eChapters

Introduction
Because of their useful uses, porous substances are of scientific interest. Depending on the size of the pores, these solids are categorized as microporous, mesoporous, and macroporous. Microporous solids are defined as having pores that are 2 nm or smaller (Figure 1) (Zheng et al., 2002). Solids that are mesoporous fall between 2 and 50 nm, while those that are macroporous are larger than 50 nm (Zheng et al., 2002).
Over the past 20 years, the synthesis of MOFs has garnered a lot of attention since it may produce a wide range of visually pleasing structures that may also be very useful for applications in other porous material-related domains. Coordination polymers, or MOFs (Figure 2), are a type of crystalline materials that are currently garnering a lot of attention because of their appealing qualities. Metal ions serve as connectors and organic bridging ligands as linkers, forming the compound’s backbone. The ligand’s chemical structure and the connecting metals’ characteristics determine whether MOFs will develop the appropriate architectural, chemical, and physical characteristics (Hu et al., 2004). They are permeable and can form structures in one, two, or three dimensions. Because of their intriguing topologies and potential uses as functional materials for gas purification, gas separation, gas storage, and adsorption (Sculley et al., 2011; Friscic, 2012; Lu et al., 2011; Burnett et al., 2012; Lin et al., 2009), molecular magnets (Kang et al., 2012; Zhang et al., 2012; He et al., 2013; Dang et al., 2010; Feng et al., 2012; Ranocchiari et al., 2011; Sumida et al.,2012), heterogeneous catalysis (Sonnauer et al.,2009; Kreno et al.,2012), luminescence, catalysts, and sensors (Chughtai et al.,2015), MOFs and coordination polymers (CPs) are of great interest to modern inorganic chemistry for their logical designation and synthesis. The potential of metal-organic frameworks as appropriate candidates for the detection of a number of pertinent organic and inorganic analytes, such as biomolecules, ionic species, hazardous compounds, environmental contaminants, etc., has been encouragingly realized. MOFs are among the leaders in the development of materials for realtime sensing applications because of their practical ability to tap various types of photophysical processes, even when they are present simultaneously, as well as their freedom to adjust their electronic characteristics and pore surfaces for

Introduction

In horticulture crops, plant materials has been  propagated through vegetative propagation methods for its superiority in growth as well as yield for centuries. Among vegetative propagation methods, micropropagation is most advance technique which made a significance in the horticultural crops to increase quality and yield. It can produce many plants from a single individual.

Abstract

Packaging plays an important role in the food processing Industry. It makes food more convenient as well as gives the food greater safety assurance from microorganisms, biological and chemical changes such that the packed foods can have longer shelf life. In order to meet the huge demand of processed food with longer shelf life, various methods of preservation and packaging are being used in the food processing industry. Drying and dehydration is one of the method which helps preservation of a perishable commodity against deterioration or spoilage.

1. Introduction
Palladium (Pd), which has the atomic number 46, was discovered in 1803 by the English chemist William Hyde Wollaston. It is a well-known transition metal recognized for its versatile catalytic properties in chemical reactions, material sciences, and various industries. The palladium-catalyzed coupling reactions extend beyond the formation of biaryls. Many carbon–carbon, carbon–nitrogen, and carbon–oxygen bond-forming reactions in organic chemistry are facilitated by palladium salts and catalytic systems derived from palladium. Some notable organic reactions that involve palladium include the Mizoroki-Heck reaction, (Biffis et al., 2018, Koranne et al., 2023, Lee et al., 2021) Suzuki-Miyaura coupling, (Zhang et al., 2023) Negishi reaction, (Haas et al., 2016). Stille coupling, (Cordovilla et al., 2015). Sonogashira coupling, (Chinchilla & Najera, 2007) Tsuji-Trost reactions, (Kvasovs et al., 2023). and Wacker catalytic processes. (Zhang et al., 2023) In this chapter, we will focus on the applications of palladium and its salts in C-N bond-forming reactions.
2. Palladium (Pd)-Catalyzed C–N Bond Formation
Besides copper, palladium metal is considered as the most widely used metal in organic synthesis. The discovery of cross-coupling reactions catalyzed by palladium(0) complexes in the 1970s was a highly important achievement that substantially changed the strategy of organic chemistry. Best applications of the palladium salts are in enantiolective and new C-N bond forming reactions. Stephen L. Buchwald and John F. Hartwig opened up the catalytic scope of palladium in newer methodologies on C–N bond forming reactions during 1990s, (Ruiz- Castillo & Buchwald, 2016) and henceforth, new methodologies of carbocycles, heterocycles, and simple organic compounds have been created in large scales (Rayadurgam et al., 2021). The mechanisms of palladium-catalyzed C-N cross-coupling reactions are critically discussed in numerous high-quality research journals with different theoretical and experimentally proven methods (Beletskaya & Averin, 2021). However, the most acceptable mechanistic pathway to reaction products in these Pd-catalyzed reactions involving palladium is illustrated in Scheme 1. The process begins with the formation of a palladium complex through the reaction of an aryl halide (which can be aliphatic, heteroaryl, or functionalized alkenes/alkynes), a palladium salt, and amino nucleophiles. In the presence of a suitable base, the loosely bonded halide or any leaving groups are eliminated, leading to the formation of a palladium (IV) complex. This complex then undergoes reductive elimination, resulting in stable aminated aryl, heteroaryl, alkyl, or functionalized alkenes/ alkynes. Additionally, a more generalized reaction mechanism is presented in a circular pathway format, highlighting the bonding approaches, rearrangements, intermediate formations, and the final release of target compounds, as depicted in Scheme 1. The involvement of higher valence organo-palladium complexes in such catalytic transformations have been well established (Hickman & Sanford, 2012).

The pineapple, botanically known as Ananas comosus Merr, is the most famous edible member of the Bromeliaceae family. It is native to southern Brazil and is known by a variety of names, including “pina” in Spanish, “abacaxi” in Portuguese, “ananas” in Dutch and French, “nanas” in Southern Asia and the East Indies, “po-lo-mah” in China, “sweet pine” in Jamaica, and merely “pine” in Guatemala (Morton, 1987). After banana and mango, the pineapple is the third most important tropical fruit of the world (Chen et al., 2019; Nath et al., 2019). The pineapple became a major cultural icon of luxury after its introduction to Europe in 17th century. Pineapple has been grown commercially in greenhouses and on many tropical plantations since the 1820s. Furthermore, it is the world’s third-largest tropical fruit producer. Hawaii was a major pineapple producer in the twentieth century, with Costa Rica, Brazil, and the Philippines accounting for nearly a third of global pineapple production. Pineapples grow as a small shrub, with the un-pollinated plant’s individual f lowers fusing to form multiple fruits. The plant is usually propagated from a side shoot or an offset produced at the top of the fruit and it matures in about a year.

Crop Improvement

Pineapple is usually propagated through asexual method by using slips, crowns or suckers. Sexual reproduction in pineapple is barely used due to its self-sterile nature and failure in formation of seeds. Seed set can occur in case of self-fertilization but the seedlings are with low vigour due to inbreeding depression (Robert et al., 2003). Pineapple is heterozygous in nature, on this wise hybridization is possible in this crop. Gametophytic self incompatibility is reported in this crop where pollen tube growth is repressed in the uppermost part of the style. Diploid chromosome number of the crop is 2n=50. The genome size of the crop is estimated to be 526Mb and total genes were anticipated to be around 25,862 in number (Zhang et al., 2014).

ABSTRACT

Plant growth promoting (PGP) bacteria play an immense role in promoting crop growth mainly by direct mechanisms such as N_2-fixation, phosphate solubilization and phytohormone production and indirectly may help to suppress pathogens or contribute to enhance absorption of nutrients leading to increase yields. The N₂fixers are grouped based on their niche adaptation as endophytic nodular symbionts (Rhizobium spp.), free living (Azotobacter spp.), associative symbionts (Azospirillum spp.) and endophytic non-nodular symbionts (Azoarcus and Gluconacetobacter diazotrophicus). In the recent past, phosphate solubilizing and phytohormone synthesizing bacterial communities also gained momentum.

Introduction
A significant challenge in the field of chemistry lies in the application of green methodologies aimed at enhancing the efficiency, cleanliness, and environmental sustainability of chemical processes in alignment with contemporary green chemistry goals. Recent global environmental issues have motivated researchers to create and implement more sustainable chemical practices to reduce the reliance on and generation of harmful toxic materials. The importance of coupling reactions lies in their role as effective and robust techniques for synthesizing key pharmaceutical agents, polymers, and natural products (Colberg, 2022). Crosscoupling reactions are particularly focused on the formation of C-C (carbon-carbon) and C-X (carbon-heteroatom) bonds. For the last three decades, cross-coupling chemistry has been widely utilized to facilitate the development, discovery, & market introduction of innovative types of pharmaceuticals and agrochemicals (Carsten Bolm, 2012).
In cross-coupling polymer reactions, two reagents equipped with activating functional groups engage with a specific metal catalyst, culminating in creating a new covalent bond. The loss of the activating groups carries out this process. In the 1940s, Kharasch and Fields first discovered the cross-coupling reactions using Grignards reagent with aryl or alkyl halides in the presence of metal halides such as NiCl2, CoCl2, FeCl3, CrCl2, or CuCl2 as a suitable catalyst. (Wu, 2021). Cross-coupling reactions have tremendous valuable applications in many vital areas, such as powerful tools for synthesizing essential pharmaceuticals, natural products, polymers, and agrochemicals. Furthermore, cross-coupling reactions have facilitated the synthesis of important molecules with industrial relevance, such as losartan, which is produced through a late-stage Suzuki cross-coupling reaction. Additionally, these reactions have created previously unattainable molecules, as the Suzuki coupling reaction ranks as the second most prevalent reaction in medicinal chemistry (Kotha, 2022). The predominance of sp2-hybridized carbon nucleophiles and electrophiles in most cross-coupling reactions has presented challenges in the pharmaceutical sector, as the “flattening” of many pharmaceutical targets results in a reduced number of specific drugs and an increase in off-target interactions. Nevertheless, crosscoupling reactions exemplify the capacity of robust synthetic methodologies to profoundly influence and inspire molecular design within the chemical industry. Recent trends in advances with the cross-coupling reactions are enabling the development of new reaction mechanisms, the synthesis of new compounds & development of new catalysts, and reactions that proceed under milder conditions.

Introduction
   
The major land mark in the primary food production is the Green revolution during sixties, eventually leading the country to self-sufficiency in food grains. At present, agriculture and allied sector contributes 22% of GDP in India. Total arable area in India is 184 million hectares contributing a total food grain production of 210.01 million tonnes. Horticultural crops including fruits, vegetables, flowers, plantation crops, spices and medicinal and aromatic plants have emerged as a major economic activity in India. Horticulture crops cover over 20.7  million hectares of area, which is approximately 11.25%  of the total gross cropped area of the country and contributes 18-20% of the gross value of India’s agricultural output. India is the world’s second largest fruit and vegetable producing country accounting for 81.29 million tonnes of fruit and 162.2 million tonnes of vegetables (Annon., 2013).

Introduction

• The green revolution of the 1960s and 1970s ended chronic food deficits and while cereals still command the attention of policy makers, fruit production has surged impressively, making India the second largest global producer behind China.

• Annual growth in horticulture has seen fruit production grow at faster rate and constitute the larger segment of agriculture. • No doubt, there has been manifold increase in area, production and productivity but when we compare the productivity of various major fruit crops with other developed countries, our productivity is very low.

• This may be mainly attributed by non-availability of quality planting material and seeds, existence of old unproductive seedling orchards, small and unirrigated land holdings, use of inferior genetic stocks/ varieties/hybrids, poor management and non-adoption of package of practices, high incidence of pest and diseases, heavy pre and post harvest losses and lack of trained human resource.

• To meet increasing demand the productivity per unit area per unit time and per unit investment has to be increased from limited land resources, where production and supply of quality planting material of elite varieties is one such important factor that can bring tremendous improvement in production, productivity and higher economic returns to farmers.

• This may be mainly attributed by non-availability of quality planting material and seeds, existence of old unproductive seedling orchards, small and unirrigated land holdings, use of inferior genetic stocks/ varieties/hybrids, poor management and non-adoption of package of practices, high incidence of pest and diseases, heavy pre and post harvest losses and lack of trained human resource.

Abstract

The structure and function of proteins involved in plant-microbe interactions is investigated through large-scale proteomics technology in a complex biological sample. Since the whole genome sequence are now available for several plant species and microbes, proteomics study has became easier, accurate and huge amount of data can be generated during plant-microbe interactions. Proteomics approaches are highly important and relevant in many studies and showed that only genomics approaches is not sufficient as much significant information are lost as the proteins and not the genes coding them are final product which is responsible for the observed phenotype.

Abstract

Production of healthy and vigorous seedlings is the foremost crucial step for raising a successful vegetable crop. Now a days seedlings are raised in trays under controlled atmospheric conditions called as transplants. As soil substitutes, artificial media made of perlite, vermiculite and peat moss are commercially available. A good rooting medium should be light weight, well drained, well aerated, and soilless with or without starter solution or added nutrients and with good water and nutrient holding capacity. The media should be sterilized before use. Selection of trays for cell shape, size and number depends on the type and nature of crop. Most of the vegetable transplants are now being produced in hardened plastic or polystyrene containers. Only good quality certified seeds should be used in media filled trays after priming, pelleting, coating or other seed treatments as per the crop requirement. Germination chambers as insulated rooms to maintain suitable conditions over large period of time may also be used. Generally vegetable crops need fertilizer application after expansion of first true leaf. Young seedlings are managed carefully to avoid any toxicity while taking care of their nutrient management. Water requirement also depends on growth stage and variation in weather conditions. Other seedling management practices include shading, thinning, weeding, disease/pest control, hardening off and subsequent transplanting. Containerized greenhouse plants can be grown using the conventional “rail” (or rack) system or the “float” system. Shipping factors such as mechanical injury, environmental conditions and length of storage affect plant vigour and establishments. IPM (integrated pest management) offers a practical way to effectively manage pests on vegetable bedding and transplants.

Introduction to Research

Research is an inseparable part of human knowledge. Its role in human life is as precious as that of salt in a vegetable. The life would lose its taste without research exactly in the same manner as a vegetable without salt. The modern academics just cannot stand and meet the aspirations of a matured society, if it does not provide for research and investigation. “The obvious function of research is to add new knowledge to the existing store. but its power for cleansing our minds of clinches and removing the rubbish of inapplicable theory is equally notable. Scientific research is a cumulative process. It is also a projective process, especially in the social sciences. Understanding can be (advanced) not only by gains in knowledge but also by discarding outworn assumptions”.

Introduction

Stored-product insects are serious pests of dried, stored, durable agricultural commodities and of many value-added food products and non-food derivatives of agricultural products worldwide. Various estimates on post harvest losses across the country revealed that there is loss of 2–12 per cent during storage exclusively by insects. Almost all the insect species may destroy 10.0 -15.0 per cent of grain and contaminate the rest with undesirable odour. The major loss is done by two internal feeders i.e. rice weevil and grain borer, which are major pests of rice, wheat and millets (Champ and Dyte, 1977). They also help in transportation of fungi (Sinha and Sinha, 1990). The losses during storage are quantity losses and quality losses. Quantity losses occur when insects, rodents, mites, birds and microorganisms, consume the grain. Infestation causes reduction in seed germination, increase in moisture, free fatty acid levels and decrease in pH and protein contents etc. resulting in total quality loss. Quality losses affect the economic value of the food grains fetching low prices to farmers (Das et al., 2013).

1. Introduction
Soils stand out as an intricate and diverse ecosystem on our planet. Their significance extends beyond supplying 98.8% of the world’s food, encompassing a wide array of essential services such as carbon storage, regulation of greenhouse gas emissions, flood prevention, and offering support to burgeoning urban populations. However, it is crucial to recognize that soil is a finite natural resource. The unprecedented growth of the human population, escalating from 250 million in the year 1000 to 6.1 billion in 2000, with projections reaching 9.8 billion by 2050, along with the intensified practices of agricultural production, is exerting immense pressure on the sustainability of soils.
For long-term sustenance the concept of ‘Soil quality’ was propagated around three decades back from now in the United States of America, and further expanded to the scientists of European and Asian countries. Soil health and soil quality are two interweaving term that signifies the potentiality or capacity of soil towards mankind. These two words complement each other in such a way that one term automatically comes with another to determine both aspects i.e. agricultural sustainability and environmental quality in terms of plant, animal and human health (Haberern, 1992; Doran, 2002). Idowu et al. (2007) remarked that the term “soil quality” is more favoured by scientists, whereas “soil health” is a term favoured by farmers as it connotes a holistic approach to soil management. The inception and application of soil quality term was officially approved by Soil Science Society of America (SSSA). They defined soil quality as “The capacity of a specific kind of soil to function within natural or managed ecosystem boundaries, to sustain biological productivity, maintain environmental quality, and promote plant and animal health” as illustrated by Karlen et al. (1997). It is a complex composition of certain properties associated with physical (texture, bulk density, water holding capacity, infiltration capacity etc.), chemical (pH, EC, organic carbon, extractable macronutrient and micronutrient etc.) and biological (microbial activity and related parameters) conditions of soil (Prabha et al., 2020). There are primarily two key methodologies for assessing soil quality: the descriptive approach, which focuses on characterizing various aspects or attributes of soil quality, and the Indicative approach, which aims to identify the ability or capacity of an attribute in a desired manner. The comprehensive process of developing a soil quality index is guided by the 3-Is framework: the Identification of indicators, Interpretation, and Integration of selected soil quality indicators. It is important to note that the specific set of indicators utilized can vary between different soils, diverse agroecosystems, and from one crop to another. Additionally, climatic conditions and other abiotic factors may also significantly influence the assessment of soil quality.
The USDA has categorized soil quality indicators into four primary groups: visual, physical, chemical, and biological indicators. However, in the current context, the dominant indicators are physical, chemical, and biological. For a systematic assessment of soil quality, it is crucial to collect individual parameters and integrate them meaningfully. Consequently, integrated soil quality indicators

Introduction

Humans and grass are inextricably linked to each other. The oldest unequivocal grass fossils are 25 million years old, originating in the Oligocene epoch (Thomasson, 1987). Grasses are one of the first permanent vegetation to reappear after disasters, such as volcanic activity, extended droughts, floods, fires, explosions, abandoned urban ghettos, and battlefields. In the past, landscaping was universally regarded as an extravagance for the affluent or as a decorative for mediocre and average structural design. Today, growers offer hundreds of selections for landscape designers who envision their backyard canvases swept with fulsome grasses. Countries are capitalizing on this industry at a furious pace and turfgrass research can be circuitously, the next moolah machine for enhancing lifestyle, real estate values and tourism revenues.

This chapter introduces emerging technologies that are transforming wool production, evaluation and processing. It examines artificial intelligence, machine learning, computer vision, precision sheep farming, genomic selection, automated grading, robotic shearing, nanotechnology, enzyme-based processing and sustainable textile technologies. Digital traceability and blockchain-style systems are also considered. The chapter highlights the importance of validated datasets, objective measurement and responsible technology adoption and identifies opportunities for improving the quality and value of Indian wool while supporting sustainability and pastoral livelihoods.

1. Introduction

Aquaculture has played a sustaining role in global food systems by providing expanded food production and livelihood benefits with relatively minimal environmental harm. (Igwegbe et al., 2021). To emphasize the importance of the aquaculture sector, the Food and Agriculture Organization of the United Nations (2020) stated that, global aquaculture production increased by 5.27%, hitting a record-breaking productivity value of 114.5 million tonnes between 1990 and 2018 (Pauly and Zeller 2017). Aquaculture has profited from developments in science and technology in nearly every aspect such as a greater diversity of species, nutritional regimes, production techniques, organizational frameworks, and marketing compared to other agricultural industries (FAO 2020). As an illustration, enhanced reproductive technologies have made it possible for individuals to achieve closed life cycles of aquaculture species, resulting in the diversification of species in the aquaculture sector (Weber and Lee 2014). The utilization of live feeds in hatcheries, such as microalgae, artemia, rotifers, brine shrimp, and various copepods, has eliminated the obstacle in breeding a variety of marine organisms (Conceição et al., 2010).

Approximately 60 varieties of fish species have shown significant improvements in features of economic value through selective breeding assisted by quantitative genetics (Zuma 2022). River shrimps (Levy et al., 2017), Yellow catfish (Roskoski et al., 1975), and mono-sex tilapias (Mair et al., 1997) all have been produced owing to sex reversal technology and DNA markers linked to sex determination. The risk of inbreeding has decreased due to intrafamily screening being made possible by molecular parentage assignment (Xu et al., 2020). Selection for characteristics, particularly are governed by single genes and a small number of significant genes (Fuji et al., 2007; Houston et al., 2008) has been made possible by QTL (quantitative trait locus mapping) and marker-assisted selection (MAS) (Yue 2014). Enhanced feed formulations dependent on the dietary needs for every fish species have enhanced feed conversion rate (FCR) and decreased feed cost (Tacon and Metian 2015). Innovations for disease control (Kelly and Renukdas 2020) have minimized the prevalence of ailments in aquaculture.

Introduction 
Over the past few decades, magnetic nanoparticles (MNPs) have been showing great importance in the field of organic synthetic reactions, catalysis, sensors, biomedicines, environment rehabilitation, etc. (Gawande, M. B. et al., 2013; Del Rio, M. et al., 2022). Numerous research teams have recognized the significance of solid support materials for the creation of environmentally acceptable nano catalysts with high catalytic activity in light of the infinite advantages of MNPs (Sharma, R. K. et al., 2016; Gawande, M. B. et al., 2013; Deng, J. et al., 2011; Nasrollahzadeh, M. et al., 2015; Hudson, R. et al., 2014; Payra, S. et al., 2017; Chng, L. L. et al., 2013; Parandhaman, T. et al., 2017; Zhang, F. et al., 2014; Pourjavadi, A. et al., 2012). Heterogeneous catalysts in organic chemistry are solid catalysts that, while remaining in a distinct phase (usually solid) from the reactants (generally liquids or gasses), promote chemical reactions without being consumed in the process. These catalysts, which have multiple benefits such as ease of separation, recyclability, and selective reactivity, are essential in a variety of industrial processes and laboratory reactions (Lattuada, M. et al., 2007; Jiang, K. et al., 2011). The standard formula for ferrite nanoparticles is MFe2O4, where M is usually divalent metal ion like copper (Cu), zinc (Zn), or nickel (Ni), and iron (Fe) is the common metal (Kazemi, M. et al., 2018). These nanoparticles work very well as heterogeneous catalysts in a variety of chemical reactions because of their special magnetic and electrical characteristics.Because of its special qualities as a catalyst in a variety of processes, copper ferrite (CuFeO4), a mixed-metal oxide, has drawn interest in organic chemistry (Kharisov, B. I. et al., 2019; Zhu, J. et al., 2014; Vannucci, A. K. et al., 2012). It is a spinel-type ferrite that can catalyse a variety of organic transformations because it combines iron and copper in a stable, highly active structure. With benefits including high stability, reusability, and low toxicity, these catalysts are frequently employed in processes like oxidation, coupling, and reduction (Taghavi Fardood, S. et al., 2018). The Figure 1 represents schematic diagram of a reaction where the ferrite nanoparticles as catalyst have been recovered with the aid of an external magnet after the formation of reaction product.

Introduction 
Over the past few decades, magnetic nanoparticles (MNPs) have been showing great importance in the field of organic synthetic reactions, catalysis, sensors, biomedicines, environment rehabilitation, etc. (Gawande, M. B. et al., 2013; Del Rio, M. et al., 2022). Numerous research teams have recognized the significance of solid support materials for the creation of environmentally acceptable nano catalysts with high catalytic activity in light of the infinite advantages of MNPs (Sharma, R. K. et al., 2016; Gawande, M. B. et al., 2013; Deng, J. et al., 2011; Nasrollahzadeh, M. et al., 2015; Hudson, R. et al., 2014; Payra, S. et al., 2017; Chng, L. L. et al., 2013; Parandhaman, T. et al., 2017; Zhang, F. et al., 2014; Pourjavadi, A. et al., 2012). Heterogeneous catalysts in organic chemistry are solid catalysts that, while remaining in a distinct phase (usually solid) from the reactants (generally liquids or gasses), promote chemical reactions without being consumed in the process. These catalysts, which have multiple benefits such as ease of separation, recyclability, and selective reactivity, are essential in a variety of industrial processes and laboratory reactions (Lattuada, M. et al., 2007; Jiang, K. et al., 2011). The standard formula for ferrite nanoparticles is MFe2O4, where M is usually divalent metal ion like copper (Cu), zinc (Zn), or nickel (Ni), and iron (Fe) is the common metal (Kazemi, M. et al., 2018). These nanoparticles work very well as heterogeneous catalysts in a variety of chemical reactions because of their special magnetic and electrical characteristics.Because of its special qualities as a catalyst in a variety of processes, copper ferrite (CuFeO4), a mixed-metal oxide, has drawn interest in organic chemistry (Kharisov, B. I. et al., 2019; Zhu, J. et al., 2014; Vannucci, A. K. et al., 2012). It is a spinel-type ferrite that can catalyse a variety of organic transformations because it combines iron and copper in a stable, highly active structure. With benefits including high stability, reusability, and low toxicity, these catalysts are frequently employed in processes like oxidation, coupling, and reduction (Taghavi Fardood, S. et al., 2018). The Figure 1 represents schematic diagram of a reaction where the ferrite nanoparticles as catalyst have been recovered with the aid of an external magnet after the formation of reaction product.

Introduction

One of the remarkable advancements in veterinary medicine recently is the application of interventional cardiology techniques to treat various congenital heart diseases. In dogs and cats, congenital heart diseases can be treated much more easily and with fewer complications using minimally invasive interventional approaches, rather than through traditional open-heart surgery. Among congenital heart diseases, treatment options are available for conditions such as PDA (Patent Ductus Arteriosus), AS (Aortic Stenosis), PS (Pulmonic Stenosis), VSD (Ventricular Septal Defect), ASD (Atrial Septal Defect), extrahepatic shunt, and stem cell applications. These diseases often cannot be significantly improved by medical treatment alone, making the use of the aforementioned interventional techniques essential for effective management.