eChapters

Abstract
 
Much attention has been paid to mycorrhza as a tool for improving the growth and health of plants.  The use of mycorrhiza in agricultureal, horticultural and forestry has been described. The significance of AM fungi in sustainable agriculture has been a subject of growing interest for the past several decades. In sustainable agriculture it is imperative to maximize benefits with low input costs. The fact remains that stable and lower human population is an integral component of sustainable agriculture and more so in an Indian context. Therefore, it is imperative to collect further information on the different aspects of AM fungal symbiosis as discussed in this article so as to utilize this plant microbe symbiotic system for the increased production and productivity in a sustainable manner. This may become possible when the integrated approach is made to study AM fungi right from the isolation of AM fungal spores to the high quality inoculum production and its application in the field. It is also imperative to stimulate new mutualism between mycorrhizal scientists and ecologists. It this regard, recent advancement made in the molecular techniques should be encouraged in order to obtain more authentic results. Adequate field testing of mycorrhizal inoculation and commercial exploitation of the potential benefits of mycorrhiza still rests on the development of suitable technology for mycorrhizal inoculum preparation.

Introduction

Fungicides are biocidal chemical compounds or biological organisms used to kill or inhibit fungi or fungal spores. An insecticide is a pesticide used against insects. Pyrethroids are widely used insecticides in agriculture as they control pests and diseases effectively in plants. Because of their low biodegradability and high persistence, they are extensively found in environmental samples such as air, water, soil, sediments, food and biological tissues [1-4]. Moreover, these chemicals induce cancer and act as endocrine disrupters in several organisms due to their high degree of toxicity. Although the use of most pyrethroids has been prohibited or limited in developed countries, they are used in many developing and under developed countries for controlling of pests and insecticides [5-8].

Abstract

Agriculture provides food, feed, fiber and many other desired products for survival of human beings in the world. Modern agriculture emphasizes on use of hybrid seeds, high yielding varieties and chemical fertilizer to increase the crop productivity within a short period. Indiscriminate use of synthetic fertilizers has led to environmental pollution and deterioration of soil health, which results in depletion of essential plant nutrients and organic matter in soil. On account of the environmental hazard and soil infertility, biofertilizer concept was developed. Biofertilizer are natural fertilizers including bacteria, fungi and algae alone or in combination that augment availability of nutrients to the plants. However, due to its short shelf life period it may not be a suitable candidate for modern agriculture. Thus, it is the need of the hour to develop an economic and eco-friendly nano-biofertilizer for sustainable agriculture.

Introduction

Food packaging is a critical technology addressing the ever-increasing demands for convenience, freshness, ease, shelf-life, safety and security of food products.
 
The main purpose of food packaging is to protect the food from microbial and chemical contamination, oxygen, water vapor and light. The type of packaging used therefore has an important role in determining the shelf-life of the food. Nanotechnology can be intervened to achieve the purpose of food packaging and it will become one of the most powerful forces for innovation in the food packaging industry.

Introduction

Weeds are unwanted plants in agricultural production causing huge losses in crop production system particularly rainfed agriculture. Of the total estimated losses caused in crop production by pests, diseases and weeds in the world, the weeds alone are responsible for one-third of it. Weeds interfere with crop growth and cause an yield loss to the tune of 10% of crop production which amounts to a total loss of about 20 million MT of food grains, valued at over Rs.10,000 crores, at current prices in India. Besides, losses of similar magnitude are experienced in vegetable, fruit and plantation crops. The losses inflicted on biodiversity, environment and health are considerable and have not been quantified scientifically.

Introduction
 
Maintaining and restoring the quality of air, water and soil is one of the great challenges of our time. Most countries face serious environmental problems, such as the availability of drinking water, the treatment of waste and wastewater, air pollution and the contamination of soil and groundwater. There are two main approaches to these problems: the first is to control pollution at source to minimize or eliminate waste production or harmful emissions; the second is to remedy the pollutants that accumulate in the environment. Considering the enormous scale of soil and groundwater contamination, the complexity of the task seems intractable. In many cases, conventional remediation and treatment technologies have shown only limited effectiveness in reducing the levels of pollutants, especially in soil and water (Rickerby and Morrison, 2007).

In plants, mineral uptake is the process in which minerals enter the cellular material, typically following the same pathway as water. The most normal entrance portal for mineral uptake is through plant roots. Some mineral ions diffuse in-between the cells. In contrast to water, some minerals are actively taken up by plant cells. Mineral nutrient concentration in roots may be 10,000 times more than in surrounding soil. During transport throughout a plant, minerals can exit xylem and enter cells that require them. Mineral ions cross plasma membranes by a chemiosmotic mechanism. Plants absorb minerals in ionic form: nitrate (NO₃^-), phosphate (HPO₄^-) and potassium ions (K+); all have difficulty crossing a charged plasma membrane. It has long been known plants expend energy to actively take up and concentrate mineral ions. Proton pump hydrolyzes ATP to transport H⁺ ions out of cell; this sets up an electrochemical gradient that causes positive ions to flow into cells. Negative ions are carried across the plasma membrane in conjunction with H⁺ ions as H⁺ ions diffuse down their concentration gradient.

Introduction

Nano science is the study of the properties of structures of the size smaller than several hundreds of nano meter (nm). Nanotechnology consists in techniques for designing and manufacturing these structures as well as applications arising from these. The development of nanoscience and nanotechnology is in line with the trend towards miniaturisation. As nanoscience and nanotechnology developed, they make the barriers between traditional scientific and technological disciplines more permeable.

Nanotechnology is an emerging of field of science which is being highly exploited in the sphere of medicine where “nano” plays a vital role in delivery of drugs or chemical molecules to the point it is required in précised quantities in right proportions. Nanoscience infuses intelligence to the truck load of chemical constituents that are to be delivered at appropriate locations and cleave from the site after the task is complete. Such process will likely to reduce the cost besides ensuring environmental safety. Nanoscale devices with its unique properties make the agricultural system more smart and effective; such devices are capable of responding to different situations by themselves, thus taking appropriate remedial action with the need of external directions from humans. In short, these devices act as a detectors and if need arises serve as a solution/remedy for the particular issue. These smart delivery systems of chemicals in controlled and targeted manner can be considered synonymous to the proposed nano-drug delivery system in human (Patolsky et al., 2006).

Nano-biofertilizers (NBFs) represent an emerging and sustainable approach to improving soil nutritional security and crop productivity in modern agriculture. By integrating beneficial microorganisms with nanomaterials, nano-biofertilizers overcome several limitations associated with conventional fertilizers and biofertilizers, such as low nutrient use efficiency, nutrient losses through leaching, poor microbial survival, and environmental pollution. This chapter provides a comprehensive overview of the role of nano-biofertilizers in enhancing soil fertility, nutrient availability, plant growth, and stress tolerance. The mechanisms underlying improved nutrient use efficiency, soil physical and chemical properties, plant physiological stability, and resistance to abiotic and biotic stresses are discussed in detail. The application of nano-biofertilizers in conventional and precision agriculture systems, including sensor-based variable rate application, fertigation, and data-driven nutrient management, is highlighted. Additionally, various application methods, environmental benefits, and challenges related to safety, scalability, regulation, and farmer adoption are critically examined. Overall, nano-biofertilizers hold immense potential to revolutionize sustainable agriculture by promoting efficient nutrient management, enhancing crop resilience, and minimizing environmental impacts, thereby contributing to long-term food security under changing climatic conditions.

Modern agriculture faces unprecedented challenges due to climate change, unsustainable farming practices, and declining soil health. In response, nanoparticle-bioinoculants (nano-bioinoculants) have emerged as a promising innovation that integrates nanotechnology with microbial inoculants to enhance plant productivity and sustainability. Conventional agriculture contributes significantly to greenhouse gas emissions, degrades microbial diversity, and compromises ecological balance. Beneficial microbes, known as bioinoculants, play a vital role in improving plant health through nutrient cycling, hormone production, and disease suppression. However, their field performance is often limited by environmental instability and low survival rates. Nanotechnology provides a solution by enabling the encapsulation of bioinoculants within nanoparticles, enhancing their stability, targeted delivery, and effectiveness. These nano-scale carriers exhibit high surface-area-to-volume ratios, improved reactivity, and strong adhesion properties, making them ideal for enhancing microbial colonization and activity in the rhizosphere. Additionally, nanoparticles function as nano-fertilizers and nano-pesticides, supporting both plant nutrition and protection against pathogens. Plant-based nanoparticle synthesis further offers an eco-friendly alternative, minimizing ecological and health risks. Studies demonstrated that nano-bioinoculants improve seed germination, stress resilience, photosynthetic activity, and crop yield across various species. They also mitigate abiotic stresses such as drought, salinity, and heavy metal toxicity while promoting systemic resistance against biotic threats. The synergistic combination of nanoparticles and microbial agents enables multifunctional benefits—supporting soil health, reducing chemical dependency, and enhancing agricultural resilience. While challenges remain in understanding

Global agricultural sector moves toward sustainability and resource efficiency, bioinoculants represent a transformative innovation. Bioinoculants (microbial inoculants) are preparations containing beneficial microorganisms such as bacteria, actinomycetes, fungi, and cyanobacteria that, when applied to seeds, seedlings, or plants, and soil, enhance nutrient availability, promote plant growth, and improve soil fertility. In the context of modern agriculture’s ecological challenges, such as soil degradation, overuse of agrochemicals, and climate variability, microbial inoculants offer a sustainable, cost-effective, and environmentally friendly alternative. However, their effectiveness is often limited by environmental stresses, short shelf life, and inconsistent field performance. Nano-bioinoculants address these limitations through the integration of nanotechnology into microbial formulations. This innovative approach improves microbial viability under field conditions, increases interaction efficiency with plant roots, and enables controlled nutrient release, leading to improved crop performance. Plant growth, soil fertility, and stress resistance are strengthened by inoculation using nanoparticles, nano-based biofertilizers, and biopesticides. Their application is particularly relevant in India, where diverse agro-climatic zones and smallholder farming systems demand low-input, high-efficiency solutions. In India, where the demand for eco-friendly and high-efficiency agri-inputs is

Biopesticides are pesticides that are produced naturally by plants, animals, microbes, and other minerals. These represent less of a harm to humans and the environment than chemical insecticides. Nanotechnology is a rapidly developing scientific topic that has numerous uses in numerous industries, including agriculture. The transport of plant hormones, seed germination, water management, transfer of target genes, nano barcoding, nano sensors, and controlled release of agrichemicals are now being investigated as applications for nanotechnology in agriculture (Worrall et al. 2018).

1. Introduction
It is the need of the hour that disposal of radioactive wastes be taken seriouslyand given appropriate attention. We house around one million gallons of liquidradioactive waste awaiting remediation at U.S. Department of Energy’s HanfordReservation alone (Parshley & McDermott, 2021). Not only the numbers are
but the increasing demand of nuclear energy paves the way forgeneration of even more radioactive waste in future. The conventional methodshave certain limitations. Ion-exchange resins have reported to bedegradedunder high radiation and chemical precipitation has proven to be ineffectivein treating low concentration of radionuclides found in groundwater, posingrisk for centuries (Zhang & Liu, 2020). Remediation methods including soil

Introduction

Since past decades, the application of nanotechnology in the areas of medicine, materials science and electronics have been widely accepted and appreciated due to its potential and benefits.  However, only during the recent years, researchers from other disciplines have started to see the potential applications of nanoscience in the field of agriculture (Robinson and Morrison, 2009). Recently, a generalized and process based framework to enable identification and characterization of the outputs (publications, patents etc.), and map them to the different agricultural research theme areas through the filter of links in the agri-value chain were developed by Kalpana Shastri et al., (2010) from National Academy of Agricultural Research Management (NAARM), Hyderabad, India. The frame work also permits assessing the implications for technology transfer, and impacts on society and environment. This frame work mainly relies on the identification of nano research and relating them agri-food thematic areas (Fig.1).

Introduction

By enhancing microbial populations, enzyme activity, soil respiration, and microbial biomass, nano-black carbon is a novel method for the enhancement of soil biological characteristics. By reducing soil acidity and boosting soil fertility, nano-black carbon is believed to improve plant development. The application of nano-black carbon to agricultural soils can have a significant positive impact on plant productivity. In addition to potentially boosting soil resilience to climate change, nano-black carbon greatly boosted enzyme activity, microbial activity, and soil organic carbon retention.Due to a liming action, nano-black carbon has been proposed as a potential biotechnology to boost agricultural yields in acidic soils.

Introduction

Fertilizers play an important role in improving soil fertility and productivity of crops regardless of nature of cropping sequence or environmental conditions. It has been unequivocally demonstrated that one third of crop productivity is dictated by fertilizers besides influencing use efficiencies of other agri-inputs. In the past four decades, nutrient use efficiency (NUE) of crops had hardly exceeded 35-50%, 18-20% and 30-35 % for N, P and K, respectively, despite our relentless efforts. The remaining nutrients stay in soil or enter into the aquatic environment causing eutrophication. In addition to the low nutrient efficiencies, Indian agriculture facing a problem of low organic matter, imbalanced fertilization and low fertilizer response that eventually caused crop yield stagnation (Biswas and sharma, 2008).

20.1 Introduction
  
Fertilizers play an important role in improving soil fertility and productivity of crops regardless of nature of cropping sequence or environmental conditions. It has been unequivocally demonstrated that one third of crop productivity is dictated by fertilizers besides influencing use efficiencies of other agri-inputs. In the past four decades, nutrient use efficiency (NUE) of crops had hardly exceeded 35-50%, 18-20% and 30-35 % for N, P and K, respectively, despite our relentless efforts. The remaining nutrients stay in soil or enter into the aquatic environment causing eutrophication. In addition to the low nutrient efficiencies, Indian agriculture is facing a problem of low organic matter, imbalanced fertilization and low fertilizer response that eventually caused crop yield stagnation (Biswas and sharma, 2008).The fertilizer response ratio in the irrigated areas of the country  has dcreased from 13.4 kg grain / kg nutrient applied in 1970’s to just 3.7 kg in 2005. In other words, more amounts of fertilizers is required to produce the same quantity of grain output. For instance, 27 kg NPK ha-1 was required to produce one tonne of grain in 1970 while the same level of production can be achieved by 109 kg NPK ha-1 in 2008. 

Nanofibres are an exciting new class of material used for several value added applications in the field of such as medical, filtration as barrier in composites, garments, wipes, insulation, and energy storage. Special properties of nanofibres make them suitable for a wide range of applications from medicine to consumer products and industrial to high-tech applications. The US - National Science Foundation (NSF) defines nanofibres as having at least one dimension of 100 nm or less (Hegde, 2005). Amongst the various nanostructures that have recently been developed for use in practical applications, nanofibres produced from synthetic and natural polymershave received increased attention due to their ease of fabrication and the ability to control their compositional, structural and functional properties (Burgeretal.,2006).