (where m could be different from n). Some exceptions exist; for example, deoxyribose, a sugar component of DNA, has the empirical formula C₅H₁₀O₄. Carbohydrates are technically hydrates of carbon; structurally it is more accurate to view them as polyhydroxy aldehydes and ketones.

The term is most common in biochemistry, where it is a synonym of saccharide. The carbohydrates (saccharides) are divided into four chemical groups: monosaccharides, disaccharides, oligosaccharides, and polysaccharides. In general, the monosaccharides and disaccharides, which are smaller (lower molecular weight) carbohydrates, are commonly referred to as sugars. While the scientific nomenclature of carbohydrates is complex, the names of the monosaccharides and disaccharides very often end in the suffix -ose. For example, grape sugar is the monosaccharide glucose, cane sugar is the disaccharide sucrose, and milk sugar is the disaccharide lactose.

1.    Carbohydrates can be represented by

(a) Fischer projection formula

(b) Haworth cyclic structure

(c) Both (a) and (b)

(d) None of these

2.    If a compound has got four chiral centers then it will have isomeric structures.

(a) 4

(b) 8

(c) 16

(d) 64

3.    The sugar, which does not possess chiral center is

(a) Glucose

(b) Fructose

(c) Glyceraldehyde

(d) Dihydroxyacetone

Food is composed of three main constituents viz; carbohydrates, proteins and fats and their derivatives. In addition to these constituents, inorganic mineral elements and diverse organic compounds like vitamins, pigments, flavouring compounds, enzymes, and acids are also present. Carbohydrates, proteins, fats and vitamins are organic in nature. The percentage of water is large in certain foods. The variation in structure, texture, colour, flavour and nutritive value is because of the varying proportions and arrangements of these constituents.

Carbohydrates are important in foods as a major source of energy, to impart crucial textural properties, and as dietary fiber which influences physiological processes. Digestible carbohydrates, which are converted into monosaccharides, which are absorbed, provide metabolic energy. Carbohydrates account for more than 70% of the caloric value of the human diet. It is recommended that all persons should limit calories from fat to not more than 30% and that most of the carbohydrate calories should come from starch. Non-digestible polysaccharides (all other than starch) comprise the major portion of dietary fiber.

Carbohydrates are the macronutrients consisting of carbon (C), hydrogen (H), and oxygen (O) atoms. In simpler terms, carbohydrates can be defined as polyhydroxy aldehydes or ketones or substances, which yield them on hydrolysis. The general formula of carbohydrates is Cn (H2 O)n , where n is the number of carbon atoms. In nature, carbohydrates are the most abundant biological molecules. In the human diet, carbohydrates are one of the main nutrients that provide energy to the body. The green plants, through the process of photosynthesis, synthesize the carbohydrates.

Classification of carbohydrates

Carbohydrates are also known as saccharides, originating from the Greek word sakcharon, which means sugar. However, not all saccharides have a sweet taste. Carbohydrates can be classified into three distinct groups: monosaccharides, oligosaccharides, and polysaccharides. The number of sugar units determines this classification.

Monosaccharides

Monosaccharides, or simple sugars, are the most basic carbohydrates. They are the monomers that serve as the building blocks for forming polymers or complex carbohydrates. Monosaccharides are the most simple carbohydrates possessing carbonyl groups, i.e., aldehyde (CHO) and ketone (C=O) groups with two or more hydroxyl (OH) groups. Monosaccharide has the generic formula Cn (H2 O)n, where n is the number of carbon atoms. Monosaccharides are sugars that cannot be hydrolyzed further to form simple carbohydrates. These crystalline solids without color dissolve in water but remain insoluble in non-polar solvents.

Abstract
Grain legumes, members of the Fabaceae family, are essential for global nutrition and sustainable agriculture. The legumes such as soybean, chickpea, lentil, pigeon pea, black gram, green gram, faba bean and field peas are renowned for their high protein and energy content. A core aspect of their significance lies in their ability to fix atmospheric nitrogen through symbiotic relationships with Rhizobium bacteria, enhancing soil fertility and reducing the need for synthetic fertilizers. This process, coupled with their role in carbon sequestration, positions legumes as crucial components of sustainable farming systems. Grain legumes, as C3 plants, rely on efficient carbon assimilation to convert atmospheric CO2 into biomass, supported by high nitrogen content for optimal photosynthesis. Additionally, the symbiotic nitrogen fixation within root nodules enables legumes to transform atmospheric nitrogen into forms usable by plants, thereby contributing to soil nitrogen pools and reducing greenhouse gas emissions. By integrating
legumes into crop rotations, farmers can enhance soil health, lower fossil energy inputs, and support ecological sustainability. This comprehensive analysis underscores the critical roles of carbon and nitrogen assimilation in maximizing the environmental and agronomic benefits of grain legumes.
Keywords: Carbon assimilation, Grain legumes, Nitrogen assimilation, Nitrogen fixation, Photosynthesis

Introduction

Organic matter in sediment consists of carbon and nutrients in the form of carbohydrates, proteins, fats and nucleic acids. Bacteria quickly eat the less resistant molecules, such as nucleic acids and many of the proteins. Sediment organic matter is derived from plant/animal detritus, bacteria or plankton formed in situ. Total organic carbon refers to the amount of organic matter preserved within sediment.

Materials

1. Sample
2. Crucibles
3. Furnace

Procedure

Take 1.0 g of sample in a crucible whose empty weight is already recorded. Place this crucible in a furnace. Switch on the furnace and set the temperature at 550°C. Keep the samples for 3 hours

1. Aquaculture and Shrimp farming

Considering the current population explosion and the speed of human-centered land encroachment, scientists have expressed concern about the availability and production of food to meet global demand. The agricultural sector alone would not be able to cope with such a huge global demand of 7.6 billion people, which does not seem to be decreasing in any way. Approximately 20% of the global population consumes fish, which originate in the aquaculture sector. On the other hand, it has grown many fold with advancements in science and technologies in fish production and post-harvest, which has become a prominent commercial sector. The fisheries sector is broadly classified into two types: marine and inland. In marine fisheries, fishermen venture into the sea to fish with their fishing vessels and gear to harvest fish, whereas in inland f isheries, fishermen go fishing in rivers, lakes, and reservoirs. However, with advancements in technology and growing demand for fish as food sources, people have started growing fish in captivity under controlled and semi controlled conditions in ponds. The history of fish culture tracks back to 2000 BC, which originated in China, where they started growing carp in captivity by providing the required conditions for fish growth. Providing suitable conditions in captivity means providing the required physical and chemical environment in the culture system by keeping the physicochemical parameters at the optimum level as required by the species cultured. Physicochemical parameters of soil and water are key to the successful culture of fish, which is why emphasis has been placed on the scientific study of the physical and chemical parameters of soil and water.

Carbon assimilation or carbon fixation is the conversion of inorganic carbon (carbon dioxide) to organic compounds by living organisms. The most prominent example is photosynthesis, although chemosynthesis is another form of carbon fixation that can take place in the absence of sunlight. Organisms that grow by fixing carbon are called autotrophs. Autotrophs include photoautotrophs, which synthesize organic compounds using the energy of sunlight, and lithoautotrophs, which synthesize organic compounds using the energy of inorganic oxidation. Heterotrophs are organisms that grow using the carbon fixed by autotrophs. The organic compounds are used by heterotrophs to produce energy and to build body structures. “Fixed carbon”, “reduced carbon”, and “organic carbon” are equivalent terms for various organic compounds.

15.1 Introduction

There is now adequate evidence about the impending global climate change and the consequences thereof. The fourth assessment report of IPCC observed that ‘warming of climate system is now unequivocal, as is now evident from observations of increase in global average air and ocean temperatures, widespread melting of snow and ice, and rising global sea level’ (IPCC, 2007). Though climate change is global in its occurrence and consequences, it is the developing countries like India that are likely to face more adverse consequences. Globally, climate change is seen as a failure of market mechanisms wherein the polluters haven’t had to pay for the negative externalities (Stern, 2007) that their economic activities caused.

Soil microorganisms in true sense are one of natural safety valves that regulate biogeochemical transformations in soil ecosystem. They act as natural agents for the disposal of organic matter. The various essential biological elements such as C, N, S and P, apart from H and O, form the primary building blocks of cells and their constituent elements are recycled through tiny microorganisms present in soil. More they are in quality and quantity, better recycling is expected by them. The organically bound materials are converted to simpler inorganic forms to complete biological cycle initiated during photosynthesis and other anabolic processes.

The cradle-to-grave dairy supply chain includes a number of operations that result in greenhouse gas (GHG) emissions related to milk production. These activities broadly include the use of agricultural inputs like fertilizers, fossil fuel for the production of animal feed and fodder, processing concentrates in cattle feed plants, enteric fermentation, manure management, and post farm gate activities like processing milk at dairy cooperative societies, milk unions, its conversion into different milk products, and their distribution through retail supply chains.

ABSTRACT

The rapid growth in population has created the need of industrialization and as a result there has been a significant increase in milk production and processing. Milk is a commodity which is consumed by persons of all age groups due to its nutritive value and health promoting attributes. However, the rapid growth in dairy sector has adversely affected the environment by emitting various greenhouse gases and thereby, resulting in global warming. Apart from it, there has been an increased usage of non- renewable resources like natural gas and coal in dairy sector. As a result, a viable balance has to be maintained between milk production and processing, environmental health and the rapidly growing population. This can only be achieved with the application of green or environment friendly technologies in all the stages of milk production and processing. This chapter will mainly deal with the various sources of greenhouse gases from dairy sector and on application of life cycle assessment and carbon foot printing for computing the impact of greenhouse gases on the environment. Also, this chapter will enclose various green technologies which can be applied in dairy sector to curb the greenhouse gas emissions.

Keywords: Carbon footprint, LCA, Greenhouse gases, Green Technology, Milk production, Milk Processing

Abstract

Cultivation of cash crops of good quality potent to give good economic returns depends largely upon adoption of modern practices in agriculture. The region under test consideration is completely irrigated and cultivates mostly the crops of grapes and sugarcane. A field testing that was carried out for the pumps used by local farmers, revealed glaring inefficiency in pump operation. This is attributed to numerous reasons, the standout of them-being improper pump selection and deviation from operating point. Survey of the farming pattern helped to establish nexus between the energy usages per acre for the two crops. Carbon Footprint was determined for the electricity utilized in these farms. Adoption of selection methodologies and efficient practices would lead to considerable saving in electrical power consumption. The impact of adoption of efficient practices was therefore quantified.

Keywords: Agriculture, Carbon Footprint, Pumps

Introduction
Global aquaculture plays a significant role in ensuring food security both directly (by making food more accessible and available) and indirectly (by promoting economic growth). Since the 1980s, aquaculture production has increased, and it has been suggested that there is theoretically enormous potential for further growth. FAO came to the conclusion that the industry should acknowledge the pertinent environmental and social issues as it continues to grow, intensify, and diversify. Climate change, and more especially the greenhouse gas (GHG) emissions that occur along food supply chains, is one of the major environmental (and social) problems. We must comprehend how aquaculture contributes to global GHG emissions and how to reduce them in order to support its sustainable growth (FAO, 2019).
What are Green House Gases?
Heat-trapping gases in the earth’s atmosphere are referred to as greenhouse gases, or GHGs. Maintaining a temperature on Earth that is conducive to life depends on greenhouse gases. The average temperature on Earth would be around -20°C if the greenhouse effect didn’t exist. Since the beginning of the Industrial Revolution, human activity has raised the atmospheric quantities
of greenhouse gases. The major GHG’s emitted into the earth’s atmosphere is given in Fig. 1.

10.1 Introduction

A single-walled carbon nanotube (SW-CNT) is a nano scale tube formed by a cylindrical shell of single atomic layer of carbon atoms. Nanotubes have diameter of a few nm and length up to 100 nm so that they form extremely thin wires. The atomic structure of SWCNT can be formed by wrapping a stripe of single atomic layer of graphite sheet al.,ong a certain direction, and this direction determines the diameter and chirality of the nanotubes. Experimental and theoretical studies have found that these nano-meter sized CNTs have novel electronic properties, which can be metallic or semiconducting, depending on their radius or chiralities (Mintmire 1992, Hamada 1992, Saito et. al., 1992, Rao 1997, Wildoer 1998 and Odom et al., 1998).

Introduction Nanoscience is a competitive and trending concept in present scientific community, especially in agricultural and allied sciences. The usage of nano-sized materials in food processing sector spreading slowly. With the passage of time and innovation continuation in nanotechnology creating interest to develop miniaturized sensors. Miniaturized sensors have lots of benefits like reducing bulkiness with low power consumption and this eventually reduces the cost. Generally inorganic semiconductors are widely used to develop nano sensors. Generally, sensors are composed of two basic unit which are an identification element and a signal transducer element. Due to its simple structure, high portability and low price, can benefitted against disadvantages of existing system, which are costlier and much more popular. High portability, ease of placement and use make it suitable for onsite use with real-time monitoring. Also, helps in qualitative and quantitative analysis of such substances during analysis of foods which may cause danger and thus inhabit a wider research and development space. For the detection of different unwanted materials or compositions in food, various chemical or biological sensing devices based on different working principles have been developed. The carbon-based nano material can be categories as Ordered Mesoporous Carbon, Carbon Nanotubes, Graphene and Its derivatives, and Carbon Dots.

Introduction

Today, according to Global Assessment of Land Degradation and Improvement (GLADA), nearly one forth area of our world land has been degraded (Arora 2019). The United Nations Convention to Combat Desertification (UNCCD) is leading the issues of soil or land degradation to restore valuable natural resources for achieving a land degradation neutral world by 2030 (Cowie et al., 2018; IPBES, 2018; Bhattacharya, 2020). Land degradation neutrality (LDN) can be achieved primarily through adoption of sustainable land management practices. Soil organic carbon (SOC) plays a multifunctional role and is sensitive to land management practices and a key indicator of soil quality, soil health and LDN. Soil is a major reservoir of terrestrial C in the biosphere and plays an important role in global C cycle. Therefore, a little change in SOC pool can significantly influence the atmospheric CO2 concentration. In general, 1 Pg of SOC stock is equivalent to about 0.47 ppm of CO2 in the atmosphere, and vice versa (Lal, 2018). Besides this it maintains overall soil sustainability and enhances food security.

Achieving carbon neutrality in Indian soils is a major challenge. Because, productive land goes out of cultivation and marginal or degraded land comes under cultivation due to urbanization, industrialization and various development activities. Also, it is very difficult to increase SOC because climatic condition prevails with a high rate of decomposition. According to an UN report, India will be the most populated country in the world and expected to add 273 million people between 2019 and 2050 which will exert huge pressure on natural resources, particularly soil and water to fulfil the increasing food demands of such ever-growing population. The extensive use of natural resources along with intensive cultivation will enhance greenhouse gases (GHGs) emission, slow down agricultural productivity, enhance land degradation, and decline factor productivity of major production systems. Due to change in distribution of rainfall and concurrent rise in temperature owing to climate change, the fertile top soil becomes more prone to degradation.

14.1 Introduction

Atmospheric concentration of CO₂ has increased from 280 ppm in pre-industrial era to 385 ppm in 2008 (+ 37.5%) and is presently increasing at the rate of 2 ppm yr^-1 or 3.5 Pg yr^-1 (1 Pg or petagram = 1 Gt = 1 gigaton = 1 billion metric ton). The increase in CO₂ emission by human activity is attributed to fossil fuel combustion, deforestation and biomass burning, soil cultivation and drainage of wetlands or peat soils. Increase in fossil fuel combustion is caused by high global energy demand of 475 Quads (1 quad = 1015 BTU) and increasing at the rate of 2.5 % yr^-1, especially in emerging economies including China, India, Mexico, Brazil, etc. The world population of 6.7 billion in 2008 is increasing at the rate of 1.3 % yr^-1 and is projected to be 9.5 billion by 2050 before stabilizing at 10 billion towards the end of the 21^st century. There exists a strong positive correlation between population growth on the one hand and CO₂ emission or the energy demand on the other. The People’s Republic of China accounted for 13% of the world’s C emissions in 2002 and that share is projected to rise to 18% by 2025 (Lal, 2004a).

INTRODUCTION

Climate change is one of the most important global environmental challenges facing humanity with implications for food production, natural ecosystems, freshwater supply, health, habitat destruction biodiversity, etc. According to the latest scientific assessment, the earth’s climate system has demonstrably changed on both global and regional scales since the pre-industrial era. Since the very beginning of civilization, land resources have been under tremendous pressure for food and forest products. Anthropogenic activities have affected the biosphere through changes in the landuse and forest management activities, thus altering the natural balance of greenhouse gases in the atmosphere. The environmental security thus, has become a serious concern across the globe. The meteorological records have shown significant increase in the environmental temperature referred to as the global warming. Human activities have increased green house gases and raised global temperature by 0.50 C over the past 100 yr, which may increase by 1.4 to 5.8°C during the next century (Bhadwal and Singh 2002). Evidence of this global crisis include the rise in global sea levels by 3.4 mm yr-1 ((http://climate. nasa.gov/vital-signs/sea-level/) through the melting of the world’s snow peaks and glaciers, which poses a threat to millions living in coastal areas. A drastic effect on splitting of huge glacier in the Antarctica has already been registered, which has thrown a challenge to save the earth, lest the very survival of the mankind will be jeopardized. Each degree rise in temperature will displace the limits of tolerance of land species some 125 km towards the poles or 150 m vertically on mountains. The Inter-governmental Panel on Climate Change (IPCC) estimates that 20 to 30 per cent of plants and animals could be at risk of extinction if average global temperatures reach the projected levels (Hawkes et al., 2000).

Greenhouse gas emission is likely to rise by 25-90% by 2030 relative to 2000 and the earth could warm by 3° C at the end of this century. Even with a temperature rise of 1-2.5° C, the Intergovernmental Panel on Climate Change predict serious disastrous effects, including reduction in crop yields in tropical and subtropical areas leading to increased risk of food shortage, spread of climate responsive diseases such as malaria, and an increased risk of extinction of 20-30% of all biodiversity present on earth (IPCC, 2007). Carbon dioxide is the most important among all greenhouse gases. Carbon sequestration may be defined as the process of removing C from the atmosphere and depositing it in a reservoir. It entails the transfer of atmospheric carbon dioxide, and its secure storage in long-lived pools (UNFCCC, 2007).

From the agroforestry point of view, carbon sequestration involves primarily the uptake of atmospheric CO₂ during photosynthesis and transfer of fixed carbon into vegetation and soil pools for ‘secure’ storage. It occurs in two major segments of agroforestry systems; aboveground and belowground. The total amount sequestered in each part differs greatly depending on a number of factors including the region, the type of system, site quality, and previous land-use (Nair, 2012). On average, the soil and aboveground parts are estimated to hold major portions, roughly 60 and 30%, respectively, of the total carbon stored in tree-based land-use systems (Lal, 2010). Sequestering CO₂ from atmosphere through natural techniques such as afforestation, reforestation, natural regeneration of forests and the adaptive agriculture is more economically and ecologically sound in increasing the carbon storage capacity of the terrestrial ecosystems (Dhyani, 2014). Although carbon sequestration through afforestation and reforestation of degraded natural forests has long been considered useful in climate change mitigation, agroforestry offers some distinct advantages (Murthy et al., 2013). The carbon in the aboveground and belowground biomass in an agroforestry system is generally much higher than the equivalent land use without trees. An agroforestry system has higher carbon sequestration potential than pastures or field crops (Kirby and Potvin, 2007).

ABSTRACT

The increasing level of green house gases in general CO₂ in particular has raised concerns about the vulnerability of human, animal and plant life. These concerns have prompted the Governments world over to take the appropriate measures to save them from perspective destruction. Forests though serve as source and sink of the CO₂, there is need to synthesize the impact of climate change on forests and the role of forests in global carbon cycle. Climate change needs to become part of decision making in forest management. Also, the agroforestry, a potential carbon sequestration activity is lagging behind, there is a growing interest in it in countries that have not only ratified Kyoto Protocol but also facing many other ecological problems on their private working land. The Clean Development Mechanism (CDM) offers benefits through sink credits and reduces the negative impact of climate change, therefore, necessary institutional arrangements should be put in place to use CDM projects effectively for generating resources through afforestation and reforestation projects for the well being of present as well as future generation. Forest/agroforestry scientists/managers need to realize the current degree of vulnerability and start thinking about their ability to cope with the impacts. Governments have initiated negotiations on policy actions to reduce the green house gases and addressed the vulnerabilities of the ecological, economic and social systems to climate change. It may be one of the least expensive ways for industries to off-set their carbon emission and tree growers to benefit through the carbon trade. Despite the fact that the certain aspects under Kyoto Protocol are still under clarification and negotiation, the forest plantations will play an important role in carbon sequestration and the implementation of Kyoto Protocol. Since the development of plantation is a slow process, the dividends will only be realized after a gap therefore the new plantation should be taken up without delay and the old one be managed as per their silvicultural rotation.

Global climate changing has been a focus for a long time in many fields, the increasing CO₂ concentration in atmosphere was considered as one main driving force for global warming. The increases in greenhouse gasses in the atmosphere contributed to raise concerns over climate change enhanced the role of forests and plantations in the global carbon cycle are growing as a great issue. Carbon dioxide (CO₂) is one of the main greenhouse gases because a huge volume of CO₂ is added to the atmosphere, when compare to all other greenhouse gases and made itself as a primary agent of global warming. It contributed 72 per cent of the total anthropogenic greenhouse gases, causing between 9-26 per cent of the greenhouse effect (Kiehl and Trenberth, 1997). According to the Intergovernmental Panel on Climate Change (IPCC), there has been an unprecedented warming trend during the 20th century. Scientists now have estimated that the average global surface temperature is likely to rise by 1.4 to 5.8°C by the end of the 21^st century (IPCC 2007).

The IPCC estimates that the level of carbon dioxide in today’s atmosphere is 31 per cent higher than it was at the start of the Industrial Revolution about 250 years ago. An atmospheric level of CO₂ has risen from 280 ppm at the pre-industrial to the present level of 375 ppm. Most of the increase has occurred in the second half of the 20^th century. The mitigation of climate change demands, determined commitment of scientists to develop strategies to effectively manage the issues of the changing climate through carbon sequestration. Carbon sequestration is ought to be a promising solution for reducing atmospheric carbon dioxide, an important greenhouse gas.

All life on planet Earth is carbon centered; hereditary characters are controlled by DNA and RNA, growth by proteins and activities by energy from carbohydrates and fats – all these are carbon compounds. Not only this, but the life also ends as carbon compounds CO₂ or CH₄, depending on aerobic or anaerobic decomposition. Incidentally soil fertility also depends very much on soil organic carbon (SOC). In ancient days, farmers used to apply manure to maintain soil fertility and even now, urea, the nitrogen fertilizer used in the largest amounts, is a carbon compound. All living forms on the Earth including all plant and animal species and their activities are a part of global carbon cycle. The carbon cycle is the biogeochemical cycle by which carbon is exchanged among the biosphere, pedosphere, geosphere, hydrosphere, and atmosphere of the earth.

Carbon dating uses the half-life of Carbon-14 to find the approximate age of an object that is 40,000 years old or younger.

5.1 What is radiocarbon dating ?

Radiocarbon dating is a method of estimating the age of organic material. It was developed right after World War II by Willard F. Libby and coworkers, and it has provided a way to determine the ages of different materials in archeology, geology, geophysics, and other branches of science. Some examples of the types of material that radiocarbon can determine the ages are wood, charcoal, marine and freshwater shell, bone and antler, and peat and organic-bearing sediments. Age determinations can also be obtained from carbonate deposits such as calcite, dissolved carbon dioxide, and carbonates in ocean, lake, and groundwater sources.

4.1 Introduction

Biomass is referred to as an indirect source of solar energy and considered a source of stored chemical energy. Biomass is renewable organic material derived from plants and animals serving as sources of energy. Biomass produced from agricultural sector is big challenges for all over the world due to its improver disposal. Mitigating greenhouse gas emissions and ensuring adequate global food supplies represent two of the last decade’s mostdifficult challenges.Although global food production has benefitted from chemical fertilizers, environmental problems have emerged as a result of their use. Additionally, overuse of fertilizers can result in hardened soil, decreased soil fertility, polluted air and water, and the release of greenhouse gases. There is an urgent need to find an alternative to chemical fertilizers that, ideally, can be sourced in abundant amounts, promotes global food production, enhances CO₂ capture , and does not affect soil health or damage the environment¹. To sustain agricultural productivity, it is crucial to maintain adequate levels of organic matter in the soil to preserve its physical, chemical, and biological integrity. Biochar, a pyrogenic black carbon, may play an important role in improving soil health, resulting in higher crop yield and absorbing atmospheric carbon dioxide. Biochar is the most auspicious straw management measures and have highest carbon abatement and economic profit².

Biochar is produced by heating biomass at high temperatures (300 – 600 °C) in a closed reactor containing no to partial levels of air. Under these conditions, biomass undergoes thermo-chemical conversion into biochar. Because of its numerous potentials uses in agriculture, energy, and the environment, much attention has been given to biochar in both political and academic areas. Biochar can be used in a variety of applications such as energy production, agriculture, carbon sequestration, waste water treatment, and bio-refinery; additionally, biochar provides an alternative strategy for managing organic waste. These advantages have renewed the interest of agricultural researchers in producing biochar from bio-residues and using the product as a soil amendment.

2.1. Origin and distribution

• Queen of spices, native to East Indies/ India, originating in the forests of the Western Ghats in Southern India.

• Also grows in Sri Lanka, Guatemala, Indo China and Tanzania.

• Cultivated in Kerala, Karnataka and Tamil Nadu.

2.2. Economic importance

• Used for flavouring various preparations of food, confectionery, beverages and liquors.

• Used as whole pod, seeds or ground.

• Used in garam masala

• Spice mixture seasons meat and vegetable dishes, and masala chai and Turkish coffee.

• Antioxidant and diuretic properties

• May lower blood pressure.

• May contain cancer-fighting compounds.

• May protect from chronic diseases due to anti-inflammatory effects.

• May help with digestive problems including ulcers.

1.0 INTRODUCTION

Cardamom (Elettaria cardamomum Maton.) acclaimed as the ‘Queen of Spices’ is the true cardamom belonging to the family Zingiberaceae. The cardamom of commerce is the dried ripe fruit and is one of the most important valued spices next only to saffron. It is native of evergreen forests of Western Ghats of South India. Cardamom is a shade loving plant (Pseophyte) thriving well in elevations up to 600-1200 m above MSL under an average annual rainfall of 1500-4000 mm and temperature range of 10-350C. India has been the world’s largest producer of cardamom until 1979-80. Later, Guatemala emerged as world’s premier producer and the exporter of cardamom accounting for about 90 per cent of the global trade. Cardamom is also grown lesser extent in Sri Lanka, Papua New Guinea and Tanzania.

Cardamom thrips: Sciothrips cardamomi: Thripidae

Thysanoptera

This thrips attacks other crops like amomum,  tea, colocasia, grapevine, castor, cotton, ginger and turmeric also. The thrips are minute greyish brown insects with fringed wings. They breed on unopened leaves, spindles, leaf sheath, flower bracts and floral tubes .

English name : Small cardamom, Lesser cardamom, Malabar cardamom
Botanical name : Elettaria cardamomum Maton
Family : Zingiberaceae
Chromosome number : 2n = 48
Centre of origin : Western Ghats of India
The cardamom of commerce is the dried capsule of Elettaria cardamomum Maton., commonly called the “queen of spices.” Crop is as one of the most significant and highly valued spices globally, it rank  after saffron and vanilla in terms of price and trade significance. The name Elettaria originates from the Tamil word elattari, where ela refers to cardamom fruit, and tari means granules or seeds of the fruit. Meanwhile, the term Cardamomum from the Greek word cardamon, which denotes cardamom. Cardamom is one of the oldest known spices, originated in India’s Southern Western Ghats around 5,000 years ago. It was among the first spices, along with cinnamon, to enter the western trade. Indian cardamom is distinctive in the global spice market due to its superior quality. The dried capsules produce essential oil and oleoresin, which contribute to its aroma and therapeutic properties. These qualities are attributed to the essential oil content (ranging from 3-8%) found in both the seed and husk. The primary components of this oil include 1,8-cineole, terpineol, and limonene.

Small cardamom (Elettaria cardamomum Maton), popularly known as the “Queen of spices”, occupies an important position among the foreign exchange earning commodities. It is cultivated on a commercial scale in Sri
Lanka, Guatemala, Tanzania and Papua New Guinea. Guatemala is the largest producer of cardamom in the World. In India, it is confined to the States of Kerala, Karnataka and Tamil Nadu. Among these States, Kerala
accounts for the major portion of production (58.4 %), followed by Karnataka (35.2 %) and Tamil Nadu (6.4 %). In Kerala, Cardamom is mainly grown in the erstwhile Travancore area in Idukki district and it is known as the Cardamom Hill Reserve (CHR). Cardamom is a native of the moist evergreen rain forests of the Western Ghats and is grown extensively in the hilly regions at elevations of 700 to 1300 metres as an under crop in forest lands. Cardamom thrives well within certain maximum and minimum thermal regimes. It is believed that diurnal symmetries in temperature trends, if any, have close links with the changes in cloudiness, humidity, atmospheric circulation pattern, winds and soil moisture. The land use pattern of cardamom tracts has changed to a great extent in recent decades. Crops like coffee, black pepper and areca nut are being cultivated at many locations in place of cardamom. With denudation of forests in many cardamom areas, the ideal cool humid microclimate has been destabilized and adversely affected the productivity of the crop.

The word cardiac arrest (CA) or heart attack is frightening. In animals heart attack does not occur in the manner as it occurs in humans. In humans the main cause of cardiac arrest or heart attack is coronary infarct. The prevalence of cardiac arrest or cardiopulmonary arrest (CPA) or heart attack in animals is relatively very low as coronary infarct is not a common disease in animals.

Key Points

• Cardiac crises can result in deadly outcomes. Prompt and precise diagnosis leads to early symptom alleviation and increased survival.

• Many illnesses qualify as cardiac crises, including thromboembolic disease, cardiac tamponade, arrhythmogenic disease, and congestive heart failure.

Introduction

A cardiovascular emergency is defined as any condition affecting the heart or vasculature that prevents appropriate blood flow, tissue perfusion, or oxygenation. Cardiac emergencies include a wide range of disorders such as arrhythmias, cardiac tamponade/pericardial effusions, and congestive heart failure (CHF).

Cardiac ultrasound is also known as echocardiography and it has a very important place in the diagnosis of cardiac diseases of the humans as well as animals. Echocardiography is an imaging of the heart using ultrasound. The diagnosis of congenital heart diseases, shunts, complex malformations, valvular heart diseases, different cardiomyopathies, endocarditis, pericardial effusion, cor pulmonale and cardiac tumours has been possible by cardiac ultra ultrasound that was otherwise difficult.

Cardiovascular system consists of heart and blood vessels which include both arteries and veins. Blood vessels formation occurs in two stages i.e vasculogenesis and angiogenesis. Splanchnic mesodermal cells lining the yolk sac form clusters, referred to as blood islands. Vasculogenesis, the formation of blood vessels from blood islands of of Pander, commences during the third week of gestation in domestic animals first in yolk sac and later in the allantois.Development of blood vessels involves a complex series of events during which endothelial cells differentiate, proliferate, migrate and become organized into vascular network. Angiogenesis describes budding and sprouting of new vessels from existing vessels. This process a fundamental requirement for embryological development, continues postnatally.

The primary function of cardiovascular system is to maintain blood circulation so that normal exchange of fluid, electrolyte, oxygen, carbon dioxide, nutrient
and excretory and secretory end products can take place between tissue and blood. Failure of circulation to any degree interferes with the transport and
exchange mechanism.

Common Maintenance

 • Clean the exterior surface with a brush or cotton waste and plenty of water or kerosene oil.

 • Lubricate or lubricate the moving or rubbing surfaces of parts as needed.

 • Filter the chemical solution/fuel oil mixture as it is poured into the tanks. Make the caps or lids leak-proof by using gaskets.

 • Flush the equipment with clean water to clean the insides of containers, tubes, and nozzles.

Care and Maintenance of Hand Sprayer & Duster

• Dusters should be made of dry and sieved dust.

 • Grease the duster gear box once a month.

 • Clean the duster after use by removing all dust from the hopper.

 • Oil the sprayer’s cup and bucket washers on a regular basis.

 • After completing the day’s work, cleanse the spray tank discharge lines and nozzles with clean water.

i) Common Maintenance

Clean outer surface with brush or cotton waste by using plenty of water or kerosene oil.

Oil the moving or rubbing surfaces of parts with lubricating oil or grease.

Filter the chemical solution/ fuel oil mixture while pouring into the tanks. Make the caps or lids leak-proof with gaskets.

Flush the equipment with clean water to wash inside parts of containers, tubes and nozzles to be free from chemicals.

Care and Management of Meat-Type Chickens (Broilers)

Broiler Overview

• Broilers are unisex young chickens raised specifically for meat production. They are typically grown to reach a body weight of 2.0 to 2.5 kg within 5 to 6 weeks, consuming 3.0 to 3.5 kg of feed, resulting in a feed conversion ratio of 1.50 to 1.75.

• Broiler meat is flvored for its tenderness, high-quality protein content, low fat and cholesterol levels, superior flavor, and juiciness.

• The broiler production cycle is divided into three phases based on the birds’ physiological and production needs: broiler starter (0-10 days), broiler grower (11-21 days), and broiler finisher (22 days to marketing).

3.1. Introduction 

Calves are the future replacement stock of dairy farm. The raising of calves, an important operation of the dairy farm requires a great deal of managemental skill, application and constant attention. Any negligency results in increased calf mortality, poor growth and development of the calves. So, care of the calves is important for success of the dairy farm.

Care and Management of Commercial Growers (09-20 weeks) Under Deep Litter System

Grower management essentially remains the same as that of chick management (brooding management) except for the additional space required for floor, feeders and waterers to keep with the size of birds. The growers may be reared in separate grower-houses or continued to be reared in brooder-cum-grower houses.

Floor space: 1260 cm² (1.4 ft²) per bird.

Feeder space: 6-8 cm per bird. One linear feeder of 120 cm length and 8 cm depth for 40 growers.

Waterer space: 2 cm per bird; a circular waterer of 36 cm and 8 cm depth of 6 lit. capacity for 50 growers. Growers are to be provided with fresh, cool and potable drinking water at least twice a day. Water requirement is increased during hot days. Care must be made not to spill water on litter.

Lighting management: No artificial lighting is given other than natural day light since they require only 9 hours of light per day.