eChapters

1.1 Introduction Millets are the most ancient grains that have been cultivated since time immemorial and consumed as food, feed and pastures. Millets are considered nutraceuticals’ since they possess significantly higher nutritional qualities compared to other cereals. Millets are grown across the world for grains and human food due to their nutritional advantages and ability to withstand adversities. Millets are preferred over other grains due to their short life cycle, low input requirement and ensured production with in-built genetic tolerance for abiotic stresses. Major millets include Pearl millet (Pennisetum glaucum L.) and sorghum (Sorghum bicolor L.), while there are numerous minor millets classified as small millets. With an extent of over 0.87 lakh ha and a production of 0.66 kg ha-1, India is the world leader in small millet production (Maitra and Shankar, 2019). Small millets are primarily grown on rainfed uplands in arid and semi-arid climates with sub-optimal management. Following the green revolution due to extreme demands for food, the main focus in India was on the production of fine cereals mainly rice and wheat to overcome hunger and poverty, while millets became ignored grains. Furthermore, urbanization, increased affluence and dietary changes relegated millets to the status of poor man’s food. However, due to a re-evaluation of nutritious characteristics, millets have recently regained their lost prestige (Maitra, 2020).

Abstract

It is evident from the previous studies that, in the crystalline terrain, the Fractures / lineaments act as master conduits for the groundwater movements and also act as favorable loci for groundwater storage. Because of this, the mapping of fracture patterns has become very popular among geoscientists. However, after witnessing failures and the fractures turned out to be water barren at many instances, geoscientists have started concentrating more on understanding the origin and the morphology of the fractures for precise groundwater targeting. In this context, a study has been conducted in parts of Western Ghats in Madurai, Dindigul and Theni districts of Tamil Nadu, South India, using remote sensing and geographic information system (GIS). In the said study, the maxima zones of transmissivity were studied in relation to fractures systems, which are normally reflected as lineaments in satellite images in the area. This study in general indicates that the transmissivity is controlled by the fractures, which are interestingly the active faults of the Quaternary period in the area.

Frankia is potent nitrogenous biofertilizer for forest trees since it establishes symbiotic association with non-leguminous plants. Nitrogen fixing non leguminous trees thrive in temperate condition. The species belong to Casuarinaceae are an exception and grow successfully in tropical areas. Alnus for temperate regions and the genus Casuarina for tropical and sub-tropical regions stand out examples of the benefits they provide to ecosystem by the way of nitrogen fixation. They have an excellent potential to adapt themselves to grow under diverse geographical and environmental conditions providing enough fuel, fodder, pulp and timber. The microsymbiont within these root nodules of non-leguminous plants has been identified and designated as Frankia (Becking, 1970).

Historical Developments

First of all Boussingault, a French farmer during 1838 drew attention that non-legumes were capable of fixing atmospheric nitrogen. The roots of Alnus were described as warty brownish biomass as large as man’s fist (Woronin, 1866). Frank and coworkers (1887a, b, 1891) studied the nodulated nitrogen f ixing trees regardless of whether they were leguminous or non-leguminous (actinorhizal). Frank believed that the bacteroids were protein deposits but subsequently he named the causative organism as Frankia subtilis. Moller (1885, 1890) reported the causative organism in the nodules as plasmodia and Frank also revised his opinion and pointed out that the causative organism was a fungus. Such conflicting results were due to imperfect techniques to differentiate between vesicles and sporangia. Later the organism was renamed as Frankia bruchorstii to honour Frank and his coworker, Brunchorst (Moller, 1890).

Free carbon dioxide in the water accumulates due to microbial activity and respiration of organisms. Surface waters normally contain less than 10 mg free CO2 per litre while some groundwater may easily exceed that concentration up to 30 to 50 mg/L.
Principle
Free CO2 reacts with sodium carbonate to form sodium bicarbonate, or with sodium hydroxide to form sodium carbonate. Completion of reaction is indicated by the development of the pink colour characteristics of phenolphthalein indicator at the equivalence pH of 8.3.
Analysis of Water and Effluents
CO2 + N2CO3 + H2O = 2NaHCO3
CO2 + 2 NaOH = N2CO3 + H2O
Reagents
1. Standard sodium hydroxide titrant (0.05N): Dissolve 40g of NaOH in boiled CO2 free distilled water and make up the volume to 1 litre. Filter the solution through a sintered glass filter to remove any Na2CO3, the concentration of solution is 1N NaOH. Store it in in glass bottle.
2. Phenolphthalein indicator

Introduction

Diazotrophs are phylogenetically diverse microbes spanning over various classes varying vastly on basis of physiological properties (Young, 1992), include various phototrophic microorganisms aerobic phototrophic Cyanobacteria (Vaishampayan et al, 2001), anaerobic purple-sulfur phototrophs like Chromatium, and green-sulfur phototrophs, e.g. Chlorobium, Rhodopseudomonas; chemolithotrophs Alcaligenes, Thiobacillus, Methanosarcina, Methanobacterium, Desulfovibrio or Azospirillum lipoferum and heterotrophic bacterial anaerobes (Clostridium), microaerophiles (Herbaspirillum), and aerobes (Azotobacter). Free-living aerobic nitrogen fixing bacterial genera found in soil include obligate aerobes as Azotobacter, Beijerinckia, Derxia, Achromobacter, Mycobacterium, Arthrobacter and Bacillus but the majority are microaerophilic (e.g. Azospirillum, Herbaspirillum) or facultative and obligate anaerobes (e.g. Klebsiella, Aerobacter, Desulfovibrios, Rhodospirillum, Clostridium, Erwinia).

Among the pulses, rajmash is one of the high potential pulse crops with a yielding potential of 18 to 20 q per ha. Rajmash or French bean (Phaseolus vulgaris L.) is a short duration non–traditional grain legume and one of the precious and highly relished pulse crops of North India. Rajmash is known by various names viz., French bean, rajma, haricot bean, field bean, kidney bean, snap bean, pole bean etc. It is an important winter vegetable grown both for tender pods and dry seeds, which form a rich source of crude protein (21.25%), fat (1.7%) and carbohydrates (70%). Besides, it contains 0.16 mg iron, 1.76 mg calcium and 3.43 mg zinc per 100 g of edible part (Jasvinder Kaur and Mehta, 1994). The fresh pods and green leaves are used as vegetable. The antimetabolites of dry beans needs removal by cooking and soaking in water.

1. Introduction
The term “plastic” is derived from the Greek word “Plasticos" whichmeans to be capable of molding into various sizes and shapes. Daily usedsynthetic plastics are categorized based on their physical and chemicalproperties, such as thermoplastic and thermosetting. (i) Thermoplastics: Astheir names suggest, thermoplastic polymers melt and turn into a plastic orrubbery state when exposed to heat. They have various numbers of polymericchains and are the most widely used plastics in day-to-day life. Examples ofthermoplastics are Polystyrene(PS), Polyvinylchloride (PVC), Polypropylene(PP), Polyethylene Terephthalate (PET), Polyethylene (PE) etc. (Massy,2017), (Sharma et al., 2017). (ii) Thermosetting polymers: As the namesuggests, they set or harden permanently when heated (Massy, 2017). Due totheirstrong crosslinked structure, they are non-recyclable polymers. Examplesinclude Polyurethanes(PUR), Phenol formaldehyde, Melamine formaldehyde,and Polyester Resin (PR) (Sharma et al., 2017). Different polymers and theirapplications are illustrated in Fig. 1.

During the last 21 years, the scientists and scholars of the M.S. Swaminathan Research Foundation (MSSRF) have been working on the design and implementation of projects which could have a large extrapolation domain in respect of imparting a pro-nature, pro-poor, pro-women and pro-sustainable livelihood orientation to technology development and dissemination. I would like to write about a few of the MSSRF initiatives, which have now become state, national and global programmes.

Mahila Kisan Sashaktikaran Pariyojana: Strengthening the role of women in agriculture

MSSRF initiated the Mahila Kisan Sashaktikaran Pariyojana in the Vidarbha region of Maharashtra in 2007 for empowering women farmers, including the widows of farmers who had committed suicide, in areas related to enhancing the productivity, profitability and sustainability of small-scale rain-fed farming. The empowerment measures incorporated access to technology, credit, inputs and market.

Maize or corn (Zea mays L.), which was first domesticated in Mexico, is the most widely grown cereal crop in the world. Maize is consumed as feed and food, and also has myriads industrial applications, including the production of bioethanol and starch. Due to its highest genetic potential, production and productivity among the cereal crops, maize is called as “Queen of the Cereals”. Noble Laureate Dr. Norman E. Borlaug, the Father of Green revolution stated 15 years ago that “The past two decades saw the revolution in rice and wheat, the next few decades will be known as maize era”. In India, maize is the third largest grain crop and its production and demand is increasing rapidly. In India, it is primarily a non-food cereal crop, with only 10% being consumed as direct human food, while the rest being used for feed, industrial and export purposes. The effective deployment of various frontier technologies viz. genetic engineering, doubled haploids, molecular markers, phenomics etc.has greatly helped in raising productivity of maize crop worldwide in the last decade.The present chapter provides an overview on role of frontier technologies in maize crop improvement.

India, a predominantly agrarian nation, relies heavily on agriculture for livelihoods. Over the decades, agricultural policies have focused on increasing the supply and accessibility of staple grains. This strategy has successfully reduced hunger and transformed the country’s food system (Pingali et al., 2019). At the forefront of this transformation stands Punjab that played a pivotal role in moving India from a food scarcity to self-sufficiency. Punjab’s agricultural success is globally recognized, driven by the rapid technology adoption, enabled through synergy of infrastructure, incentives and most critically, information (Singh & Kohli, 1997). Among these drivers, dissemination through agricultural extension proved instrumental in ensuring that innovations such as high-yielding variety (HYV) seeds, irrigation facilities and market incentives reached farmers effectively. While various factors contributed to Punjab’s growth, but agricultural extension remains a cornerstone, translating research breakthroughs into fieldlevel impact. Punjab Agricultural University (PAU) has been a key catalyst in this journey. while serving as a premier institution in agricultural research, education, and extension. PAU’s extension system has evolved in response to shifting agricultural needs, environmental challenges, and technological advancements. Beginning in 1960s, PAU led the Green Revolution by introducing HYVs and modern agricultural inputs through a dedicated, farmer-focused extension network (Gulati et al., 2018). In its early decades, PAU’s extension services emphasized increasing productivity through mechanization and the use of fertilizers and pesticides. Initiatives such as Kisan Melas (Farmers’ Fairs) and Kisan Clubs’ facilitated knowledge transfer to rural communities, fostering large-scale adoption of new technologies. However, by the late 1980s, concerns such as soil degradation and pest resistance prompted a strategic pivot. The PAU approach shifted from purely productivity-focused methods to more sustainable and diversified practices such as Integrated Nutrient Management (INM), integrated weed management (IWM) Integrated Pest Management (IPM), water conservation, etc. Today, PAU continues to modernize its extension practices through participatory, farmer-centric approaches. The current emphasis lies in promoting innovation, entrepreneurship, adaptability and sustainability through a blend of traditional outreach and modern ICT tools. Notable innovative approaches include e-extension services via mobile apps and online portals, real-time advisory systems through SMS and digital platforms, hybrid training modules

Fruit trees can be planted in the backyard or any open space near the house. In absence of backyard area, fruit trees can also be grown on the rooftop by planting in polythene bag, plastic container, cemented pot, etc. Growing fruits like papaya, banana, lemon, mango, pineapple, coconut, pomegranate, etc. in the premises of house can fulfil the family requirement of fruits. It will help to get fresh fruits from own garden, which are free from any chemical or pesticide. There is a different satisfaction in plucking of fruits grown by own effect.

Mango

Mango (Mangifera indica) is one of the prominent fruit crops of India. It has delicious taste and excellent flavour. Mango fruit is utilized at all the stages of its development. Raw fruits are used for preparation of pickle, chutney and juice. The ripe fruits are consumed directly and are used for preparation of several products like squash, syrup, jam and jelly. Ripe mango contains about 0.6 per cent protein, 0.1 per cent fat, 11.8 per cent carbohydrate, 0.3 per cent minerals and 1.1 per cent fibre. 

SYNOPSIS

Many plants or plant parts are eaten as food. In addition to essential vitamins, minerals, and fibers, plant foods contain phytochemicals and antioxidants, which actively provide protection against diseases. Several studies carried out all over the world have demonstrated the protective values of fruits. Fruits are the ripened ovaries of plants, including the seeds within. Many plants have evolved fruits that are attractive as a food source to animals, so that animals will eat the fruits and excrete the seeds some distance away.

ABSTRACT

This paper demonstrates the ability of FTIR for analyzing compositional structures of naturally occurring crystals namely gypsum and calcite. As these two crystals occur in a wide variety of geological environments and are susceptible to compositional and structural changes influenced by pressure, temperature, crystallization fluids and so many other factors, these are extensively studied by geoscientists for interpretation of paleoenvironment, modeling diagenesis of sediments and deducing sediment maturity for hydrocarbon exploration, study of these two crystals is important. Naturally occurring gypsum and calcite crystals collected from Cretaceous marine deposits of Ariyalur area were chosen for the present study as extensive occurrences of hydrocarbons are reported from offshore region of Cauvery basin and exploratory works are going on in the onland region. It is observed that the vibrational spectra of studied crystals show specific patterns in terms of stretching patterns of O-H, C-O, C=O, SO₄ and CO₂. As FTIR offers fast, cost-effective, non-destructive method of analyses of natural compounds, as it is proven useful, it can be utilized extensively in academic research and commercial exploration activities by geoscientists.

Keywords : Spectral characterization, calcite, gypsum, diagenesis, paleoclimate, hydrocarbon exploration.

16.1 Fuel Cell

Fuel cell is an electrochemical device that convert chemical energy of a reaction directly into electrical energy. The basic physical structure of a fuel cell consists of an electrolyte layer in contact with a porous anode and cathode on either side. A schematic representation of a fuel cell with the reactant or product gases and the ion conduction flow directions through the cell is shown in Fig. 16.1

15.1 Fuel Cell

Fuel cell is a electrochemical device that convert chemical energy of a reaction directly into electrical energy. The basic physical structure of a fuel cell consists of an electrolyte layer in contact with a porous anode and cathode on either side. A schematic representation of a fuel cell with the reactant or product gases and the ion conduction flow directions through the cell is shown in Fig. 15.1

9.1 Introduction

Hydrogen is colourless and odourless gas. Hydrogen is simplest and lightest element and most abundant available element on the earth. It is not primary energy source as it does not exist in free state however it presents in compound with oxygen (water) and carbon, nitrogen and oxygen in living material and fossil fuels (natural gas, coal and biomass). Therefore, hydrogen can be produced from these sources using some external energy. Hydrogen can be burned without generating CO₂ and have clean combustion. but with air it can form very explosive mixture. Hydrogen is considered as an energy carrier. Like energy carrier allows the transport of energy in usable form from one place to another. 

INTRODUCTION
The fuel system in a tractor engine is essential for maintaining efficient engine operation by ensuring clean and well-regulated fuel is delivered to the combustion chamber for optimal performance. Proper upkeep of this system, including regular checks on fuel filters, lines, and pumps, helps extend the engine’s lifespan and guarantees smooth operation during demanding agricultural tasks. The fuel system plays a key role in supplying the engine with precisely regulated fuel for combustion. Core components like the fuel pump, fuel filter, and fuel injectors work together to deliver the right quantity of fuel at the appropriate time, ensuring the engine operates efficiently, performs reliably, and lasts longer.
FUEL PUMP
The fuel pump is responsible for drawing fuel from the fuel tank and delivering it to the engine at the correct pressure. It ensures a consistent and reliable flow of fuel to the fuel injectors or carburetor.
Types of Fuel Pumps
• Mechanical Fuel Pump: Common in older tractors, this pump is usually driven by the engine through a gear or camshaft. It delivers fuel from the tank to the fuel system at a steady pressure.
• Electric Fuel Pump: Found in modern tractors, electric pumps are powered by the tractor’s electrical system and provide more consistent pressure and flow. These are often located near the fuel tank and can be activated by a relay or switch.

INTRODUCTION
The fuel system in a tractor engine is essential for providing the engine with the right amount of fuel to enable efficient combustion. Its primary function is to guarantee a steady and reliable flow of clean, properly atomized fuel, which is crucial for achieving optimal performance and fuel efficiency. The system consists of various components that collaborate to manage different processes such as storing, filtering, and delivering the fuel to the combustion chamber.
These processes must work in harmony to ensure the engine operates smoothly, maintaining both power output and efficiency. Proper atomization of the fuel ensures that it mixes well with air, allowing for more complete combustion and minimizing the chances of fuel wastage or emission of harmful substances. From fuel storage tanks to injectors, every part of the fuel system is designed to meet the demands of the engine under various operating conditions.
A well-functioning fuel system helps maintain engine longevity, reduces fuel consumption, and ensures that the engine can perform at its best across different workloads and environments.
Fuel is a substance consumed by the engine to produce power. The common fuel for Internal Combustion engines are
1. Petrol
2. Power kerosene
3. High speed diesel
Calorific value of fuel
The heat liberated by combustion of a fuel is known as calorific value or heat value of the fuel. It is expressed in kcal/kg of the fuel

Although plants can be grown to maturity in aerated nutrient solutions and other media, virtually all land plants, including those on which we depend for food, fibre and fuel, grow in soil. The soil has three-fold function to perform with respect to crop growth: physical, chemical and biological.

For the intelligent appreciation and understanding of various reactions and processes associated with soils a little basic knowledge of chemistry is helpful. If the reader follows this chapter carefully, the working knowledge of chemistry thus acquired will enable him to follow all the complicated chemical reactions taking place in the soil.

What is Chemistry? Chemistry is the science that deals with the chemical changes. What is a chemical change? When two or more substances combine to give a substance entirely different in properties to the individual components, the change is called a chemical action to distinguish it from the purely physical action in which the properties of the product are intermediate between the components. The latter naturally can be separated easily by mechanical means. For instance a mixture of sand and water can be separated by passing through a filter, and a mixture of salt and water can be separated by evaporating the water when the salt is left as residue. But water itself is a compound of two gases: oxygen and hydrogen. Its properties are totally different from its components. We can freeze it, evaporate it and perform a host of other operations on it without changing it in the least.

Atoms and molecules: The whole science of chemistry rests on atoms and molecules If these are understood clearly, basic chemistry is reduced to simplicity. Take a familiar object like gold or silver and go on subdividing it into smaller and smaller bits. You will reach a stage that further subdivision will become impossible. You will have reached the primary units, the elementary bricks of which the substance is made up, namely the “Atoms”. An atom in chemistry is the smallest brick from which all material substances in the world are made up. Not that you can see an atom. It is so small that even the most powerful microscope will nut reveal its presence. You could perhaps just see a collection of a million atoms as a tiny spot of light if it is illuminated with a powerful beam of light. Even then you could not say if it was round, square, or oblong. However, you need not look for any such tangible proof to believe in the existence of atoms. Even pure logic would compel you to stop somewhere if you started with an imaginary division and sub-division of a substance. You could not go on ad infinitum. Even the ancients, who knew no modern chemistry, believed in their existence purely from philosophical reasoning.