eChapters

Soil fertility evaluation is conducted for providing an adequate supply of essential plant nutriens to ensure optimum plant productivity, while maximising economic benefits and minimising environmental degradation.
 
Mathematical modelling of nutrient application

The significance of an essential plant nutrient was contained in the Liebig’s law of minimum.

Abstract

In semiarid climates, a significant component of recharge to basin aquifers occurs along the mountain front. In this scenario Mountain Front Recharge study has been carried along the foothills of Courtallam ,Tamil Nadu. A total of 53 groundwater samples were collected along the foothills and measured for major cations and anions using standard procedure. Saturation index (SI) of carbonate minerals like Aragonite,Magnesite, Calcite and Dolomite,LogpCO₂ and Ionic strength obtained from WATEQ4F output. pH plays a significant role in the saturation index of the minerals. Most of the Carbonate minerals shows undersaturation  with the pH range 7.5. Positive relationship between SI and HCO₃ is noticed. A sharp increase of pCO₂ values towards the foothills region suggests that the groundwater has been recharged by, acquiring longer flow path during its infiltration into deeper level near foot hill region. The SI of these carbonate minerals was spatially distributed to identify the areas of higher SI and also it is compared with the water level fluctuation to understand the recharge process along the foothill region as well as riparian zone.

Abstract

The geochemical signature and vulnerability of groundwater of the East Coastal aquifers of  India from Pondicherry to Nagapattinam were determined. The coastal aquifers are fragile and this situation becomes more intense in aquifer systems like that of the Pondicherry to Nagapattinam region. A total of 136 water samples were collected during pre and post monsoon of 2008 and 2009 respectively. Out of which 45 samples for each pre and post monsoon from shallow groundwater and 23 samples for each pre and post monsoon from deeper groundwater.. The samples collected were analysed for major, minor cations and anions. Selected samples were also analysed for stable isotopes (d¹⁸O and dD). The analysed samples were studied for; their utility for different purpose, the nature of the geochemical classification, their variations in ion ratios, extent of sea water intrusion and the percentage of mixing, The study reveals that chief mechanism controlling shallow groundwater is the salts precipitated in the pore spaces during the Pre monsoon were leached and dissolved during the subsequent monsoon apart from sea water intrusion. Southern part of the study area  is more vulnerable than the Northern part of the study area.

Abstract

A total of 30 groundwater samples were collected in four different seasons (Pre Monsoon, South West Monsoon, North East Monsoon and Post Monsoon) from the coastal aquifers of Kalpakkam region of Tamilnadu. The samples were collected covering the seasonal and lithological variations to infer the influence of natural geochemical processes and anthropogenic sources on the groundwater chemistry. The collected samples were analysed for the parameters like EC, pH and Major ions. The saturation index of silicates and carbonates shows that state of saturation to over saturation, but the sulphate minerals is dominantly under saturated. In the inverse modeling three models are obtained using PHREEQC and the error percentage is noted as 7.45%.

Abstract

Deduction of overindulgence fluoride (F)  from the water has been endeavor by numerous investigators by using different materials both natural and artificial. The objective of this paper was to attempt the fluoride removal by using the locally available natural materials such as red soil, untreated charcoal, local powdered brick, fly-ash from Neyveli (thermal power plant) and mineral serpentine were used, adopting column method. Maximum defluoridation occurs immediately after the experiment has started. The morality of fluoride removed per gram is more in red soil when compared to the other materials. Variation of fluoride removal with time was studied after the erection of the column /unit, the defluoridation setup was then connected to the public water supply from the overhead tank of 50,000L capacity. Higher F removal was noted when flow rate was lesser. An attempt on the regeneration of the fluoride adsorbed soil was also made.

Fertilizer

Fertilizers are defined as materials having definite chemical composition with a high analytical value that supply essential plant nutrients in available form. They are usually manufactured by industries and sold with a trade name. They are commonly synthetic in nature and also called as chemical fertilizers/inorganic fertilizers/commercial fertilizers other than lime and gypsum. Most of the chemical fertilizers are inorganic in nature.

Methods of fertilizer application

Two major methods are used to apply fertilizers  
I) Application of fertilizers in solid form 
II) Application of fertilizers in liquid forms

Toxic elements like Cadmium (Cd), Fluoride (F), heavy metals, radioactive metals are associated with mainly rock phosphates, other organic wastes like sewage sludge and pollutants. Their chemistry is similar to plant nutrients and replace them in their physiology leading to reduced uptake of nutrients, productivity and contaminated food chain.

Abstract

Coastal aquifers are the sources of freshwater which are being over extracted due to increase in population, agriculture and industrial activities. This over exploitation has resulted in decline in groundwater level and intrusion of sea water into the coastal aquifers making it unfit for human utilities. An attempt has been made in the coastal tracts of Pondicherry region using Electrical resistivity imaging. The survey has been attempted in six locations spread thought the study area and the interpretation has been attempted by RES2DINV software. The profile length attempted was between 150 to 300 m with electrode spacings between 5 to 10 m. The apparent resistivity ranges between 0.1 to 1183 & ohm. Sea water intrusion was prominent along the northern parts of the study area and lower resistivity isolated in kirumambakkam has been interpreted as salinity due to the presence of clay minerals. In nallavadu saline intrusion has been identified at shallow depth.

Abstract

A study on the Subsurface groundwater discharge (SGD) in the coastal Cuddalore region of south east India has been carried out. Measurement of surface water Radon, Water level, Electrical Conductivity (EC) and pH for a total of twenty four hours, by hourly interval the measurement has been calculated and promote correlated with tidal values calculated by WX Tide 32 software. The SGD measurements were made by using a modified seepage meter. The study reveals a match with water level variation and tide with minor variation due to influx of surface water. Saline discharges, fresh groundwater discharges and surface water mixing processes were identified along the coast. Lower SGD (37.24 – 79.16 cm/day) were observed during fresh groundwater discharge.

Abstract

A study on colloids in groundwater and its relationship with the geochemical parameters is reasonably essential because of its facilitating nature to transport radionuclides in groundwater. Colloid sampling has been carried out in the coastal aquifers of southeast coast of India. Two different bore wells were selected based on the distance from the coast to collect groundwater samples. On the basis of the result achieved from this study, a reliable representation is emerging. The values of pH and EC are governed by the different size fraction of colloids. In this study, the relation between different size fractions of groundwater colloids and its pH, TDS and EC were carried out. These parameters were analyzed in the lab and its influence with four fractions of colloid like 1.2, 0.8, 0.45 and 0.22 µm have been discovered by smooth scatter plot. The accumulation of particles weighting by normal weighing instrument. There is an higher accumulation of particles found in Kalpakkam than Anupuram in all the size fractions. For separation of particles high frequency pressure was used by ultrasonic cleaner had been carried out. This method is very simple and more reasonable than any other methods.

Abstract

In Gadilam river basin, groundwater is found in both hard rock and sedimentary terrain and is the most important source of rural/urban drinking water supply. Gadilam river basin has gained its importance due to the presence of Neyveli Lignite open cast mine (NLC), group of industrial estate (SIPCOT), extensive depressurization of Cuddalore aquifer and boreholes of New Veeranam Scheme (NVS) in the downstream of the basin. A total of 178 water samples were collected in four different seasons at various lithologies. The collected samples were analyzed for various physico-chemical parameters using standard procedures. Geochemical indicators of groundwater were used to identify the chemical processes that control hydrogeochemsitry. Interpretation of hydrogeochemical data suggests that leaching of ions followed by weathering and anthropogenic impact controls the chemistry of the groundwater. Isotopic study reveals that recharge from meteoric source in sedimentary terrain and rock water interaction with significant evaporation prevails in hard rock region. This thorough understanding helps us to make judicial usage and to maintain the quality of this commodity.

Many farmer participatory field  experiments were designed and conducted in different states of India having large area under acid soils, with locally available soil ameliorants to study their effect on soil health and crop performance. This work was done during 2000 & 2005 under an ICAR network project on “Soil characterization and resource management of acid soil regions for increasing productivity”. The details of the field locations are presented in table 1.

The state of Odisha located in the Coromondal coast of India has a tropical monsoon climate characterized by high humidity, high rainfall (1497 mm) and short and medium winter. It is the 10^th largest and 11th most populous state accounting about 5% of the geographical area and 4% of the population of the country. The geographical area of the state is 15.57 m ha, out of which 0.62 m ha is arable land. Agriculture contributes 28% to  state domestic production and employs 64% of the work force.

The adjustment and maintenance of soil pH at a value suitable for optimal crop production is the first step in soil management, because soil pH affects soil properties, nutrient availability and plant nutrition. In India, about 30M ha cultivated  land  suffer from high soil acidity (pH < 5.5). These soils are critically degraded and are of poor health producing crop yields, which are often less than 50% of that in normal soils. Due to this, farmers use much less fertilizers for crops (50 to 80 kg NPK ha^-1), since this is not profitable.

Abstract

The development and management of fresh groundwater resources in coastal aquifers are seriously constrained by the impact of seawater intrusion. The coastal aquifers are fragile and this situation becomes more intense like that of the coastal Cuddalore region. The geochemical signature of groundwater of Cuddalore coast was studied for Pre Monsoon, Southwest, North east and Post Monsoon seasons by collecting total of 64 groundwater samples in each season. The collected samples from were analysed for physical parameters, such as electrical conductivity (EC), pH and major ion concentrations, such as Ca, Mg, Na, K, Cl, HCO₃, PO₄ and SO₄. Interpretation of analytical data shows the predominance of  Na–Cl type   in PRM and Ca- Mg-Cl type  is the dominant facies during POM. The Chaddas evaluation diagram shows that the hydrogeochemical evaluation plot for PRM samples fall in  Na-Cl type. The ratios of Na/Cl and Cl/HCO₃ is also enumerated the fact that the most of the samples from PRM and few samples from other seasons also indicates dominance of salt water intrusion.

Abstract

Aquifers are usually composed of permeable layers that can ways a considerable amount of groundwater. Usually, aquifer units are correlated through the concept of lithostratigraphy. For low-permeable aquifers, it is difficult to define the spatial distribution of hydrogeological units, and this study attempts to use geochemical methods to identify the groundwater flow paths in an area of Southeast coast of Tamil Nadu, India. Multiple geochemical analyses, including groundwater chemistry; stable isotopic compositions of d¹⁸O and 8D contents were performed.  Spatial distribution of d¹⁸O, dD, Cl-/HCO-₃ show that northeastern part of the study area seriously affected by seawater intrusion. The highly permeable aquifers at the east coastal region are characterized by high hydraulic conductivity as compared with other regions of the study area. Hydrogeochemical characteristics based on bivariate diagrams of major and minor ions show that changes in the chemical composition of groundwater are mainly controlled by the salinization process followed by cation-exchange reactions.

Abstract

Dissolved Organic Carbon (DOC) consisting of water soluble organic molecules and by products of organic decomposition and chemical degradation processes, constitutes a critical link in carbon and nutrient cycles. The quality, or chemical and physical character, of DOC affects the degree to which it is transformed by biological and chemical processes. The significance of DOC was studied in layered coastal aquifers of the Pondicherry region during four different seasons. Pondicherry region has varied geological set up ranging from Cretaceous to Recent formations. A total of 52 groundwater samples were collected from various aquifers like Alluvium, Tertiary(Upper Cuddalore, Lower Cuddalore) and Cretaceous for two different seasons of pre- monsoon(PRM), and post-monsoon (POM). The samples were analyzed for major ions and DOC. The range of DOC in the study area is 0-14 mg/l. Very high DOC concentrations were measured during PRM in the samples from Alluvium and Lower Cuddalore Formation. The samples of these formations were compared with pH, Ionic strength, log pCO₂ and carbonate minerals concentration. The alluvial aquifer shows that pH governed dissolution along the coastal tracts and in Upper Cuddalore formation it’s based on interaction between aquifer matrix and groundwater.

Abstract

Groundwater is most favored as a source of drinking water in all over world. It is often thought to be cleaner and easier to treat when compared with surface water and as a result, many wells have been sunk. Uranium and other radionuclides in water can lead to health problems if present in higher concentrations. In order to study the behavior and to understand the influence of lithology in groundwater of Madurai district, a study was conducted by collecting a total of 216 samples of different seasons (Premonsoon, South west monsoon, Northeast monsoon and Post monsoon) with respect to lithology and the number of samples was depending upon their spatial coverage in the study area. The groundwater samples were analysed for U, Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃^-, Cl^-, SO₄^2-, PO₄^3-, NO₃^-, F^-, H₄SiO₄, pH, EC, TDS. It was identified that the higher concentration of Uranium (156 ppb) were noted in the northern part of the study area. They are chiefly restricted to the Granitic terrain and nearby Charnockitic regions. The weathering process induces the release of higher U ions from the granitic terrain and the evaporated recharge water from the tank /reservoir  also induces the release of U ions from the rock matrix, it may also be due to fertilizer enriched agricultural return flows. The key source for all these processes and hydrogeochemical processes is identified to be lithology which inturn controls all the other processes in the study area.

Introduction

Large scale exploitation of groundwater using modern deep well boring technology and powerful pumps is the order of the day in India and elsewhere. Increase in agriculture area and year around cultivation of water intensive crops, frequently failing monsoons (Fig.5.1) all have led to drying up of surface water and increased dependence on groundwater.

Thus, given the scenario of over exploitation of the available groundwater, it is essential that proper storage and management of available groundwater resources be identified.