eChapters

Among the various natural resources upon which all living organisms depend, soil is the unique because of its non-renewable in nature, heterogeneity in space and time and susceptibility to degradation inflicted by biotic as well as abiotic agents. Whereas, escalating population demands, in one way, to bring more land under the plough for providing food, fodder, fuel and fibre, simultaneously, on the other way, these finite natural resources are dwindling by leaps and bound, through overexploitations and mismanagement, the combined effect of which leads to land degradation, a serious global threat and major environmental issues in the present times.

Micronutrients are those elements essential for green plants but required in very small quantity for their growth and development. There are altogether eight micronutrient elements in soil consisting of iron, manganese, zinc, copper, boron, molybdenum and chlorine with the recent addition of nickel. These together with large number of other elements usually present in plants with small concentrations are formed as trace elements. Another element, cobalt is known to be required for microorganisms concerned mainly with nitrogen fixation in legumes affects indirectly the growth of many higher plants, thus, may be considered to be included in the list of essential micronutrient element. Similarly, Vanadium and sodium although present as beneficiary elements for plant growth may also have the possibilities to be enlisted into this group of elements.

Nitrogen Content in Indian Soil Because of tropical and subtropical climates Indian soils have very low nitrogen content and in the majority of cultivated soil it varies from 0.02% to 0.13%. Low levels of N in Indian soil is primarily attributed to climate and secondarily to cropping. Climate plays the dominant role in determining the nitrogen content in soil through the effect of soil organic matter content. Generally heavy textured soils have higher N content than loamy or sandy soils. Other factors remaining the same, total N content in soil decreases with the increase in annual temperature at a given humidity level, on the other hand, it increases with increasing humidity level at a given annual temperature. Maximum N content in soil occurs in the surface layer of soils and decreases with depth in soil profile. The variation of distribution of N content in soil with depth is attributed by varying accumulation of organic matter in soil profile.

The living organisms in the terrestrial ecosystem have unique characteristics of taking up the substances from atmosphere and soil for the synthesis of their own cellular component or as a source of energy. The supply and absorption of chemical compounds required for the growth and metabolism of the organisms may be defined as nutrition and the compounds required by them are called nutrients. The process by which the nutrients are converted to cellular material is known as the metabolism. Out of 118 chemical elements so far detected in the modern periodic table, 92 elements from hydrogen to uranium are naturally occurring, a large portion (more than sixty) of such have been detected in the plant tissues. But, the elements which take part in the nutritional requirement and metabolic processes of the plant are said to be essential elements, others which do not participate in such processes are considered non-essential.

Salt affected soils can be defined as the soils containing excess amount soluble salts in their profiles in a proportion that adversely affect to soil properties and ultimately on crop growth. The soluble salts present in these soils are composed primarily with calcium, magnesium and sodium as cationic and chlorides sulfates and carbonates as anionic constituents along with the presence of potassium, nitrate and others as minor quantities. All soils invariably contain some soluble salts, but they cause harmful effects on crop growth only when accumulates in excess amount in soil solution or increase their concentration in exchange complex of the soil. Based on the presence of sodium salts and the predominance of sodium in the exchange complex, salt affected soils are classified into main categories of 1) Saline soils – contain excess soluble sodium in soil solution with little or no sodium content in exchange complex, 2) Alkaline (Sodic) soils – contain appreciable quantity of sodium adsorbed in exchange complex of soil but may or may not contain soluble sodium salts in soil solution. These soils are also divided into following types –

Soil acidity is most conveniently measured by pH of soil suspension with water. Pure water undergoes dissociation into hydrogen and hydroxyl ions and are in equilibrium with undissiociated water molecules Thus, H2 O ??? ??? H+ + OH- (1) and in presence of another H2 O molecule, H+ converts to H3 O+ H+ + H2 O ??? ??? H3 O+ (2) Since water is a weak electrolyte and dissociates as per Eqn. 1, the ionic product of water can be written as – KW = aH+ x aOH- = (CH+ x COH– ) x ( fH+ x fOH-) (3) where, a, C, and f represents the activities, concentrations and activity coefficients of respective ions. In pure water and in dilute solutions the activity coefficients are approximately unity thus the product of concentrations of H+ and OH-1 is the ionic product of water and at ordinary temperature (250 C) this has a constant value of 10-14 gm ions per litre so, Kw =(CH+ x COH–1) = 10-14 gm ion per litre (4) such that, CH+ = COH–1 = 107 gm ion per litre Therefore, if hydrogen ion concentration of an aqueous solution exceeds this value, (10-7gm ion per litre), the solution is said to be acidic then there will be a proportionate decrease of OH- concentration to maintain the constant value of ionic product.

Soil survey is essentially a systematic examination of morphological, a set of other variable soil characteristics, description, classification and mapping of soil in an area alongwith a report making an interpretation to predict their potentials for various uses particularly for crop production.

Activities of Soil Survey Soil survey is composed of the following activities –

1. Anticipation of soil variability - The initial activity of soil survey is obtained by classifying the surveyed data according to different land forms and existing land uses either through field traversing, or aerial photo or by satellite images of the concerned area.

2. Characterisation and classification – This is done on the basis of soil profile description supported with soil analytical data.

3. Soil mapping - This is performed by showing the distribution of types of soil or soil mapping units based on already classified soils with their landforms, and land uses or their combinations.

4. Interpretation - It is the process of making prediction about the potentials of soils for various uses like choice of farm practices – agriculture, horticulture, forestry, pastures etc. and their management practices.

Classification means the process of ordering or grouping of objects having large number of population and wide variations into shorter one in a systematic manner with selected characteristics. Soils being the natural objects have no exception with other objects to classify them in a best possible way. Thus, soil classification refers to the systematic categorization of soils into various groups, classes or any simpler form based on the similar properties and other distinguishing characteristics. The main purposes of soil classification are to organize knowledge, easy remembering of the soil properties for each group and better understanding about the components and the relationships among individuals and various groups of soils. Various soil classification systems have been evolved during the past for categorizing the soils into various groups but the Soil Taxonomy has been now accepted as most scientific system of classification.

The solid phase of a soil system makes up a mixture of inorganic and organic materials. The inorganic fraction of soil originated from the weathering of rocks and minerals consists of rock fragments and minerals of varying sizes and composition. Hence, this inorganic soil fraction composed by soil minerals also referred as mineral fraction of soil and is caused due to alteration of mineralogical composition of soil by bioclimatic factors. A great deal of attention is being paid to the composition of minerals in soils, their formation and distribution over the earth’s surface. Soil genesis or pedogenosis (a more useful term as soil belongs to pedosphere) deals with the processes of formation and development of soil. The branch of soil science that integrates the studies of genesis, morphology and classification of soils as natural body is called Pedology. The process of weathering of rocks, pedogenesis and development of soil profile are described successively in this chapter.

Temperature is the measure of the thermal state of a body with respect to its ability to transfer heat. Soil derives its heat almost entirely directly from the sun and losses much of it back into the atmosphere. The major processes for heat transfer in soil are: Radiation, Convection, Conduction and Latent heat exchanges between soil and atmosphere. The most important source of which is the incident radiation supplying almost all the heat energy for the biosphere and also determines the thermal regime of soil. Soil temperature or thermal regimes of soil is an extremely important property of soil as it regulates plant growth directly and influences moisture and aeration status in soil, soil structures, microbial activities and decomposition of plant residues and the availability of plant nutrients . It is controlled mainly by its thermal properties and radiation exchange over the surface and their variations within the soil. The quantity of incident solar radiation and heating the soil depends on the several factors such as exposure and latitude, albedo, soil colour, slope vegetation and composition of soil.

Water is absolute necessary constituents for the survival and growth of all the living substances on earth. It is the most essential ingredients for many of the physiological and metabolic process in plants, like photosynthesis to form sugars, translocation of cell constituents and maintenance of cell turgidity. Soil, being an adsorbent of water received from precipitation or rainfall acts as reservoir to meet requirement by plant during growing season. Water retained in the soil serves as solvent to dissolve salts and nutrients and as a carrier to translocate them for absorption by plants. It plays significant role in weathering reaction, soil forming processes and profile development. Water is also important for growth and activities of microorganisms influencing decomposition of organic matter, transformation of mineral nutrients and other physical, chemical and biological properties in soil. This chapter deals with the retention and movement of water in soils to obtain better understanding of soil-water-plant-atmosphere relationships.

The major components of soil consisting with mineral and organic matter, water and air produces a three phase systems of solid, liquid and gas. Many of the soil properties influencing crop growth and other uses depend mostly on the relative proportions of these components as well as the size, shape and arrangements of the solid matters. The physical properties of soil have strong significance in sustaining agricultural productivity. Fertiliser alone or in conjunction with suitable crop varieties and plant protection measures cannot be sufficient towards improving crop productivity unless the soil physical properties are maintained at satisfactory level. Improvement and restoration of physical properties in soil are necessary for protection of soil resources against degradation. The physical properties of soil discussed in this chapter includes soil densities, texture, structure, porosity and consistency of soils and colour of the soil.

Soil Colloids A colloid, also known as colloidal solution or colloidal system, is a mixture in which finely divided particles (less than 1µm in size) known as dispersed phase are suspended in a medium, called dispersion medium. The particles must be dispersed in a medium and both the dispersed phase and dispersion medium may be solid, liquid or gaseous which leads to numbers of possible colloidal systems. In soil, the clay fraction (< 2µm in size) together with finer fractions of some organic matter forms the composition in a state of colloidal nature, known as soil colloids. The soil solids as dispersed phase predominates in the dispersion medium (soil solution). As such, colloids in a soil are referred to as ‘sol’. Clay colloids display the most reactive fractions of soil governing their distinct properties such as adsorption and exchange of ions, zeta potential, flocculation and other electrokinetic phenomenon.

The organic constituents of soils or soil organic matter is the most essential components of soil consisting of plant and animal residues at various stages of decomposition, cells and tissues of living or nonliving organisms and the substances synthesized by their decomposition. Soil organic matter exerts profound effect on soil productivity as it acts as source and sink of plant nutrients especially nitrogen and sulphur. It also involves in major biochemical processes to transform or release of plant nutrients into their available forms. Thus, it plays vital role in soil fertility maintenance, through increasing cation exchange capacity and improving soil physical properties, such as bulk density, aggregation, water retention capacity and also supports all kinds of biological activities in soil. The soil organic matter mostly concerns only with dead organic fractions formed from the decomposition of original plant and animal residues using as a source of food and energy by the soil microorganisms. It can be distinguished into –

Soil is a dynamic natural body of the uppermost layer of earth’s crust produced by the transformation of mineral and organic substances on the earth’ s surface under the influence of environmental factors over a long period. It is the most basic of all natural resources upon which all living forms on the terrestrial ecosystem directly and indirectly depends. However, soil resources are finite, nonrenewable, fragile and heterogeneous in space and time. As a component of pedosphere, it occurs as interface between the lithosphere and atmosphere and strongly interacts with biosphere and hydrosphere (Figure 1 & 2).

Soil is a natural resource that exists on the planet much before the existence of mankind on it. The human relationship with soil throughout the history of mankind has marked its ability of crop production and influenced the success of civilisation. Such relationships also affirm soil as the foundation of agriculture and food security, supplying all the essential ingredients to plants, as fundamentals to life on planet, and support various biogeochemical cycles on earth’ s terrestrial ecosystem. Prosperity of human society depends on the utilisation of planet’ s resources in creative and productive ways. Of these resources, soil has gained much importance as it provides human to sustain themselves with their capacity to food production, to make significant contribution towards biodiversity and other ecosystem services that are vital for the functioning and resilience of earth’ s environment. Soil occupies a pivotal position in the environment to maintain its quality.

Methods and procedures for the qualitative characterization and quantitative analysis of different constituents of soil organic matter are presented in this Chapter.

20.1. Moisture

The soil sample should be in an air-dry condition after mixing, sieving and grinding. When stored in a moisture-tight container, the free H₂O content should not vary appreciably during storage. While most determinations can be done on air-dry samples, for certain purposes such as obtaining summation values, a moisture content value is required.

Managing soil organic matter is of paramount importance in sustainable crop production. Human interventions always lead to a decrease in soil organic matter content and biological activity. Therefore, even for maintaining moderate levels of organic matter in soils, sustained efforts should be in place. Such sustained efforts should include adopting high-residue crops in rotation and ensuring regular return of residues to soils.

It is all the more difficult to maintain the organic matter content in well aerated soils and soils of hot and arid regions, because in these soils added materials decompose rapidly. However, in comparison, it may not be so difficult to maintain the organic matter levels in fine-textured soils with restricted aeration and in soils of cold temperate regions.

19.1. Measures that Decrease Soil Organic Matter Content

The study of soil organic matter is becoming increasingly important by the day as world agriculture attempts to ensure sustainability of soils, while at the same time striving to enhance food production to feed an ever-burgeoning population. The use of green manures and pasture leys, the return of residues and additions of organic amendments to the soil are often resorted to in an attempt to increase soil organic matter which immensely benefit the physical, chemical and biological make-up of the soil.

The nuclear magnetic resonance spectroscopy (NMR) has led to major advances in the studies on the nature and chemical composition of soil organic matter. The technique has the potential for characterizing organic matter in the intact soil and its size fractions without the need for extraction and fractionation. Furthermore, it can provide information on the compositional changes in crop residues, peat and litter of the forest soils during biodegradation and humification.