eChapters

1.1. What is Earth?

The Earth is a layered body consisting of three parts: core, mantle, and crust. The radius of the Earth is nearly 6370 km of which crust, mantle and core share a depth of 40, 2850 and 3480 km, respectively (Figure 1.1). Exterior of the Earth contains the outer lithosphere which is surrounded (70% of surface) by water (hydrosphere). Solid and liquid sphere are surrounded by gas (atmosphere). The atmosphere is of 320 km above the lithosphere / hydrosphere. It is believed that there is a progressive increase in temperature with depth, if one goes to the core from the Earth crust. There is a rise of approximately about 1°F for every 64 feet depth on an average. Therefore, one could imagine that the interior of the earth is in molten condition.

2.1. Minerals

Primarily, minerals are usually inorganic substances possessing a definite chemical composition and a definite molecular arrangement which is usually expressed in geometric form. The mineral matter is made up of various elements, combined to form compounds. Usually, minerals consist of more than one constituent elements. Quartz contains two elements, silicon and oxygen. Other minerals may contain many elements, such as amphibole consists of several elements that include sodium, calcium, magnesium, iron, aluminium, silicon, and oxygen. Some elements exist as such without forming compounds. They contain exceptionally one element. Graphite (C), diamond (C), and Sulphur (S). Minerals are naturally occurring crystalline solid where the atoms are arranged in a regular three-dimensional array. A crystal is a solid, formed by a repeating three-dimensional pattern of atoms, ions, or molecules & possessing fixed distances between the different parts. Minerals that do not grow in these regular or crystalline patterns are called amorphous solids. When we talk about ‘naturally occurring’, we exclude the laboratory-synthesized crystalline solids. Glass and amber are also naturally occurring solid, but they are not crystalline and thus, they are not considered as minerals, rather they are referred as amorphous solids.

3.1. What is weathering?

Weathering may be defined as the transformation process of solid rocks, involving the disintegration and decomposition of rocks and minerals, into soil.

There are different types of weathering: physical, chemical and biological.

3.1.1. Physical weathering

In physical weathering the chemical composition of the weathered products remains same as that of the parental rocks. It is involved in fragmentation of rocks into comparatively smaller sizes. It does not transform the parental rock into a newer one that may differ from the parental rock in chemical composition. The process is totally physical in nature. But this is also true that physical weathering encourages chemical weathering, and both may be carried out simultaneously because physical weathering promotes more surface area of parental rocks for more interaction with agents of chemical weathering.

4.1. What is pH?

pH is used to classify substance as acidic, neutral and alkaline, based on the prevalence of free H⁺ ions. Water molecules on autoionization dissociate to produce H⁺ and OH^- in equal number, although degree of dissociation is very small because of its stability (about one molecule in 10 million is ionized at any one time). H⁺ ions later attached to un-ionized water molecule to give rise hydronium ions, (H₃O)⁺

5.1. What is soil organic matter?

Plant and animal residues which are not yet added to the soil are considered as organic materials. However, once they are added to soil, they become soil organic matter. Therefore, organic materials contributing to the soil matrix are referred as Soil Organic Matter (SOM). Sometimes SOM is also used to highlight only the non-living organic materials produced by living organisms. But SOM should be regarded as a broad term that includes biomass, partially decayed residue, and highly decomposed and transformed organic substances, humus. Agricultural soil contains nearly 1-5% of SOM, which is regarded as least amount in soil as compared to other three soil components, minerals (45%), air (25%) and water (25%). However, it contributes enormously to soil productivity. Soil productivity and fertility exhibit direct positive relationship with SOM content in soil. Plants and animals are considered as primary and secondary sources of soil organic matter, respectively. Plant residues and application of organic manures e.g., farmyard manure, compost or green manuring help to build up organic matter in soil and thus, enrich the soil with organic carbon and other plant nutrients. Under natural conditions, roots of grasses in grasslands, the leaves including shoot portion of the large trees in forest lands and after harvesting the crop remnants in agricultural field provide enough incorporation of organic materials in soil. SOM plays a vital role to maintain sustainability in agricultural production through producing healthy soils and thus, healthy crops.

6.1. What is colloid and colloidal system?

A colloidal particle may be defined as a substance which is microscopically dispersed evenly throughout another phase and is possessing a size of 10^-7 to 10^-3 mm and representing a larger surface area per unit mass. Thus, a colloidal system refers to a two-phase system in which small particles of one phase which might be of solid, liquid or gas is suspended evenly in the second phase of solid, liquid or gaseous material. These colloidal systems may be of solid in liquid or solid in gas or liquid in liquid or liquid in gas. Unique examples of liquid in liquid colloidal system includes the fat droplets dispersed in water of milk. When you put floor disinfectant liquid in water, it forms a white emulsion. Thus, emulsion becomes a colloidal system of liquid in liquid. Likewise, in fog, water droplets are suspended in gaseous air. So, fog is an example of a colloidal system, constituting of liquid dispersed in gas. When we refer smoke, it contains carbon particles (solid) suspended in air (colloidal system of solid and gas). However, smog is composed of smoke and fog. In case of soil colloidal system, soil colloids, which are of tiny particles (<0.001 mm size) and may be of organic and inorganic nature, are suspended in soil solution (water) and referred to as sol. Colloidal chemistry, which involves in the surface reactivity and charge characteristics of colloids, plays a pivotal role in total soil chemistry.

7.1. Introduction

Like all other living organisms such as humans, animals, and microorganisms, plants also need elemental nutrients for their growth and development. They assemble the nutrients from soil, water and air. However, to obtain economical crop yield, nutrients are also supplied to the crops from external sources such as chemical fertilizers and manures and using biofertilizers. It is the present-day need to handle the soil fertility status in a more realistic and careful way to obtain maximum crop harvest. Under poor management practices, soil may become infertile and loose its importance in agricultural use. In modern days, huge food demand for the burgeoning human population does not permit to show luxury to use only fertile soil. Moderately fertile soil or even degraded soil should also be managed properly so that they may be used to grow crops. For this, plant nutrients status of the soil plays a significant role along with other soil properties. For sustainable soil fertility management, parameters such as crop to be raised, its nutrient demand at various growth stages, current nutrient status of the soil, amount of nutrient application based on the soil testing results etc are important to be considered. Balanced nutrition to the plants is the prerequisite to obtain maximum benefit. If nutrients supplied to the plants are low in quantity than their requirement, crop production is lowered down. Similarly, if the nutrients are provided in more amount in the soil or unbalanced way through fertilizer or manure applications, total crop yield is suffered. It is a very common example that excess of phosphorus leads to zinc deficiency in most crop plants and it has been observed that excess N is responsible for potassium starvation in potato. Again, excess of iron, manganese, zinc, copper shows plant toxicity. Addition of nutrients to soils in excess also causes environmental pollution when the excess nutrients are lost from soil by leaching, surface run-off and volatilization. Unscientific way of soil fertilization leads to increasing cost of cultivation and imparts adverse effect to the environment instead of doing any good. Therefore, one should have a clear knowledge on soil fertility to obtain a sustainable productivity.

8.1. What is an ion exchange reaction and its application in soil system

Ion exchange is a reversible chemical reaction between two substances, either between two electrolytes or between an electrolyte solution and a solid complex as well as between two solid phases (if in close contact with each other), where ions of equal charge may be interchanged in equivalent proportion.

Organic colloids and inorganic micelles (clays) are sites of ion exchange. Soil contains silicate clay minerals which exhibit charges due to isomorphous substitution as well as due to the pH dependant charges for ionisation of hydrogen and hydroxide functional groups. Organic matter present in soil also contributes to the pH dependent charges due to the presence of various active functional groups. Thus, the organic and inorganic colloids present in soil bear positive or negative charges. Electric charge on soil particles is neutralized by equivalent amount of oppositely charged exchangeable counter ions, held by coulomb forces and van der Waals forces. Ca⁺², Mg⁺², H⁺, K⁺, Na⁺, NH₄ ⁺, Al⁺³, Fe⁺³, Fe⁺², Mn⁺², etc. are the common cations present in soil where Ca⁺² serves as the dominant ion. However, Na⁺ and Al(OH)₂ ⁺ are the dominant cations found in the exchangeable phase in strong alkali and strong acid soils, respectively. SO₄ ^- 2, Cl^-, HCO₃ ^-1, NO₃ ^- etc. are the most common anions found in soil to neutralize positively charged soil colloids.

9.1. Introduction

Soil biology is a branch of science that studies the soil inhabiting organisms in relation to their ecology, functions, behaviour and impact on various soil processes and plant growth. Soil fertility is directly dependant on humus content as well as the presence of microorganisms in soil, although surface soil does not contain more than 0.5% by weight of living organisms. However, such a small portion of soil constituent as compared to other organic and inorganic constituents plays a significant and major role in transformation of plant nutrients from their unavailable to available form from organic wastes, soils and fertilizers. They have a direct role in improving soil tilth, providing an appropriate environment for root growth, decomposing organic residues to form humus and in turn releasing nutrients for plants use, releasing many plant growth promoters, fixing inert atmospheric nitrogen in plant usable forms and they promote many other important processes without which plants cannot survive. Absence of living organisms in soil leads to its infertility. An understanding of microbial processes in soil environment, keeping in view of soil nutrient status, carbon sequestration, soil health and quality, overall sustainability in agriculture and also global warming in respect of greenhouse gas emissions (nitrous oxide and methane) through agricultural practices, is very important in regulating nutrient release at different plant growth stages. If we are in a state to understand how various biological processes influence various changes in soil environment or in the opposite way that how different soil conditions alter the soil biota in number as well as in their functions and diversity, it is easier to implement soil management practices that promote to gain more benefits.

Microorganisms are ubiquitous in nature. Possessing a diverse habitat, they are found everywhere in soil, air and water at a varied temperature and pH. One may find the highest genetic diversity of life within the domain of microorganisms. But unfortunately very few are known to us, so far only 1% of the microbial species on the earth are culturable. However, it is believed that soil of one gram may contain hundreds of millions to billions of microbes which may represent several thousand microbial species. In respect of the population, bacteria top the list followed by actinomycetes, fungi, algae and protozoa in accordance with a decreasing numerical order. Out of three important soil fertility components viz. physical, chemical and biological; the biological component is least understood due to its wide complexity.

10.1. Introduction

The soils possessing characteristics that are not suitable and economical for crop growth are termed as Problem soils. These characteristics may be of physical, chemical and biological. For cultivation of crops in these soils, it is necessary to follow specific management interventions and proper reclamation measures. Frequently we come across another term, ’degraded soil’. Degraded soil is also a problem soil. However, there exists a hair-line difference between problem and degraded soil. Problem soils refer to the soils in which the inherent soil characteristics, obtained from its genesis, pose problems for their optimal use, while degraded soils are developed due to anthropogenic activities by unwise management interventions.

10.2. Types of problem

Mainly there are four types of problem that may exist in soils: physical problems, chemical problems, biological problems and nutritional problems as a result of physical, chemical and biological constraints in soils.

11.1. What is acid soil?

Acid soils refer to those soils that are characterized with the presence of higher concentration of H⁺ in soil solution and at exchangeable sites or characterized with its high proton donating capacity such as aluminium (Al³⁺) on hydrolysis gives rise to proton. Both H⁺ and Al³⁺ are responsible to contribute soil acidity. Al³⁺ causes soil acidity indirectly by generating H⁺ through its hydrolysis, while H⁺ contributes directly. Therefore, due to more abundance of H⁺, they exhibit low soil pH and low base saturation (Ca²⁺, Mg²⁺, Na⁺ and K⁺). Such soil is considered as problematic soil because plant growth is affected adversely under acidic conditions and they suffer root injuries when grown in acid soils. Besides, soil acidity interferes in the soil nutrients availability to plants, making them either deficient to plants (such as phosphorus, calcium, magnesium, molybdenum) or toxic to plants for their more availability. Under acidic condition, Al, Mn and Fe are found in more soluble form. Thus, they are taken up by the plant in such a higher level that they become toxic to plants. Phosphorus becomes immobile due to the formation of insoluble compounds with aluminium and iron under acidic conditions. Ca, Mg and Mo also become unavailable in acid soil and show their deficiency symptoms. Soil acidity also affects soil microbial growth and thus, in turn, affects the nutrient dynamics in soil. Soil acidification is induced heavily under intensive agricultural practices such as increasing leaching due to more irrigation practices, addition of fertilizers, build-up of soil organic matter and many other possible ways.

12.1. Introduction

All soils invariably contain soluble salts. However, physico-chemical and biological soil properties start degrading when excessive amount of salts are accumulated in soil, particularly in rhizosphere, due to several anthropogenic activities and environmental conditions, and crop production is severely affected. Then we refer those soils as salt-affected soil.

The need of intensive agriculture to keep pace with the increasing world population for their food requirement necessitates to bring more agricultural land area under irrigation. However, irrigation system without taking enough drainage provision and poor water quality and its poor management may make the situation worst due to the development of salt-affected soils that ensue unproductive soil and low crop yield. Crops grown on salt-affected soils suffer from high osmotic stress, nutritional disorders due to nutrient (N, Ca, K, P, Fe, Zn) deficiency, specific ion toxicities, poor soil physical conditions and as a consequence, a reduced crop productivity.

Although it is considered that the rocks and minerals on weathering lead to salt accumulation in the soil, but the salt-affected soils are not truly originated from the accumulation of such salts in situ. On the contrary, occurrence of salt-affected soils is due to receiving salts that come from other locations with water. Sea water inundation in coastal belt, irrigation with poor quality water including saline groundwater, poor drainage system, irrigation adopting unscientific ways leading to waterlogging, shallow water table etc. contribute heavily toward development of salt-affected soils. Salt-affected soils may occur under almost all climatic conditions. Their distribution, however, is relatively more extensive in the arid and semi-arid regions compared to the humid regions because of poor precipitation to leach soluble salt adequately. Since evapotranspiration greatly exceeds precipitation in these climatic conditions, the soluble salts move upward with water due to capillary action and are left behind on the surface soil and the rhizosphere, once water is evaporated. The commanding ions of accumulated salts in affected soil are sodium, potassium, magnesium, calcium, chlorides, sulphates, carbonates and bicarbonates. The nature and properties of salt-affected soils are so diverse that they require specific approaches for their reclamation and management. Therefore, it is necessary to know their origin, formation, nature, chemistry and properties in detail to classify them into groups for their proper management to maintain sustainable agriculture.

13.1. Introduction

Water is chemically benign. However, its interference in free gas exchange in soil becomes detrimental to crop growth when soils are subjected to waterlogging or plants are submerged with water.Waterlogging of soil refers to a soil condition when the soil attains a moisture regime to such an extent that oxygen is not available in the pore space in enough quantity for plant roots to respire adequately. On the contrary, detrimental gases such as carbon dioxide, methane, hydrogen sulphide, ethylene etc. accumulate in the root zone and adversely influence the growth of plants. Thus, anaerobic condition prevails in waterlogged soil causing depletion of oxygen and increase of CO₂ in root zone, which severely affects aerobic micro-organisms while harmful organisms proliferate and restrict the plant growth. Waterlogging leads to nutrient deficiencies or nutrient toxicities, root tip decomposition and eventually, reduced growth or death of the plant. Physical, chemical and biological activities in the soil are also disturbed due to low temperature. However, this is important to note that plants differ among themselves in their demand for oxygen. Even oxygen demand for same plants differs with its growth stage. Therefore, it is well understood that there is no universal level of soil oxygen that can identify waterlogged conditions for all plants. Mostly waterlogging prevails in the land due to non-permeability of the soil material, the presence of an impervious layer in soil horizon, or a high-water table.

14.1. Introduction

Environmental pollution primarily deals with five types of pollution: soil pollution, water pollution, air pollution, sound pollution and light pollution. However, soil, water and air pollutions are considered very important as the pollutants from the environmental compartments may be cycled within themselves, enter the food web and interfere the biological processes adversely of any living species. Soil supplies nutrients and water to plants which, in turn, act as the nutrient supplier to animals and humans. Thus, maintenance of soil quality is considered prerequisite for growth of plants, animals and humans. If soil, water and air are polluted through various mechanisms, living components in the environment are suffered adversely. Soil, water and air pollutions are associated with the build-up of soil contaminants such as toxic organic and inorganic compounds, petroleum hydrocarbons, radioactive materials, salts, disease causing agents etc. above the permissible limit, so that their presence will cast adverse effects on physicochemical and biological properties of soil which in turn exert negative impact on crop growth and on any non-targeted organisms. Common soil contaminants include heavy metals, pesticides, petroleum hydrocarbons, fertilizers if used in excessive amount, and many others. Contamination of the soil, air and water results from intensification of farming activities. Primarily nutrients (particularly nitrogen and phosphorus), sediment, wastes, pesticides and salts are regarded as agricultural nonpoint source pollutant. Realistically, most of the pollutants originate from anthropogenic activities, although there exists many naturally occurring mineral components that may exhibit toxicity towards living system at higher concentration. Land disposal of municipal and industrial wastes, automobile emissions, mining activity, and application of fertilizers and pesticides to agricultural field cause a continuous accumulation of heavy metals and other pollutant components in soils. These pose threats of environmental degradation via soil erosion, loss of biodiversity, climate change etc.

Soil sampling is the first step of soil analysis. As very small fraction of the huge soil mass is used for analysis, it becomes extremely important to get a true representative soil sample of the field.

Accumulation of nutrient elements in plant tissues indicates the accessibility of the concerned elements from the soil to the plant. Although different plant species and even different varieties of the same species may vary in their nutrient requirements, composition of a part or of the whole plant may well be adopted as a guideline to support the soil-test results for factual assessment of soil’s nutrient supplying power.

The quality of irrigation water is a crucial factor for long-term soil productivity. Poor quality water if used for a long time can make the soil less productive or even barren, depending on the amount and type of constituents present in it and the texture of the soil in question. Low or marginally saline waters sometimes appear to stimulate crop growth because of the higher amounts of nutrient ions present.

A pH meter is very commonly used for the measurement of the reaction of a solution or a medium. The pH determination with the help of a pH meter is based on the measurement of the electromotive force (e.m.f) of a pH cell consisting of an electrode sensitive to W ions and a reference electrode.

Soil testing identifies various constraints in soil that limit crop production. Fertilizer recommendation and soil management practices to be adopted are based on the soil test report. Soil testing starts with collection of soil samples from the field
and ends with interpretation of soil test results leading to necessary recommendations for increasing crop production.

Aim of the Experiment: The composite soil samples, collected, are air-dried and processed before analysis in the laboratory.

Soil texture is the relative proportion of sand, silt and clay in soil by weight. As per the classification of the inorganic soil particle by the International Society of Soil Science, diameters of the sand, silt and clay particles vary from 2 to 0.02 mm, 0.02 to 0.002 mm and less than 0.002 mm, respectively. There are 3 broad textural groups i.e sand, loam and clay and each broad textural group is subdivided into different textural classes depending upon the proportion of sand, silt and clay.

Pore space or porosity : Porosity is an index of the relative pore volume in the soil or volume fraction of pores. Its value generally lies in the range of 0.3-0.36 (30-60%). Coarse textured soils tend to be less porus than fine textured soil, though the mean size of individual pores is greater in the former than in the latter. The total porosity, in any case, reveals nothing about the pore size distribution which itself is an important property.

Primary particles tend to adhere under natural condition so as to form secondary unit called aggregates. It is very difficult to determine the diameter of the individual aggregated particle. So the mean weight diameter is calculated as a single value constant, which indicate the wetted average value for a group of aggregates.

The soil water plays an important role in the physical, chemical and biological activities taken place in the soil which directly or indirectly affects the crop growth. The water content of the soil can be measured by different methods. These methods are gravimetric method, neutron scattering method and electrical resistance method.

Field capacity may be defined as the amount of water held in soil after excess water has drained away and the rate of downward movement of water was materially decreased which usually taken place within two to three days after heavy rain or irrigation. In this condition water was moved out of the macropores and air has moved into take its place. 

Infiltration is the entry of a fluid from one medium into another. Soil water plays an important role in nature. The entry of rain or irrigation water into soil is called infiltration. Infiltration rate is defined as the amount of water entering into a soil per unit area per unit time under one atmospheric pressure. The infiltration rate depends upon initial moisture content of soil, condition of soil surface and permeability of various layers.

The maximum water holding capacity is the amount of water, expressed as percentage on oven dry basis held by a soil when it is completely saturated with water. At this moisture content, all the pore spaces are completely filled with water.

Determination of soil texture mainly depends on the complete dispersion of soil aggregates into their individual primary particles without triturating the particles themselves, accurate fractionation of the sample into various separates, sedimentation of different particles in the viscous medium as well as measurement of individual particle by the hydrometer.

Atomic weight of an element is defined as the relative average weight of its atom as compared to the weight of an atom of C12 (stable isotope) taken as 12 on the a.m.u. (atomic mass unit) scale.

Electrical conductivity of the soil is the quantity of electricity in coulombs that passes per second per cm3 of the soil solution under an applied potential difference of 1 volt. It is written as EC in abbreviated form and is expressed in millimohs cm-1 or dS m-1 (deciSiemen m-1). Current flows in the soil solution due to presence of soluble salts like Cl- , SO2- 4 and NO3 - of Na+, K+ Ca++ and Mg++. These salts fully dissociate in water to their constituent cations and anions and the current is carried by those cations anions in the soil solution.

In the detection of soil organic carbon a known weight of soil is heated with an excess volume of standard K2 Cr2 O7 in the presence of Con. H2 SO4 . The soil is slowly digested at the low temperature by the heat of dilution of H2 SO4 and the organic carbon in the soil is thus oxidized to CO2 . The highest temperature attained by the heat of dilution reaction produced with the addition of Con. H2 SO4 is approximately 12o C which is sufficient to oxidize the active forms of the soil organic carbon but not the more inert forms of carbon that may be present.

The lime requirement (LR) of an acid soil is the amount of lime needed to neutralize the acidity from an initial condition to some target soil pH, like 7.0. Different methods are used to calculate a LR for specific soils. Lime requirement tests will always recommend adding enough lime to neutralize all the acidity associated with soil pH, much of the salt-replaceable acidity, and some of the residual acidity.

The statement is still valid as long as it is understood that in an aqueous solution the substances involved are subject to dissociation, which changes the ionization state of the substances. 

The Kjeldahl method is mainly divided into three main steps. This method needs to be carried out in proper sequence. 

In Bray’s method a mixture of ammonium fluoride and hydrochloric acid (NH4F + HCl) act as the extracting agent. It works in two ways, firstly, the hydrogen ions from HCl have a solubilising effect, especially on Ca-P, which makes phosphate get extracted. Secondly, the fluoride ions (from ammonium fluoride) complex with the Al3+ and Fe3+ ions, thereby releasing the Al and Fe bound phosphorous into the extract.

Olsen P were found to bear a quadratic relationship, with Olsen’s extractant underestimating the content in phytoavailable P of soils with high Olsen P contents relatively to soils with low contents. The ‘‘change point’’ at which phytoavailable P began to increase rapidly per unit change in Olsen P was 53 mg Olsen P kg–1 soil. For the acid soils, a significant quadratic relationship was found between the amount of P desorbed to water and Olsen P at the three soil:solution ratios studied.

Potassium is extracted from the soil with the help of suitable extractant CH3COONH4 by shacking followed by filtration or centrifugation & is determined in the extract using flame photometer. The analysis photometer is based on the measurement of the intensity of characteristic lime emission given by the element to be determined .

Reagents

• Buffer solution : Dissolve 67.5 g of Ammo. Chloride in 200 ml distilled water. Add 570 ml Ammonium solution. The volume make up to 1 ltr.

• EBT : 0.2 g in 25 ml methanol.

Soil is shaken with 0.15 % CaCl2 solution. Chloride ions displace adsorbed sulphate during extraction. Calcium ions suppress the extraction of soil organic matter and hence eliminate the contamination caused by extractable organic S.

Soil is shaken with 0.15 % CaCl2 solution. Chloride ions displace adsorbed sulphate during extraction. Calcium ions suppress the extraction of soil organic matter and hence eliminate the contamination caused by extractable organic S.

Diethylene tetramine penta acetic acid (DTPA) being a chelating agent is used in the determination of available Fe, Mn, Cu and Zn. When the soil is shaken with a solution of DTPA, it combines with metal ions in the solution and form soluble complexes of Fe++, Mn++, Cu++ and Zn++. The CaCl2 and triethanolamine (TEA) solution slightly raise and buffer the soil pH and mitigates the effect of Ca++ and Mg++.

Procedure

• Take 1 g soil in a 50 ml beaker

• Add 25 ml 1M KCL solution 

Take 1 g phenolpathalin powder in a 100 ml volumetric flask. Then add volume up to 100 ml by ethanol (Ethyl alcohol).

Digestion Mixure : This is a mixture of two salt. That is potassium sulfate and cupper sulfate with 9:1 ratio (90 g Potassium sulfate + 10 g Copper sulphate).

100 ppm ‘P’ : By dissolving oven dry KH2 PO4 salt. Take 0.4393 gm of KH2 PO4 and volume to 1 ltr that gives 100 ppm ‘P’.

Take 5 ml/2.5 ml aliquot in a 25 ml volumetric flask.

6.25 HNO3 (for 2 ltr) : Take 181 ml of conc HNO3 and diluted to 2 ltr in a volumetric flask.

Aim : To determine the Calcium in plant sample.

Aim : To determine the Magnesium in plant sample.

The artificial intelligence (AI) world is quickly growing as it reaches several different industries. You currently will see AI used for many different purposes from agriculture to automotive; with the passage of time you will see even more of it. Agriculture is one of the most important branches of the IT industry. Agriculture is an important industry and is a big part of our economy’s base. In terms of annual sales, the agricultural industry contributes to our economy almost 17%.AI is becoming a technical advancement that boost and protects crop yield, as climate change and populations rise. Here in this chapter basics of Artificial Intelligence have been discussed how it can be related to agriculture.

1. Introduction

Artificial Intelligence has become most prominent in current generation. Every field is utilizing Artificial Intelligence for their better results and which also result in saving a lot of time. As Artificial intelligence is boosting different sectors to increase the productivity and efficiency and its utilization across different sectors like in the field of CIVIL Artificial Intelligence can be used to analyze the structures of buildings, dams etc., and Artificial Intelligence solutions are assisting in so many ways to overcome the traditional challenges in every field.

I. What is Artificial Intelligence

Artificial Intelligence is one of the most prominent field of Computer Science Engineering which attempts to redefine the tasks which are carried out by humans in their daily life with better results and maximum accuracy. Artificial Intelligence is actually meant to ease the work of human where the word artificial states the work done without any human interference and intelligence states the capabilities like human brain to perform tasks. The field artificial Intelligence has given so many definitions from time to time which can be typically stated as