eChapters

Introduction

Agrochemicals are categorised based on the specific target organisms they are intended to control, including insects, weeds, and fungi. Among these target organisms, weeds significantly contribute to the highest economic losses due to their interference in crop production. Herbicides, the predominant class of agrochemicals globally, account for 48% of the total expenditure. The largest consumers of agrochemicals are Europe, Asia, and the United States. Herbicides have various biological and chemical properties (Roy et al., 2023a). They exhibit variations in behaviour and spectrum weed control. These properties play an important role in herbicide selection, method of utilisation and application, post-application effects such as toxicity and residue accumulation in the soil. The crucial factor for any herbicide application is the behaviour of the herbicide in the soil and its transformation or modification once it reaches the soil (Miller and Westra, 1914). The fate of herbicides and their efficiency are regulated by herbicide properties, soil characteristics and climatic conditions.

Objectives
• Comprehend the fundamental concepts of personal and professional communication and their significance in various contexts.
• Develop an understanding of the key elements that contribute to effective verbal and non-verbal communication.
• Identify common barriers to communication and learn strategies toovercome them in personal and professional settings.
• Enhance personal communication skills, including active listening, empathy, assertiveness, and constructive feedback.
• Acquire professional communication skills essential for writing, verbal interactions, and presentations in the workplace.
• Understand the dynamics of communication in different professional contexts, including teamwork, cross-cultural communication, and conflict resolution.
What is Communication
Communication is the process of exchanging information, thoughts, ideas, and feelings between individuals or groups. It involves the sender, message, medium, receiver, and feedback. Types of communication include personal communication, which is informal a nd characterized by emotional and personal expression, and professional communication, which is formal and involves clear messaging that follows organizational protocols.

Dr. Chauhan’s philosophy as a Veterinary Pathologist reflects a profound understanding of the interconnectedness of life and an unwavering commitment to the well-being of animals. His approach is rooted in compassion, scientific rigor, and a holistic appreciation of the delicate balance that sustains ecosystems. Over the years, he has become a beacon of hope for gaushalas and cow enthusiasts, demonstrating that veterinary medicine is not just a profession but a calling that demands empathy, dedication, and an unyielding respect for life.
At the core of Dr. Chauhan’s philosophy is the belief that every living being, regardless of its size or species, deserves dignity and care. To him, animals are not mere creatures but sentient beings with emotions, instincts, and intrinsic value. This perspective shapes his practice, as he treats each animal with the same care and attention he would give to a human patient. Whether it’s a stray dog in need of emergency care, a farm animal requiring preventive medicine, or an endangered species in a conservation program, Dr. Chauhan approaches his work with equal seriousness and respect.
Dr. Chauhan emphasizes the importance of understanding animals within the context of their natural behaviors and environments. He often says, “To heal an animal, you must first listen to what it cannot say.” This insight has driven him to study not only veterinary medicine but also animal behavior, ecology, and the complex relationships between humans and animals. He believes that understanding these dynamics is essential for providing comprehensive care. For example, he advocates for preventive care practices that align with an animal’s natural rhythms, such as vaccination schedules that account for seasonal changes and diets that mimic an animal’s natural food sources.

Natural farming in India adopts a preventive and ecosystem-based approach to pest and disease management, prioritizing ecological harmony over chemical control. Rather than eradicating pests, the aim is to regulate their populations through natural mechanisms and enhance the farm’s biological resilience.
Natural farmers commonly use plant-based formulations such as Agniastra, Brahmastra, and Neemastra. These are prepared from locally available herbs, cow urine, and cow dung, and serve as effective insecticidal and antifungal sprays. Neem (Azadirachta indica) plays a central role due to its wide-ranging pestrepelling properties and is a staple in fermented bio-sprays. Practices like crop
rotation, intercropping, and companion planting help disrupt pest life cycles and minimize disease occurrence. Crops like marigold deter nematodes and aphids, while plants like basil and turmeric suppress fungal infections. These practices also promote the presence of beneficial insects and pollinators, contributing to natural pest control.
A key strategy in natural farming is enhancing soil health through inputs like Jeevamrit, compost, and fermented plant extracts. These boost microbial activity, which in turn suppresses soil-borne pathogens and strengthens plant
immunity. Waaphasa—ensuring proper soil aeration—helps prevent root diseases by maintaining an optimal air-moisture balance in the rhizosphere.
Regular field inspection and sanitation help in early detection of pest issues. Timely weeding and residue management further reduce disease spread. Immediate application of natural deterrents can prevent outbreaks from escalating.

Introduction

Surging food demand and shrinking land resources to produce more from the limited natural resources like soil and water is poised to environmental degradation. Increased production must be achieved mainly by increasing crop productivity per unit area while sustaining the environment and enhanced input use efficiency. Agricultural production systems are increasingly under pressure to adapt decision-making process to be make more informed and efficient use of irrigation water, fertilizers and pesticides. Adverse effects of climate change are added challenges to agricultural productivity. Efficient crop management strategies to improve resource use efficiency and reduce crop losses are vital issues to be taken care for a sustainable sustainably enhanced production system. Genetic improvement approaches involving high throughput phenotyping and genomics-assisted breeding enhancing resource use efficiency, stress tolerance, yield has become imperative. Precise crop health monitoring is one of the keys to the modern production system. Obviously, disease forecasting and surveillance systems are in great demand to adopt precise management against the losses caused by diseases. Predicting disease risk at regional and global scales is of great interest for on-farm management and for assessment of agricultural policies and practices.

Insect pests cause huge losses ranging from 5 to 80% of even up to 100%. Acute food shortage following world war –II and Bengal famine (1943) due to failure of rice crop due to a paddy disease indicate the severity of the loss, caused by the pests and diseases. The insects in storage on an average consume and spoil an additional 4 million tones of grains every year. All this indicates the importance of plant protection by which we can save millions of tones of food grains which are otherwise eaten away by different pests. Losses due to insect pests in Indian agriculture are 23.3 per cent. One of the practical means of increasing crop production is to minimize the pest associated losses.

A pest is any organism which occurs in large numbers and conflict with man’s welfare, convenience and profit.

Pests are often controlled with man made chemicals which have many harmful effects, for example:

In agricultural practices pesticide application is an inevitable factor for maintaining high crop productivity and is currently an integral part of modern farming. Pests (insects, microbes and weeds) cause approximately 20-30% loss in crop production so making pesticide use indispensable for crop protection.
 
Pesticide : A pesticide may be defined as ‘any agent or chemical or a mixture of chemicals/ substances intended to prevent, destroy, repel or irritate one or more pest populations causing economic loss in crop production’. Worldwide more than 450 active pesticide chemicals formulated into more than 10,000 commercial products are currently used by farmers. The most worrying aspect is that about two-third of the 800 chemicals tested so far have been found involved in causing or promoting tumor in rodents. Yet more than 50,000 synthetic chemicals/formulations remain untested so far.

Scope

This method is suitable for most OPs, OCs, SPs, and herbicides residue analysis.

Apparatus required

• Homogenizer
• Centrifuge
• Nitrogen evaporator

Principle

Acetone is used for extraction the most nonionic pesticide residue, and residue are partitioned from acetone to dichloromethane/hexane phase. After removing traces dichloromethane, final extract is made up with acetone. This extract can be determined by GC with selective detectors. Further for organochlorine and synthetic pyrethroids extract should be cleaned up using florisil column. And for determination organophosphate extract should undergo to charcoal-celite cleanup.

For the determination carbamates, the extract is subjected to C-18 solid phase cartridge clean up.

Principle

Pesticide residues in milk are derived from the intake of pesticide contaminated feed and fodder.

Scope

This method is suitable for most OPs, OCs, SPs, and herbicides residue analysis.

Principle

Pesticide residues are extracted from soil using a mixture of acetone/water in a soxhlet apparatus for 7-8 hours. This extract can be determined directly by GLC.

Scope: This method is suitable for most OPs, OCs, SPs, and herbicides residue analysis.

India is recovering from the euphoria of the Green Revolution and battling the residual effects of the extensively used chemical fertilizers and pesticides in the country’s soils. The decade from 1980 to 1990 alone saw the area under pesticides in India, increased a whopping 20-fold, from six million hectares to 125 million hectares. After a high annual consumption of nearly 75000 MT reached in the early ’90s, interventions in the form of Integrated Pest Management (IPM) practices have only now started to show a declining trend in the use of pesticides in India. Interestingly, India’s consumption of pesticides per hectare is low (0.288 kg/ha) when compared with world averages—0.5 kg/ha against Korea’s 6.60 kg/ha and Japan’s 12.0 kg/ha. According to the pesticides industry statistics, India spends US $3/ha on pesticides compared with US $24/ha spent by Philippines, US $255/ha spent by South Korea and US $633/ha by Japan. Yet, despite a comparatively low use of pesticides in India, the contamination of food products in the country is alarming. About 20 per cent of Indian food products contain pesticide residues above tolerance level compared to only 2 per cent globally. No detectable residues are found in only 49 per cent Indian food products compared to 80 per cent globally. A pesticide is any substance or mixture of substances intended for preventing, destroying, repelling or mitigating any pest. Though often misunderstood to refer only to insecticides, the term pesticide also applies to herbicides, fungicides and various other substances used to control pests.

Pesticides and their metabolites have received particular attention in the last few years in environmental trace organic analysis because they are regularly detected in food products, surface/ground waters and soil strata throughout the world as consequence of their widespread use for agricultural and nonagricultural purposes. So it is the need of the hour to study the levels of pesticides residues in plants, water and soil and their fate in environment after its degradation.

It would be necessary to work out tolerance limits of pesticides residues in/on crops, soil and water and the efforts, therefore, are directed towards various residue analytical methods like TLC, GLC and HPLC etc. which are suitable for the purpose.

A pesticides residue is any substance or mixture of substances in food, agricultural commodities or animal feed resulting from the use of pesticides and includes any specified derivatives such as degradation products and impurities that are considered to be of toxicological significance.

Pesticide residue analysis (PRA) may be defined as the quantitative and qualitative analyses of the representative samples drawn from agricultural field, market and environment for pesticides and their toxic metabolites.

Principle: Acetone is used for extraction the most nonionic pesticide residue, and residue are partitioned from acetone to dichloromethane/hexane phase. After removing traces dichloromethane, final extract is made up with acetone. This extract can be determined by GC with selective detectors FPD-P/NPD without cleanup. Further for organochlorine and synthetic pyrethroids extract should be cleaned up using florisil column. And for determination organophosphate extract should undergo to charcoal-celite cleanup.

Pesticides are used to control plant growth (herbicides), insects (insecticides), worms  (vermicides), bacteria (bacteriocides), fungi (fungicides), and other organisms. Almost without exception, pesticides are used to benefit humans by the control of unwanted species of plants (e.g. weeds in a lawn), disease-causing bacteria (e.g., Pneumococcus, the causative agent of pneumonia), disease-carrying insects (e.g. malarial or yellow fever mosquitoes) or in controlling destruction of agricultural products by disease-causing organisms (e.g., corn-borers, the virus of anthurium blight). Although they are by and large mostly beneficial, pesticides used both properly and improperly are also “resources out of place”, that is pollutants, that are subject to normal ecological processes.

10.1. Classification of pesticides

10.1.1. Based on organisms

Though a large number of insect pests are reported to attack mango, which cause considerable damage to mango crops in India. More than 492 species of insects, 17 species of mites and 26 species of nematodes have been reported to be infesting mango trees, about 45 per cent of which have been reported from India. Almost a dozen of them have been found damaging the crop to a considerable extent causing severe losses and, therefore, may be termed as major pests of mango. These are hopper, mealy bug, inflorescence midge, fruitfly, scale insect, shoot borer, leaf webber and stone weevil. Of these, insects infesting the crop during flowering and fruiting periods cause more severe damage. The insects other than those indicated above are considered as less injurious to mango crop and are placed in the category of minor pests. A brief description of the biology and control of major pests of mango is given below. Mango suffers from several diseases at all stages of its life. All the parts of the plant, namely, trunk, branch, twig, leaf, petiole, flower and fruit are attacked by a number of pathogens including fungi, bacteria and algae. They cause several kinds of rot, die back, anthracnose, scab, necrosis, blotch, spots, mildew, etc. Some of these diseases like powdery mildew are of great economic importance as they cause heavy losses in mango production. Major pests and diseases of mango and their control measures are discussed below.

3.1. Paddy

3.1.1. Thrips: Stenchaetothrips biformis (Thripidae: Thysanoptera)

6.1. Cotton

6.1.1. Leafhopper: Amrasca devastans (Cicadellidae: Hemiptera)

5.1. Groundnut

5.1.1. Aphids - Aphis craccivora (Aphididae: Hemiptera)