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Soil organic matter is any material produced originally by living organisms (plant or animal) that is returned to the soil and goes through the decomposition process. At any given time, it consists of a range of materials from the intact original tissues of plants and animals to the substantially decomposed mixture of materials known as humus. Soil organic matter (SOM) is the organic component of soil, consisting of three primary parts including plant residues and living soil organisms, decomposing (active) organic matter, and stable organic matter (humus). Most soil organic matter originates from plant tissue.

Soil organic matter (SOM) is one of the most complex materials existing in nature. Besides the organic constituents in undecayed plant and animal tissues, SOM contains both living and dead microbial cells, microbially synthesized compounds and an unending array of derivatives of these materials produced as the result of microbial activity. Soil organic matter contains most of the naturally occurring organic compounds. Some components of SOM are undoubtedly unique to the soil environment, particularly those involving inorganic-organic complexes.

4.0 Soil organic Matter

The soil organic matter (SOM) is a storehouse of multi-nutrient elements, composed mainly of carbon, hydrogen and oxygen and small amounts of other elements like nitrogen, phosphorous, sulphur, potassium, calcium , magnesium and organic residues coming out from the decomposed plant or animal products (Figure 4.1). The SOM may have the recently incorporated materials or age-old decomposed materials or with living flora or fauna in the organic matrix. Soil organic matter is one of the important components determining soil quality indices and also for enriching the fertility status of soil for production maximization. The nutrient retention capacity , water holding capacity, degradation of pollutant elements, carbon sequestration, soil structure and aggregate stability are affected by the presence of SOM.

Carbon may present in soil in four different forms:

1. Carbonates: Mainly as CaCO₃ and MgCO₃, active CO₃^2- and HCO₃^- ions and gaseous CO₂.
2. Highly condensed elemental organic form: Charcoal, graphite.
3. Completely decomposed resistant organic residues: Humus.
4. Undecomposed and partially decomposed organic residues.

Carbon may be present in soil in four different forms:

1. Carbonates: Mainly as CaCO₃ and MgCO₃, active CO₃ ^2- and HCO₃ ^- ions and gaseous CO₂.
2. Highly condensed elemental organic form: Charcoal, graphite.
3. Completely decomposed resistant organic residues: Humus.
4. Undecomposed and partially decomposed organic residues.

The latter three fractions constitute the total organic carbon of which last two are chemically active form.

To millions of different organisms around the world, soil is the habitat. A handful of soil can contain billions of soil micro-organisms. One gram of a fertile soil can harbour up to one billion bacteria. Only 5% of what is produced by green plants is consumed by animals, but 95% is consumed by microorganisms. Soil organisms are generally grouped into microfauna/microorganisms and macrofauna. The main soil microorganisms are bacteria, fungi, and protozoa. The macro-fauna includes oligochaeta, arthropods, mollusks and nematodes. These organisms play an essential role in soil formation and soil environment.

27.1. Bacteria

Bacteria are the major single-celled microorganisms in the soil ecosystem that are responsible for many important processes. There are many different types of bacteria and most of them are aerobic, requiring oxygen from the soil atmosphere. However, there are bacteria that live without oxygen and other types can live both with and without oxygen. The growth of these bacteria is limited by the food that is available in the soil. They decompose plant materials as well as other organisms’ wastes that contain plant nutrients in an unusable form and convert them into a form that can be used by plants. One such essential nutrient that is converted by bacteria is nitrogen. Nitrogen-fixing bacteria are able to use the nitrogen (N₂) that exists in the atmosphere and convert it through cellular processes into ammonia (NH₃). Nitrifying bacteria mix ammonia with water to create ammonium ion (NH₄+) and nitrate (NO₃^-), which can be used by other organisms.

11.1 Determination of Penetrability of Soil

Penetrability of a soil is usually assessed by the penetration resistance, which a measure of soil strength and thereby the soil compaction. Penetration resistance is the capacity of the soil in its confined state to resist penetration by a rigid object. Besides soil strength, the penetration resistance also depends on the size, shape and orientation of the axis of the penetrating probe. The penetrating probe may be a finger, pencil, stick, root or any specially designed object having a specified geometric shape and a device to measure the resistance as it is pushed into the soil.

Soil penetrability is intimately related to agriculture because of its adverse impact on draught requirement during ploughing, root development and crop yield, to civil engineering due to its relation to settlement, stability and ground water flow.

Soil penetrability is a measure of the ease with which an object can be pushed or driven into the soil. Any device designed to measure the resistance to penetration may be called penetrometer. There are several types of penetrometers: (i) pocket penetrometer, (ii) proctor penetrometer, (iii) cone penetrometer, and (iv) split-spoon penetrometer. Here, we will discuss about two most commonly used penetrometers viz. pocket penetrometer and cone penetrometer used for agricultural purposes.

Crusting soils

What is soil crusting?

Soil crusting refers to formation of a compact thin layer having high bulk density and high penetration resistance at the soil surface when dries after dispersion of fine particles and clogging of pores due to beating action of rain drop and slaking of irrigation water.

In arid and semiarid regions, crust formation occurs due to the destruction of soil aggregates. Crust formation occurs in all types of soils except sand. It is characterized by high bulk density, low non capillary pores, low hydraulic conductivity and aeration and high penetration resistance.

Introduction

Soil aeration status involves the rate of such ventilation, as well as the proportion of pore space filled with air, The composition of that soil air and the resulting chemical oxidation or reduction potential in the soil environment. Water provides the base for food, nutritional and environmental security. Soil water plays a significant role in controlling the energy balance of the soil and its overlying micro-environment by modifying its radiation exchanges and thermal properties. Soil temperatures affect plant and microorganism growth and also influence soil drying by evaporation. It is a central maximum of ecology that “everything is connected to everything else.” This interconnectedness is one reason why soils are such fascinating and challenging objects of study. In this chapter we shall explore three aspects of the soil air, water and temperature.

This chapter presents laboratory procedures for measuring the major physical properties that regulate soil behaviour, water availability, aeration and root development. It begins with particle-density determination using a pycnometer and proceeds to bulk density, soil texture, moisture content, total pore space, porosity and water-holding capacity. Each practical exercise provides the underlying principle, required apparatus, procedural steps, calculations and relevant precautions. The hydrometer method is introduced for estimating the proportions of sand, silt and clay. Methods for evaluating moisture retention and pore relationships are also described. Collectively, these measurements help characterize soil structure, compaction, drainage, water storage and its suitability for crop production.

ABSORPTION ACTIVE: Movement of ions and water into the plant root as a result of metabolic processes by the root, frequently against an electrochemical potential gradient.

Soil physics is the study of soil’s physical properties and processes. Soil physics deals with the dynamics of physical soil components and their phases as solid, liquids, and gases. Physical properties of soil include texture, structure, density, porosity, consistency, temperature, colour and water content. The physical properties depend on the amount, size, shape and arrangement and mineral composition of its particles , kind and amount of organic matter and the volume and form of its pores and the way they are occupied by water, air at a particular time.

1. The smallest size soil separate is

a. Sand      b. Silt

c. Clay        d. Loam

Soil pollution is defined as presence of xenobiotics (e.g. chemical compounds, radioactive elements) that alters the soil properties viz., both chemical, physical and biological properties of soil. Soil pollution, including heavy metals, may be of natural origin, like volcanic eruptions, atmospheric lightning, animal excrements or ore leaching. Nevertheless, human activity and mostly chemical industry, mining and metallurgy, as well as municipal waste management and traffic emissions are the main source of environmental pollution.

Soil pollution indicates the presence in the soil of any chemical or substance out of place and/or present at an abnormally higher concentration so as to adversely affect any non-targeted organism. Soil pollution often cannot be visually perceived or directly assessed, thus rendering it a latent danger. The Status of the World’s Soil Resources Report identified soil pollution as one of the main soil threats affecting global soils and the ecosystems services provided by them. Concerns about soil pollution are growing in every region. Recently, the United Nations Environmental Assembly (UNEA-3) adopted a resolution calling for accelerated actions and collaboration to address and manage soil pollution. This consensus, achieved by more than 170 countries, is a clear sign of the global relevance of soil pollution and of the willingness of these countries to develop concrete solutions to address the causes and impacts of this major threat.

29.1. Sources of Soil Pollution

The main anthropogenic sources of soil pollution are the chemicals used in or produced as byproducts of industrial activities, domestic, livestock and municipal wastes (including wastewater), agrochemicals, and petroleum- derived products. These chemicals are released to the environment accidentally, for example from oil spills or leaching from landfills, or intentionally, as is the case with the use of fertilizers and pesticides, irrigation with untreated wastewater, or land application of sewage sludge. Soil pollution also results from atmospheric deposition from smelting, transportation, pesticide applications and combustion of many substances as well as radionuclide fallouts from atmospheric weapons testing and nuclear accidents. New concerns are being raised about emerging pollutants such as pharmaceuticals, endocrine disruptors, hormones and toxins, among others, and biological pollutants, such as micropollutants in soils, which include bacteria and viruses.

Introduction

Productivity has increased as a result of the significant industrialization that has occurred in India during the past 40 years. However, it has also had detrimental effects on the ecology, particularly in India where soil contamination is progressively becoming more severe. In addition to the effects of man and land use, soil is constantly adapting changes in environmental conditions. A characteristic of soil pollution is the decrease in soil productivity brought on by the presence of soil pollutants. Some changes in the soil will be temporary and reversible, while others will be permanent. Pollutants in the soil have a negative impact on the physical, chemical, and biological characteristics of the soil and decrease its production. Soil pollution is a result of a variety of factors, including pesticides, fertilizers, organic manure, chemicals, radioactive waste, abandoned food, clothing, leather goods, plastics, paper, bottles, tins, and corpses. Industrial waste contains chemicals including iron, lead, mercury, copper, zinc, cadmium, aluminum, cyanides, acids, and alkalis, among others, which either directly or indirectly enter the soil.

Pollution

Pollution is an undesirable change in physical, chemical or biological characteristics of air, water or land caused by excessive accumulation of pollutants (substances causing pollution).

Kind of pollution

Pollution can be classified in many ways:

1.1 INTRODUCTION

This volume is concerned with the chemistry of soil processes. These are rather arbitrarily divided and discussed in the first part of this book in terms of mass flow and diffusion, precipitation, cation, anion and ligand exchange, adsorption, translocation of metals, and oxidation and reduction. The way in which these processes operate to determine the fate of different substances added to soils is described in the remaining part of the book. In this initial chapter an attempt is made to show how the individual chemical processes described later combine with physical and biological processes to give soils their ability to support plant life, and to accept the detritus of the world and to convert it to harmless constituents of the soil mass.

There are over 100,000 different types of soil in the world, each with its own set of characteristics. If any soil is dug deep, one can see that it is made of layers, or horizons. The horizons together form a soil profile. Each profile tells a story about the life of a soil.

The development of soil profile is a constructive process where in disintegrated materials resulting from weathering of rocks and minerals get converted into a soil body. Soil Individual or Polypedon is a natural unit of soil that differs from its adjoining unit on the landscape in one or more properties. In modern soil taxonomy, polypedon is the unit of soil mapping. Apedon is the smallest volume recognizable in nature that can be called “a soil”.

Introduction

Intensive production of agricultural crops has contributed to decline in soil quality, leading to lower crop productivity and farm profitability. Major causes of this decline are soil compaction, surface crusting, low organic matter, increased pressure and damage from diseases, weeds, insects, and other pests, as well as a lower density and diversity of beneficial soil organisms. These constraints have increased the interest of farmers in assessing the health status of their soils and in implementing sustainable soil management practices. Soil health is critically important to sustainable agricultural productivity and environmental well being. Healthy soils provide a range of environmental services including water infiltration, habitat provision and profitable and sustainable agriculture.