eChapters

Sulfate can have harmful effects on aquatic life in freshwaters, sulfate cause osmotic stress or specific ion toxicity in aquatic organisms, especially in soft waters where Ca2+ and Mg2+ concentrations are low. Egg fertilization and early embryonic development were the most sensitive developmental stages of whitefish to sulfate (Karjalainen et al., 2021).
Sulphate (SO4 2-) may be estimated by either turbidimetric or gravimetric methods (APHA, 1995)
1. Turbidimetric method is more applicable in the range of 1- 40 mg Sulphate (SO4 2-)/ L
2. Gravimetric method is suitable if the concentration of Sulphate (SO4 2-) is above 10 mg/ L
Turbidimetric Method (Range 1 - 40 mg/L of sulphate) Principle
Sulphate ion (SO4 2-) precipitated with barium chloride (BaCl2) in an acetic acid medium in order to form crystals of barium sulphate (BaSO4).
BaCl2 + SO4 2-+ BaSO4 (precipitate)
The formation of these crystals is increased in the presence of an acetic acid solution containing sodium acetate, potassium nitrate, acetic acid and magnesium chloride. The suspended barium sulphate (BaSO4) is measured by spectrophotometer and concentration of sulphate (SO4 2-) is determined by comparison of the reading with a standard curve. Minimum detectable concentration is approximately 1 mg (SO4 2-) / L.

Microbial transformations of sulfur (S) are even more complex than those of nitrogen because of the large number of oxidation states of S and the fact that several transformations of S also occur abiotically. Although a number of oxidation states of S are possible, only three are significant in nature, 2 (sulfhydryl, R–SH, and sulfide, HS-), 0 (elemental sulfur, S0), and 6 (sulfate, SO₄ 2-). The bulk of S Earth’s S is in sediments and rocks in the form of sulfate minerals, primarily gypsum (CaSO₄) and sulfide minerals (pyrite, FeS2), but the oceans constitute the most significant reservoir of SO₄ ^2- in the biosphere. A significant amount of S, in particular sulfur dioxide (SO₂), enters the S cycle from human activities, primarily the burning of fossil fuels.

Hydrogen Sulfide and Sulfate Reduction

A major volatile S gas is hydrogen sulfide (H₂S). Hydrogen sulfide is produced from bacterial sulfate reduction or is emitted from sulfide springs and volcanoes. Although H₂S is volatile, different forms exist depending on pH: H₂S predominates below pH 7 and the nonvolatile HS- and S^2- predominate above pH 7. Collectively,H₂S, HS, and S₂ are referred to as “sulfide.” Sulfate-reducing bacteria are a large and highly diverse group and are widespread in nature. However, in anoxic habitats such as freshwater sediments and many soils, sulfate reduction is SO₄ ^2- limited. Moreover, because organic electron donors (or H₂, which is a product of the fermentation of organic compounds) are needed to support sulfate reduction, it only occurs where significant amounts of organic material are present.

Sulphur (S) occurs in soil in both organic and inorganic forms. Inorganic S fraction may occur as sulphate (SO₄^2-) and compounds of lower oxidation state such as sulphide (S^2-), polysulphide (S_n^2-), thiosulphate (S₂O₃^2-) and elemental sulphur (S⁰). In well drained soils inorganic S usually present as sulphate. Under anaerobic condition (reduced or waterlogged soil) inorganic S mainly occur as sulphide and under extreme condition as elemental S form. Estimation of S carried out in two steps:

Sulphur (S) occurs in soil in both organic and inorganic forms. Inorganic S fraction may occurs as sulphate (SO₄^2-) and compounds of lower oxidation state such as sulphide (S^2-), polysulphide (S_n^2-), thiosulphate (S₂O₃^2-) and elemental sulphur (S⁰). In well drained soils inorganic S usually present as sulphate. Under anaerobic condition (reduced or waterlogged soil) inorganic S mainly occur as sulphide and under extreme condition as elemental S form. Estimation of S is carried out in two steps:

1. Extraction of different forms of S from soil by suitable extractant.
2. The filtrate is then analysed for S by the turbidimetric method.

The turbidimetric method is the most widely used one because of its simplicity and rapidity.

Sulphur in nature follows similar cycle as that of nitrogen and shares many common features with it. In soils, decomposition of organic matter releases major portion of nitrogen and sulphur bound in proteins, as cystine or methionine amino acids, or vitamins, etc. In proteins, on an average, for every 36 atoms of nitrogen one atom of sulphur is present. Mineralization supplies a large fraction of nitrogen and sulphur to the plants. Secondly, both nitrogen and sulphur have several chemical forms under different soil conditions (Table 8.1) and both are subject to microbial reduction. Thirdly, both can enter or leave soil in gaseous form and both are subject to some degree of leaching in the anionic form.

The One Nation One Subscription (ONOS) scheme is a cornerstone of India’s ambition to become a self reliant and developed nation by 2047 envisaged by Hon’ble Prime Minister Shri Narendra Modi Ji. The initiative is a significant step to enhance access to scientific and academic resources across the country. This initiative can positively impact Indian journal ratings and boost subscriptions by addressing several challenges listed below:
• Increased Access to Global Resources
• Enhanced Research Quality 118 | Promoting Excellence in Agricultural Sciences
• Support for Smaller Institutions
• Boost to Indian Journals
• Fostering Interdisciplinary Collaboration
By bridging gaps in resource accessibility and improving research output, ONOS can play a pivotal role in elevating the status of Indian journals on global platforms. While evaluating Indian Journals of Agricultural and Allied Sciences, comprehensive and inclusive databases with many characteristics listed below should be adopted so as to ensure equal focus and benefit from international exposure:
• The database should have regional and multi-lingual journals with proper translation or abstracting, interdisciplinary research output, more and new journals/technical reports/official scientific documents/conference proceedings etc, open access for smaller journals to ensure readily accessible cutting-edge research in agriculture
• The database should provide more nuanced metrics that value realistic impact and localized research contributions considering immediate practical applications
• The database should include a wide range of journals across diverse disciplines, including agriculture, forestry, veterinary sciences, and environmental science with more inclusion of regional and specialized journals, providing access to a broader spectrum of agricultural research
• The database should emphasis on journals from developing regions, which often publish research addressing local agricultural challenges. This diversity helps in showcasing research contributions from regions/countries with significant agricultural economies
• The database of agriculture-related journals should overlap with other related fields viz., environmental science, biology, and social sciences, reflecting the interdisciplinary nature of agriculture. This helps researchers access a more comprehensive set of resources
• The database have detailed subject areas, allowing researchers to pinpoint agricultural science journals within relevant subfields like:

Uncertainty is an inevitable character of any system where most of the contradictory factors are either unpredictable or unfathomable. The higher is the complexity, the lesser would be the resilience. Agricultural production system, as it is managed in Indian condition, is the most vulnerable one to a plethora of uncertainties. Mostly managed in an open air rainfed conditions, it has been exposed to weather and resource uncertainties, market volatility, poor access to technology and a fragile input delivery mechanism.

Objectives

1. To estimate and assess the general status of perceived uncertainty of farmers by scale and dimension

7.1 Summary

Never ever in the annals of human civilization, the importance of ecological resilience has become so important and imperative as we are perceiving now. Both the need and greed of food economics have driven the resource bases of our ecosystem, to a dilapidated and fragile status. By 2050 the world’s population will touch close to 9.5 billion and we have to scale up our food production 60% more then what it is right now. In India by 2040, we have to cross 450 million tons of our targeted food production to keep rhythm with population growth. By 2035 we are going to cross the population of China. Understanding the cascade of risks for climate change, as well as the vulnerabilities to these risks, is key to frame ways to adapt. Reducing vulnerabilities is key to reducing the net impacts on food security and nutrition and also to reducing long-term effects. Increasing resilience of food security in the face of climate change calls for multiple interventions, from social protection to agricultural practices and risk management..

When population pressure is soaring up, the need to produce more food from less and less available land and water, the issues of ecological resilience are coming up more swashbuckling and humongous. The aftermath of green revolution has contributed to achievement in food security on one hand, the other hand water has been contaminated and depleted, soil has been eroded with a sharp decline of organic carbon. We are losing 15 tons of topsoil per hectare per year and inviting a disruptive agro-ecosystem, the syndrome of which are quite vivid and prominent.

6.1 Summary

The study analyzed the economics of family migration decision and its relationship with urban informal sector and agricultural efficiency. The study is mainly based on primary survey, though various secondary data Sources have been consulted. The primary survey has been conducted in Birbhum district of West Bengal covering 300 households with equal share of rural and urban households. The selection of the district is mainly guided by the dominance of rural-urban migration and the wide prevalence of both agricultural and non-agricultural activities. By tracing the reasons of migration across the states of India, the study provides a vivid picture of the rural-urban migration in West Bengal and it is associated linkages with agricultural efficiency and urban informal sector. Sophisticated statistical and econometric tools have been utilized to justify the economic explanation of rural urban migration in West Bengal.

This chapter presents the conclusions of the research study. Based on these conclusions, recommendations relating to the effective implementation and management of Cyber Reference Service (CRS) in agricultural libraries in Maharashtra are made.

6.1 Introduction

The overall aim of this research was to investigate and analyze CRS in the Agricultural College and University libraries of Maharashtra. The study adopted a mixed-methods approach by combining quantitative and qualitative methods to achieve its aims and objectives. 

7.1. Summary
The planet rise at this moment cannot endure and conjure up any further stress and distress created by un-mindful modernization of agriculture. This situation has gone further complex with the unabated rate of urbanization. The natural resources which looked plenty some 50 years back, now is coming up something scant and degraded. We have to protect this planet; hence, we have to protect our agriculture by placing ecological resilience with its perfect balance and dynamics. In doing so, we need to manage and recycle energy, water, and biodiversity in such a way that the operating agro-ecosystem can perform for another centuries. This is a herculean task, it will only be possible when farmers and other citizens are participating elegantly and equally into the process, because farmers are not producing food for their own, rather they are feeding the entire civilization. Every year 15-20 tonnes of top soils are being eroded, the highest anytime; the sea level is rising at the rate 5-10 mm again it has become highest over the last decades and the prediction for rate of changes in rainfall and temperature contributing to global warming has been accelerate like anything. In addition to this, we need to feed 950 crores of population by 2050, while lands are getting fragmented, resources are fragile, and water is getting increasingly contaminated. Thus, CA is the only option to create a perfect balance between productivity with increase of ecological resilience, even within the cropping system by introducing crop diversification with leguminous crops and this is specially so when the biodiversity is also getting eroded. Water harvesting is the need of the hour as we can make our farm more energy parsimonious, we have direct whatever crop residues are produced in the soil echelon and making this concept a revolution into a reality we have to go in a massive way with bring awareness, creating policies, and mobilizing community to make our agriculture ever- green and ever- resilient.
On this context the present research has been conducted with the following objectives:

Agriculture is a fundamental human activity that depends intrinsically on natural processes, including soil fertility, water recycling, and pollination, and both nature and agriculture are increasingly suffering the negative impacts of climate change (EEA, 2019). At the same time, unsustainable agriculture also poses a major threat to biodiversity (Secretariat of the Convention on Biological Diversity, 2014), negatively affects the state of our soil and water, and is an important contributor to climate change (Jia et al., 2019).

Sunflower was introduced as an oil seed crop in India in 1967. The crop is now widely cultivated in all parts of India and in any type of situation. Sunflower belongs to Compositae family and the cultivated species is Helianthus annus spp. macrocarpus. Apart from the edible oil species, there are non-oily types, other edible forms and ornaments. Helianthus tuberosus gives the edible tubers.

Supervised classification is the technique to classify raster image in which prior information about the classes in the form of training sites is provided by the user. Training site represents a homogeneous area in a particular class. The spectral response pattern of training sites is used to classify the raster image.The pixels of raster imagewhich have spectral response pattern similar to that of training sites of a particular class are grouped in that class. As there is some variability in the spectral response pattern of a particular class, therefore, multiple training sites per class are taken for supervised classification. Supervised classification of raster images can be performed by various methods. Conventional methods include maximum likelihood classifier, minimum distance to mean classifier, and parallelepiped classifier. Now a days, machine learning algorithms are also gaining importance in this context. These classifying algorithms are first trained or calibrated using the data of training sites.This trained model is then validated on the independent datasets for accuracy assessment. If the accuracy of the developed model is of acceptable level, then that model is used for the classification of raster data.

In this chapter, we are going to discuss the execution of maximum likelihood classifier and few machine learning techniques for supervised classification of raster image in R software. The training sites used in this exercise are in the form of points shapefile. The raster image is classified into six classesi.e. built- up, fallow soil, riverine sand, salt-affected soil, vegetation, and water. For performing this exercise, first of all,set the working directory and import the required packages.

Abstract
Food insecurity and malnutrition are on the rise globally, impacting millions, especially in rural regions where extreme poverty and food insecurity are deeply rooted. Vulnerable groups, including women, youth, and indigenous peoples, are disproportionately affected. Producing foo  that meets dietary needs and ensuring its availability in the future is essential for sustainable development and food sustainability. Addressing the growing global food security concerns and supporting the increasing population requires the continual expansion of plant-based proteins’ significance. Legumes are excellent sources of proteins, carbohydrates, and both soluble and insoluble dietary fibers. Legumes, with their high dietary fiber and low-fat content, help maintain body weight and lower the risk of cardiovascular disease. They are also rich in essential minerals such as potassium, calcium, magnesium, phosphorus, and iron, and provide important vitamins like folate, thiamine (B1), riboflavin (B2), and niacin (B3). Additionally, pulses contain various phytochemicals, including phenolics, flavonoids, phytates, lectins, tannins, saponins, oxalates, enzyme inhibitors, phytosterols, and antimicrobial peptides, which offer numerous potential health benefits. These phytochemicals exhibit anti-inflammatory, anticancer, antimicrobial, and anti-ulcerative properties. Incorporating legumes into agricultural systems can foster more sustainable and climate-resilient farming practices. In developing countries, legumes are often used to supplement cereals or starchy foods to combat protein-energy malnutrition, as animal proteins tend to be expensive in these regions.
Keywords: Antioxidants, Food security, Legume, Malnutrition, Healthy diet

The advancement of agricultural sciences depends on systems that are fair, inclusive, and innovative. The rating of agricultural journals requires unique considerations due to the interdisciplinary and regionally diverse nature of agricultural research. By addressing structural inequities, prioritizing accessibility, and fostering leadership, the global agricultural research community can ensure its continued relevance in solving the most pressing challenges of our time (Fig. 17.1).
This book has explored the multifaceted issues facing agricultural sciences, offering a comprehensive roadmap to create systems that uphold the highest standards of equity, innovation, and collaboration.
17.1. Reforming Journal Ratings
A key pillar of advancing agricultural sciences lies in the reform of journal rating systems. Current systems often rely heavily on impact factors, a metric that, while useful, is not comprehensive. By moving toward a multidimensional evaluation framework, we can prioritize relevance, diversity of contributions, and societal impact alongside citation metrics. Reforms could include:
• Incorporating qualitative assessments of journals, such as their contributions to underrepresented research areas or regions.
• Promoting open-access journals that adhere to rigorous peer-review standards.

4.1 Determination of Specific Surface Area of Soil

Specific surface area of a soil is defined as surface area per unit weight of soil and is expressed as m² g^-1. The specific surface of soil greatly influences the physical and chemical properties such as retention of water at high suction, swelling, plasticity, soil strength, cation exchange capacity and availability of nutrients. The basic principle of determination of specific surface is based on the amount of gas or polar liquid required to form a monomolecular layer on the soild. Knowledge of molecular size (diameter) and the mass of the adsorbate enables one to calculate specific surface of the adsorbent.

Principle

Dyal and Hendricks (1950) introduced a method for estimating specific area based upon the adsorption of ethylene glycol (EG) to form a monomolecular layer over the entire soil surface. The method involves adding EG to pretreated soil or clay sample and evaporating the excess EG in an evacuated system. The quantity of EG retained at the moment the evaporating rate decreases is proportional to the surface area. Later on Carter et al. (1965) suggested the use of ethylene glycol monoethyl ether (EGME) having high vapour pressure at room temperature than EG for determining surface area of the layer silicate minerals and soils.

Abstract

The state of Tamil Nadu has a low easterly gradient slope and there are number of rivers, big and small originate from the west flow towards east south easterly and confluence the Bay of Bengal. These were grouped into seventeen major and minor river basins, the Cauvery being the largest basin and the river is also a near perennial river. These river basins receive rainfall both from the southwest and northeast monsoons. The state has over 40,000 surface water bodies and number of major dams and reservoirs. Even then, since the rainfall of the north east monsoon, the major source of water source to these basins, occurs in short span of few days with high rainfall, neither adequate storage is there to store them nor the recharge possibility is available, thus all leading to flooding and wastage. The 40,000 and odd water bodies are heavily silted and polluted too. The paper provides an over view of all these, basin wise, and in addition, strongly advocates intra state river linkage and improvised irrigation management as the best option to save the state from its water deficiency.

5.1 INTRODUCTION: THE PHYSICAL CHEMISTRY OF COLLOIDAL SUSPENSIONS

This chapter is concerned with understanding the factors which influence the partition of ions between solid surfaces and aqueous solutions. There are many aspects of soil science such as some of those concerned with soil formation, transfer of nutrient ions from soil particles to plant roots, soil pollutant interaction and soil management which are critically dependent on what happens in the space of the order of 1 nm wide between solid and equilibrium solution. A broad survey of the development of ideas on soil-electrolyte interaction shows that there have been two main avenues of approach. One views the soil as an electrically charged surface with its adsorbed hydrated ions as one phase in equilibrium with solution, which is seen as the second phase. The other approach focuses on the electrical double layer extending from the charged solid surface out into the solution. In the latter approach the solid surface, the outer equilibrium solution and the make up of the transition zone between these two phases must all be involved in any detailed consideration of the micro structure of the system. For a full and proper understanding of soil-electrolyte interaction anything less than a detailed analysis of the micro-structure is likely to be inadequate and in this it must be remembered that the interaction between electrical double layers which overlap with one another is likely to be important.

4.1 INTRODUCTION

It has been suggested that the relationship of surface chemistry to soil science is similar to that of biochemistry to biology. Certainly the fact that surfaces of soil particles are extensive and reactive leads to a dominance of surface chemistry in soil behaviour, but it is not an exclusive relationship, because many precipitation reactions, oxidation and reduction processes, and biological reactions take place more or less independently of the surface processes. Nevertheless it is difficult to understand soil properties fully without an appreciation of the nature and extent of the surfaces of the soil constituents, and this chapter is devoted to a discussion of this topic.