eChapters

The native and applied organic matter play an important role in terms of nutrient adsorption , nutrient mobility and microbial habitat on soil. The dominant ions present in soil under a particular agro-ecological situation may or may not be available to the growing plants due to the presence of organic matter. The binding energy and the stability of the organo-metal complexation would play an important role in availability of nutrients to the plants. The organo-metal complexation reaction depends on the nature of the ionic species (ionic/non ionic) present in soil. The organic fractions (Humic acid/Fulvic acid) react with metal ions present in soil to form complexes which may be stable or unstable depending upon the molecular arrangement and degree of coiling of humic/fulvic substances. The surface charge density on clay and soil pH also play an important role to determine the order of stability of different nutrients (macro/micro) in soil.

Understanding the chemistry of submerged soil in the field of Geology, Pedology, Agriculture and other allied sectors draws attention to the research on characteristic changes in soil under submergence. It has been reported that, about 72% of the earth’s surface is covered by submerged soils or sediments . Rice plants have unique adaptation capability to grow under submerged soil and in any type of soil (acid/alkaline) condition or land situation (upland/lowland). The knowledge on changes of important physical, chemical and biological properties under submergence have important role to play in understanding the mechanisms of availability of nutrients to the plants and sustainability of the crop during its growing period.

9.0 Submerged Soil

The soils which are saturated with water for a longer period of time in a year to make the soil a distinctive gley horizons resulting from oxidation-reduction processes are called submerged soil. About 72% of the earth’s surface is covered with soil –submergence or sediments.

Nutrient adsorption in soil is one of the important phenomena in terms of nutrient availability to plants. Due to the nutrient fixation of the added nutrients supplied through fertilizers or manures may result the increase in cost of production due to the non-availability of the added nutrients at the optimum level to the plants. Hence, management options are required to release the sorbed nutrients from soil for better availability to the plants. The ion-fixation is driven by physico-chemical and biological processes and varies under agro ecological situations. The chemistry of ion fixation in the form of specific or non-specific adsorption on soil colloids will help understanding the bonding and adsorption reactions of ions in the soil.

8.0 What is fixation?

Fixation of plant nutrients in soil may be defined as the process, where readily soluble plant nutrients are transformed into less soluble forms by physical or chemical reaction with organic or inorganic compounds and thus restricting the mobility of ions in soil that leads to the decrease in availability to the plants. There are two kinds of fixation in general, viz; cation (N, K, Fe, Mn, Cu, Zn, Ca,Mg etc.) and anion (P, B, Mo etc.) in soils. The fixation of ions in soil is governed by important physical and chemical parameters of soil based on which the available pools of nutrients for plants may be determined.

The soil acidity and alkalinity are major driving forces in regard to the mobility of plant nutrients from soil to plants. The extreme acidity or alkalinity cause damage to the crops and thus yield is affected. Correction of soil acidity or alkalinity depend upon the pH of the soil and its previous management options. Application of fertilizer in soil may be one of the factors affecting soil conditions. Exchangeable and soluble iron and aluminium ions and their hydroxy ion species may contribute hydrolysis to release H+ ions to the soil solution. The soluble salts of carbonate and bicarbonates also develop salinity in soils.

7.0 Soil reactions

Soil reaction is an indication of the acidity or alkalinity of soil and is measured in pH . The pH scale ranges from 0 to 14 with pH 7 as the neutral point. When the amount of active hydrogen ions in the soil solution increases the soil pH decreases and thus becoming more acidic in reaction. One of the outstanding physiological characteristics of the soil solution is its reaction. Soil reaction can influence the physico-chemical properties of soil which can regulate the growth and activity of plant and soil organisms associated with it.

The exchange of ions (cations or anions) are important phenomena in soil for the growth and nutrition of the crops. The oppositely charged ions are being adsorbed by the clay colloids which are subjected to be released or exchanged reversibly from the soil solution. The participating ions in the exchange process are called exchangeable or counter ions. The activity of ions depends on the pH of the soil. Hence, factors like, soil texture, organic matter, concentration of ions could govern the ion exchange phenomena in soil.

6.0 Ion Exchange

Ion exchange is a reversible process where exchange of ions are possible between the two electrolytes or between an electrolyte solution and a complex. The ion exchange processes help in purification, separation, and decontamination of aqueous and other ion-containing solutions. The ion-exchange resins (functionalized porous or gel polymer), zeolites, montmorillonite, clay and soil humus are considered as typical ion exchangers which are either cation exchangers [exchanging positively charged ions (cations)], or anion exchangers [which can exchange negatively charged ions (anions)].

Soil colloidal substances are composed of very fine particles (< 0.002 mm diameter) that undergoes two phase system in a heterogenous manner, where, one phase (disperse phase) is disperse in a fine state of subdivision in another medium called dispersion medium. The soil colloidal properties are affected by the physico-chemical and biological parameters of soils. The availability of plant nutrients are governed mostly by the surface charge characteristics of clay colloids.

5.0 Soil Colloids

Soil colloids being one of the active constituents determine the physical and chemical properties of the soil with the diameter ranging from 1 μm to 2 μm. The origin of the particles may be organic and inorganic constituents.

4.0 Soil organic Matter

The soil organic matter (SOM) is a storehouse of multi-nutrient elements, composed mainly of carbon, hydrogen and oxygen and small amounts of other elements like nitrogen, phosphorous, sulphur, potassium, calcium , magnesium and organic residues coming out from the decomposed plant or animal products (Figure 4.1). The SOM may have the recently incorporated materials or age-old decomposed materials or with living flora or fauna in the organic matrix. Soil organic matter is one of the important components determining soil quality indices and also for enriching the fertility status of soil for production maximization. The nutrient retention capacity , water holding capacity, degradation of pollutant elements, carbon sequestration, soil structure and aggregate stability are affected by the presence of SOM.

The plant can absorb more than sixty elements as revealed from the plant tissue analysis, still a few elements is considered essential for the growth and nutrition of the plants. The deficiency of any one of the essential elements can stop completing the life cycle of the plants which is reflected on the yield of the crop. The growth of the plant which is expressed in terms of dry weight, length ,diameter etc. are interlinked with the plant available nutrients of soils.

3.1 Essential Nutrients

The essential elements are those elements which are required for growth and nutrition of the plants. There are 17 elements known to be essential nutrients for plants. The essential elements are classified as micro and macronutrients depending upon the requirement of the crop. Among the naturally occurring elements, eighteen elements are considered essential to plants. These are: C, H, O, N, P, K, Ca, Mg, S, Fe, Mn, Zn, Cu, B, Mo, Cl, Ni, Co. The elements which are found in different sources are required to be in available forms (Table 3.1) for growth and nutrition of the plants.

Soil is one of the major platforms on which life sustains. Soil, the product of weathering, covers the earth’s surface. Soil is the medium of plant growth and thus it requires proper attention for better crop yield. The land is the constituent of soil, vegetation, physico-chemical and biological attributes affecting its usages. The soil may act as a sink or source for the elements and other materials. Hence, it requires to understand the various components to facilitate management options for improving the fertility status of soil.

2.0 Soil

The soil is a natural dynamic body on which plant grows. It is a complex mixtures of minerals, water, air, organic matter and microorganisms. Besides, there exist an unconsolidated mineral or organic material on the surface of the earth and thus becomes a natural medium for the growth and nutrition of the plants.

The knowledge on fundamental principle of chemistry is important to understand and examine the mechanisms of reactions to form products. The chemistry of soil processes will also help understanding the correlation between the basic and applied sciences for achieving the sustainable ecosystem in the environment. The formation and stability of bonds, thermodynamic principles, radioactivity, coordination number etc. are essential to solve the on-going interactions in nature. The structure of atomic models, valence and equivalent weight, creating elementary particles, quarks, neutrinos, bosons are some of the important arena where fundamental study and research can be explored for the basic and strategic ideas. Hence, it is very much essential to apprehend the concept of physical chemistry, soil chemistry and geochemistry to correlate with the definitions of chemistry for understanding the source/sink properties of soils for nutrient adsorption and release characteristics.

Introduction

Before start of this chapter some pertinent questions need to be answered. What are different agro ecology and what are the problem soils. Since dawn of agriculture in early 2000 B.C. man has been doing agriculture as subsistence farming to cater the needs for his own consumption. Later on as the population increased, the availability of land per pearson reduced and further the commercialization of agriculture after world war II, particularly in industrialized nation, compelled farmers to increase productivity per unit area. The green revolution involving higher fertilizer uses, more use of agrochemicals together with evolvement of improved crop varieties in later part of twentieth century played vital role in producing higher grain production resulting the global production triplet in contrast to merely increase in total global cultivated area to the extent of 10%.

The catastrophe of green revolution was realized in later years when reports of soil health degradation started appearing. Intensified agriculture characterized by excessive use of fertilizers, agrochemicals and unsupportable level of over exploitation of natural resources led to serious degradation of ecosystem. Thus management of agroecosystem has reached to a crossroad with serious pressure to increase productivity simultaneously holding the soil health with prime concern for future generation. Thus the soil heath under different agroecosystem are posing problem as the soil productivity has not reached to plateau level but has started reducing year after year. Thus such soils are becoming problem which need special attention to bring them back to support higher crop production.

Introduction

Land capability classification is one of the very important issues in terms of sustainable land use. Land is the most valuable natural resource which needs to be harnessed according to its potential. Land use planning and management is a known strategy for achieving sustainable development. A properly prepared land use plan based on sound scientific and technical procedures, and land utilization strategies can summarize rationally the future demands. This accompanied by a strong planning process, where communities and various stakeholders are involved, can strengthen the decision making process on allocation and utilization of land resources. Land capability is referred as suitability of the land based on inherent characteristics of the soil associated land features, and climatic conditions that limit their safe use under agriculture, forestry etc. Land capability classification is a system of grouping soils primarily on the basis of their capability to produce common cultivated crops and pasture plants without deteriorating over a long period of time. The capability classification is one of a number of interpretive groupings of soils made primarily for agricultural purposes, mainly based on the inherent soil characteristics, external land features and climatic factors that limit the use of land for agricultural purposes. The land capability is governed by the different land attributes such as the type of soil, its depth and texture, underlying geology, topography, hydrology, etc. It also includes soil irrigation classes and ground water table position to decide overall suitability of lands for sustained use under irrigation. The classification points out automatically the possibilities and limitations of the climate and soil for each crop and type of agriculture.

Introduction

Soil pollution is anything that causes contamination of soil and degrades the soil quality. It occurs when the pollutants causing the pollution decrease the quality of the soil and convert the soil inhabitable for micro and macro organisms living in the soil. Soil pollution can occur either because of human activities and/or natural processes. However, mainly it is due to human activities. The soil contamination can occur due to the presence of chemicals such as ammonia, pesticides, lead, herbicides, mercury, nitrate, naphthalene, petroleum hydrocarbons, etc. in an excess amount.

Soils can be polluted with several organic and inorganic pollutants. Organic pollutants contain hazardous persistent organic compounds viz. polychlorinated dibenzofurans (PCDFs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzodioxins (PCDDs), polychlorinated biphenyls (PCBs), polychlorinated naphthalines (PCNs) and other persistent organic compounds. Inorganic pollutants contain heavy metals like lead (Pb), cadmium (Cd), mercury (Hg), zinc (Zn), copper (Cu), arsenic (As) and nickel (Ni) as well as some radioactive compounds or radionuclides. The major sources of soil pollutants are anthropogenic. It contains mainly two sources, point and diffuse; the point sources contains industrial wastes, municipal wastes, domestic wastes, medical wastes, agrochemicals, agricultural wastes, composts and sludges and nuclear wastes. Organic and inorganic soil pollutants can be toxic for plants, animals soil organisms and others. Some compound of the soil pollutants enter into the food chain and can adversely affect on human health. Soil pollutants can be also transferred to surrounding air and water through leaching, volatilization, runoff and dust storms. Quality of air and water adversely affected can be degraded. Thus, remediation of polluted soils has become an awful necessity in many areas of the world.

Introduction

The term multipurpose trees (MPT) refers to all woody perennials that are grown to provide more than one significant function (shelter shade, land sustainability) of the land use system they implement. More emphasis is given to trees which are indigenous in nature and have the capability to fix atmospheric nitrogen. All trees are said to be multipurpose. The term “multipurpose” as applied to trees for agroforestry refers to their use for more than one service or production function in an agroforestry system (Burley and Wood, 1991).

Multipurpose trees species (MPT) are grown to provide more than one significant crop of function or form. These may include fuel wood, fiber, fodder, flower, fruit, fertilizer (6F) timber, industrial purpose, nitrogen f ixing, soil conservation, soil protection and rehabilitation, shade and nurse trees, medicine, windbreak, shelterbelts, live fences, aesthetic or recreational purpose, shown in Table 16.1.

Remote sensing

It is the art and science of obtaining information about an object, area, or phenomenon through the analysis of data acquired by a device without being in physical contact. Remote sensing technology involves acquiring information about the earth’s surface and atmosphere, using satellite based sensor, interpretation, of spectral measurements and characterization of land resources and environmental phenomena.

The information recorded by this technology is not visible to humankind. It provides synoptic view as well as three-dimensional view of larger area. And data are received periodically and helps in monitoring the changes at short intervals. The data recording is unbiased one which is stored permanently and can be used in many applications. Thus, processing of data is faster than the conventional interpretation method. Thus, soil resources data collected by extensive ground surveys and soil maps were prepared using cartographic techniques these were tedious, costly and time consuming. Multi date, multi spectral and real time satellite data provide a reliable accurate tool for assessment and repeat coverage of the same area at the same local time for monitoring soil resources (Joshi, 2013). In remote sensing, reflected energy from the object is recorded by a sensor. The information about the object is obtained through the analysis of reflected rays. Three energy interactions occurs when electromagnetic energy falls on any surface feature i.e., reflection, absorption and transmission.

Introduction

One of the most common concerns in irrigated agriculture is regarding water quality or salinity. Out of the ground water surveyed in different Indian States, as much as 84% is rated either saline or alkaline (Minhas 1996). Salinity management is very important for using saline water in irrigation safely. This requires an understanding of how salts affect soil as well as plants, of how hydrogeologic processes affect salt accumulation, and also of how cropping and irrigation activities affect soil and water salinity.

The objectives of management practices for getting optimal crop production with saline irrigation water include the prevention of salt build-up in soil which limit the productivity of soils and the control of salt balances in the soil-water system, as well as minimising the damaging effects of salinity on crop growth (Meiri and Plaut 1985). Amongst the various soil, water, and crop management options available, there is usually no single way to achieve safe use of saline water in irrigation but many different approaches and practices can be combined into satisfactory irrigation systems using saline water. The appropriate combination depends upon edaphic, hydrogeologic, climatic factors as well as social and economic condition of the farmer. Several practices interact with each other, and should be considered in an integrated manner, along with climatic and human factors. Because of the climate, the basic principles of saline water management need some adaptation, e.g. providing for a leaching requirement is not appropriate when the growing season for post-monsoon winter crops starts with a surface-leached soil profile, because it would increase the salt load. High salinities during the initial stages of growth are particularly harmful. Recommendations for effective management of irrigation water salinity depend upon local soil properties, climate, and water quality; options of crops and rotations; and irrigation and farm management capabilities

Introduction

Irrigated agriculture is dependent on an adequate water supply of usable quality. The water quality used for irrigation is essential for the yield of crops, maintenance of soil productivity, and protection of the environment as well. The quality of irrigation water is defined with respect to its effect on plant growth, soil properties, soil biological equilibrium, and irrigation technology. Conceptually, water quality refers to the characteristics of a water supply that will influence its suitability for a specific use, i.e. how well the quality meets the needs of the user. Specific uses have different quality needs and one water supply is considered more acceptable (of better quality) if it produces better results or causes fewer problems than an alternative water supply. For example, good quality river water which can be used successfully for irrigation may be unacceptable for municipal use without treatment to remove its sediment load. Similarly, snowmelt water of excellent quality for municipal use may be too corrosive for industrial use without treatment to reduce its corrosion potential.

Introduction

Black cotton soils are formed by the solidification of molten magma; it covers a large area of the Deccan plateau. The depth of this soil is very high in the lower part of the Krishna – Godavari basin. The clay fraction is very high which is responsible for the heavy waterlogging in the area of heavy rainfall and become more vulnerable to soil erosion. The fine fraction of soil not allows draining out through the soil profile and at the same time the rate of evaporation is low. During summer soils suffer from moisture stress and it becomes very hard but at the same time during the rainy season moisture content very high. this imposes severe constraints on conventional agriculture use as a result most of the land remains fallow and subjected to soil erosion due to heavy rain. The nutrient status of the soil is quite good in Vertisol but these constraints limit crop production. To manage black cotton soil for crop production it is advisable to use animal-powered devices for surface soil drainage, Counter cultivation, adoption of a new cropping system will be helpful for better crop production.

Introduction

Desert soils are the soils of arid regions that remain dry for most part of the year and support sparse xerophytes. The amount of water received by precipitation is far less than what is lost by evapotranspiration. Most deserts receive an average precipitation of less than 400 mm. Because of extreme imbalance between evapotranspiration and precipitation, many desert soils contain salts.

Distribution

Deserts occupy about one-third of the areas of Africa and Australia, 11% of Asia and about 8% of the Americas (Boul et al. 1997). Desert soils include both cold and hot desert. In India, desert soils occur in three agro-ecological regions (AER). The cold arid desert of extreme north (Leh, Ladakh region of Jammu & Kashmir ), the hot arid desert of north western India (Rajasthan, southern parts of Haryana and Punjab and northern parts of Gujarat) and the tropical arid desert of the Deccan plateau in South India represents AER 1, 2 and 3, respectively. The three different desert regions in India have characteristic climatic and soil conditions.

Introduction

Calcareous soils are those that contain high levels of calcium carbonate (CaCO3 ) that affects soil properties related to plant growth, such as soil water relations and the availability of plant nutrients (Elgabaly, 1973), and give effervescence visibly releasing CO2 gas when treated with dilute 0.1 N hydrochloric acid. The pH of calcareous soil is > 7.0 and also regarded as an alkaline (basic) soil.

Calcareous soils have often more than 15% CaCO3 in the soil that may occur in various forms (powdery, nodules, crusts etc.). Soils with high CaCO3 belong to the Calcisols and related calcic subgroups of other soils. They are relatively widespread in the drier areas of the earth. They occupy >30% of the earth’s surface, and their CaCO3 content varies from just detectable up to 95% (Marschner, 1995).

Formation of calcareous soils

Calcareous soils occur naturally in arid and semi-arid regions because of relatively little leaching. They also occur in humid and semi-humid zones if their parent material is rich in CaCO3 , such as limestone, shells or calcareous glacial tills, and the parent material is relatively young and has undergone little weathering. Some soils that develop from calcareous parent material can be calcareous throughout their profile. This will generally occur in the arid regions where precipitation is scarce. It has been estimated that these soils comprise over one-third of the world’s land surface area (Taalab et al. 2019, Aboukila et al. 2018).