eChapters

5.1 Introduction

Today, energy distribution and environmental issues have developed into international threats. Demand for alternative fuels increases every day due to rapid population growth, rising living standards, and economical sustainability. With its massive population, India has become the fourth largest energy consumer country in the world after the United States, China, and Russia. Because most nations use fossil fuels to fulfill their energy demands, they create negative impacts on the environment including raising global temperatures, pollution, acid rain, and other effects. As such, the quest for alternative fuels derived from renewable resources has captured significant attention throughout the world¹. Biomass as a renewable energy sources is an important asset for achieving economic development is due to the availability of biomass at a low cost, a good conversion efficiency, the addition of jobs, and an increase in the biodiversity^2,3. Typically, biomass is composed of cellulose (40-50%), hemicelluloses (25-35%), and lignin (15-30%). Large amount of resources for biomass are available such as woody biomass, crop residues and their by-products, food processing waste, municipal solid waste, aquatic plant etc.

In the present context, pyrolysis process has been received a remarkable identity as a potential method for the conversion of any organic biomass into valuable energy rich products due to its simple in operation and also required a reasonable cost for conversion process. Pyrolysis is the thermal decomposition of any organic material at a specific temperature in absence of air/oxygen; the process ends with three resulting products, namely liquid (bio-oil), solid (biochar), and syngases⁴. Recently, biooil produced through pyrolysis process and further it up grading has been attracted a significant attention due to its major use as biofuel and as a precursor material for making chemicals⁵. The pyrolysis process also classified in three different types as per its operating conditions; slow, fast and flash pyrolysis.

8.1 General

Pyrolysis is a process that utilizes heat or fire to separate biomass, derived from the ancient Greek words “pyro” meaning fire, and “lysis” meaning separation. A thermochemical conversion process transforms biomass into a useful intermediate liquid product. This product can then be converted into a hydrocarbon biofuel, oxygenated fuel additive, or a petrochemical substitute. Pyrolysis shares similarities with other thermochemical processes such as cracking, carbonization, torrefaction, destructive distillation, dry distillation, and thermolysis. However, it is not related to gasification, which involves chemical reactions with a gasification medium.

Introduction

Watershed management has emerged as an important research area in recent years. Understanding the morphology of the catchment is one of the widely used methods for watershed management. Morphometry is the measurement and mathematical analysis of the configuration of the earth’s surface, shape, and dimension of its landforms (Agarwal 1998; Obi Reddy et al., 2002). The study of watershed is very useful in drainage basin evaluation, silt erosion control, flood frequency analysis, watershed prioritization, natural resources management, and conservation (Waikar and Nilawar, 2014). The significance of morphometric analysis is highlighted in the basins that are either un-gauged or difficult to access. The morphometry is usually analyzed through measurement of linear, aerial, relief, gradient of channel network, and contributing ground slope of the basin (Magesh et al., 2012). The hydrological behavior of a basin can be easily determined through the areal parameters (Mahala, 2020.) The evolutionary history of any basin can be best understood through the implication of different relief morphometric measures of drainage basin (Sharma and Sarma, 2013).

GIS and RS techniques are proven convenient methods for morphometric characterization of sub-watersheds and prioritization of watersheds. As the satellite images provide a synoptic view of a large area, the RS and GIS methods become very useful in the analysis of drainage basin morphometry (Rai et al., 2017). Thus, the morphometric analysis using spatial techniques has emerged to be the fast and efficient method as compared to most of the conventional methods (Rao et al., 2010) such as manual extraction of drainage network and assigning the stream order from a published Survey of India topographic map. The present study aims at using remote sensing and GIS technology to compute various parameters of morphometric characteristics of the Chaliyar River basin.

This chapter sheds light on a geohazard namely quicksand. Unlike other geohazards, it waits for its victims to cause hazard. Though discounted as a myth and also as a monster problem in Hollywood film stories, phenomenon of quicksand is real and could inflict life threatening dangers. Analyses of genetic causes, associated properties and locales of its occurrences indicate that more deaths might have resulted due to panic and drowning in waters than by quicksand itself. Based on these inferences, potential mitigation measures are presented in this chapter.

INTRODUCTION

Quicksand, referred as “pudhai manal” in Tamil, is one of the lesser known dangerous natural phenomena that cause death of human and other unsuspecting animals. It is a geohazard of different sort. It is different in a sense that it never “goes” anywhere like tsunami or causes hazard like flood or landslide or any other geohazard; but it waits for hapless victims; that is., it is harmless until human beings or other fauna step into the region of quicksand. It is commonly prevalent in many river beds and other locales near water bodies located amidst dense forests. Many a deaths occur due to quicksand but go unnoticed owing to its “non catastrophic” nature. It is also a geohazard less understood pertaining to causes of formation, potential to cause damage and occurrence (www.mythbuster.com). This chapter is an attempt to review the existing literature on this geohazard for better understanding.

energy plants need to convert carbon dioxide and water into carbohydrates and oxygen. The carbohydrates produced by photosynthesis are used for vegetative and reproductive growth and to increase crop biomass. The solar energy required for photosynthesis is available during day time. In crop canopies radiation is transmitted through leaves and between leaves resulting in changes of spectral composition rapidly with depth. In the absence of vegetation, solar radiation reaches the earth surface after it gets depleted in the atmosphere due to:
• Reflection of incoming radiation by the cloud tops
• Absorption of ultraviolet radiation by the ozone present in the atmosphere and infrared radiation by the greenhouse gases and water vapour
• Scattering of radiation by the solid particles suspended in the atmosphere
The remaining parts of solar radiation called insolation i.e. incoming solar radiation reach the earth surface. After it is incident on the earth surface, a fraction of the solar radiation gets reflected back into the atmosphere. The difference between the incoming solar radiation and outgoing solar radiation is called net radiation. The net radiation can be calculated using radiation balance which takes into consideration both incoming solar radiation and outgoing solar radiation. The equation for radiation balance can be written as:

Radioactive pollution is largely attributable to radioactivity, a natural property of certain elements, such as radium, uranium, thorium, etc. of spontaneously emitting protons (alpha particles), electrons (beta particles), and gamma rays (short-wave electromagnetic waves) through the disintegration of their atomic nuclei (nuclides).

An alpha particle consists of two protons and two neutrons, which is akin to a helium nucleus. Alpha particles travel at a very slow speed, whereas gamma rays propagate at the speed of light. The alpha particles have less penetration power than the beta and gamma rays. In human tissues, alpha particles can penetrate up to a depth of about 0.005 to 0.008 cm. The gamma rays, on the other hand, are the most penetrating and can easily pass through a human body without striking anything in between. The high penetration power of gamma rays is because they have no charge; therefore, they do not interact with anything as the charged alpha particles would do

Abstract

The dating of fluvial landforms by archaeological, epigraphical, historical, thermo-luminescence, radiocarbon, etc. are of greater significance because it not only provides information on the date of origin of such fluvial landforms but also isostatic, eustatic, climatic histories of the Quaternary period. Hence, the Geoscientists have always been giving greater importance to the dating of the fluvial landforms. In India, the Cauvery is one such river studied for its migratory melodrama with the help of satellite data and inferred that the river Cauvery has earlier flowed along the Hogenekkal-Chennai tract (PCS-1-Palaeo Channel System-1) during 500 thousand to 3000 YBP (years Before Present), then migrated towards southerly and flowed along the present day paths of Thoppurar, Vaniyar and Ponnaiyar rivers (PCS-2) during 2700-2300 YBP and further migrated southerly and entered into Tiruchirappalli-Thanjavur plains after 2300 YBP and finally anticlockwisely migrated in different parts of the present day Cauvery delta and stabilized as river Coleroon during 2100-750 YBP. Such broad chronological history was brought out on the basis of archaeological, epigraphical, historical, literature and few radiocarbon dating. In the present study, more number of radiocarbon dating was done in various palaeochannels of river Cauvery which has over all coincided with above observations and further provided discrete information on (1) the southerly migration of river Cauvery from PCS-1 to PCS-2 after 8000 YBP, (2) tectonic arching and splitting up of channels in Chennai region during above period, (3) gradual younging nature of palaeochannels from PCS-1 of Chennai region to PCS-3 of Tiruchirappalli – Thanjavur region, etc.

Sensors onboard the satellite records the intensity of emitted or reflected electromagnetic radiations in the form of digital number (DN) for each pixel. These digital numbers can be transformed to more meaningful intensity units like radiance or reflectance. This process of conversion of digital numbers to radiance or reflectance is known as radiometric calibration. Sensor specific information is required to conduct radiometric calibration.

The Gujarat state is located on the north-west of India between 20^o6' N and 24^o42' N latitude and 60^o24' E to 74^o24' longitude. The climate of Gujarat is semi-arid tropical . the summers are very hot, the winter season is uncertain and irregular. The Arabian sea and Gulf of cambay have a moderating effect on the climate of the coastal areas of the state.

The state has a coastline of 1600 km (27% of the country) out of which Saurashtra and Kutch has about 1125 km long coastal line. The total coastal cropped area of the state is 8.75 lakh ha (9.11% of total cultivated area) spread over three agro-climatic regions of the state, out of which 91% comes under arid and semiarid climate type (Table 1). The important crops of the region are groundnut, bajara, sorghum, cotton, and wheat. The ground water availability is also scare. In the state recently the soil degradation through salinity has caught hold over 1.2 m ha of land, of which, about 0.3 m ha occurs in the coastal area. About 1125 km long coastal line is in Saurashtra and Kutch which comprises about 0.1079 m ha of saline land which needs to be treated for salinity reduction.
 

Rapeseed
Rapeseed (Brassica napus L.), a member of the Brassicaceae family, is one of the primary oilseed crops cultivated for biodiesel production, particularly in Europe and Canada (Hoekman et al., 2012; Demirbas, 2009). Its seeds contain 40-45% oil, making it one of the most efficient oil crops for biofuel production (Ramos et al., 2009). The extracted oil is known as canola oil, which is preferred for both food and fuel applications due to its low erucic acid and glucosinolate content (Atabani et al., 2012). Rapeseed (Brassica napus L.), is one of the biofuel species that has achieved global attention, primarily due to its high yield, climatic versatility as well as its low environmental impact than fossil fuels (Singh et al., 2010). The crop is being grown all over the temperate region because its ability to resist cold temperatures and pests is a major advantage for the practice of sustainable agriculture. Moreover, the rapeseed has been positively affected by the development of biotechnology and the utilization of hybrid breeding that has been significantly increasing the oil yield and disease resistance of rapeseed, thus, facilitating the biodiesel production from this plant (Zanetti et al., 2013). Biodiesel from rapeseed has ecological advantages, significantly reducing greenhouse gas emissions by up to 50% compared to regular diesel (Hill et al., 2006). It also supports rural economic development through the diversification of farmer income and diminishing reliance on imported petroleum (FAO, 2021). The increasing price of the biofuel, chiefly supported by sustainable energy policies and reducing carbon footprint policies, is one of the driving factors for increasing demand of rapeseed as global demand for renewable energy sources rises (Euopean Commission 2021).
Sunflower
Sunflower (Helianthus annuus L.) is an important oilseed crop used for biodiesel production, especially in temperate regions like Europe and North America (Demirbas, 2009). The oil content of sunflower seeds ranges from 25-50%, making it a suitable feedstock for biofuel (Atabani et al., 2012). The characteristics of sunflower oil, such as the high content of unsaturated fatty acids, lead to better cold flow properties of its biodiesel (Ramos et al., 2009). In addition, the creation of high-oleic sunflower varieties allowed considerable improvement in oxidative stability and led to the fact that sunflower biodiesel is more suitable for storage and combustion (Dimitrijevic et al., 2017). A second

The great Indian epic ‘Ramayana’ says that ‘Lord Rama’ has tried to cross over the Bay of Bengal so as to reach Sri Lanka from India from three points along the southeastern fringe of the Indian coast. Firstly, he is said to have tried to cross from Vedaranniyam which is mythologically called as ‘Kodiyakkarai’ Secondly from Manamelkudi and finally crossed over to Sri Lanka from Rameswaram Island (Fig.1), as the former two coastal locations were widely separated from Sri Lanka by Bay of Bengal and the Rameswaram Island was nearer to Sri Lanka during that period. But, the recently acquired satellite data shows the huge accretion of sediments and rapid land building activity off Vedaranniyam coast (Fig. 2 and 3). The geomorphic interpretations carried out using IRS 1A imagery and 14^C archaeological dating of such geomorphic features have shown that such ongoing sediment accretion phenomena off vedaranniyam nose might in future connect the Vedaranniyam part of Indian Peninsula with Jaffna Peninsula of Sri Lanka if the sediment accumulation continues unabated. The sediment accretion in this area, therefore, requires detailed studies particularly in the context of the coastal ecosystem (Fig. 1).

Soil testing kit is developed to determine the available nutrient status of soil by rapid test methods. With this system of soil testing, a farmer can test his own soil as often and, in as many places as he feels necessary, and after gauging the need of his soil, he can apply the fertilizers as required. The present mode of soil testing in laboratories usually takes few days and sometime weeks and the farmers may have to travel long distances to submit the soil sample.

ABSTRACT

The carbonatites are genetically and geochemically distinct and contain several rare earth minerals that are unknown or are very rare in other types of rocks. A useful review of the REE’s in carbonatites is given by Cullers and Graf (1984), who point out that carbonatite contains the highest concentration of REE’s and highest LREE: HREE (La:Lu) ratio of any igneous rock. High REE abundances are considered as the diagnostic character of carbonatites to discriminate them against recrystallized limestone. Rare earth mineralization in carbonatities can be classified into three categories. The first is primary magmatic crystallization (bastnaesite). The second is hydrothermal mineralization and the third is supergene mineralization produced by weathering of carbonatitie bodies. The only economic Nb mineral in carbonatite is pyrochlore. Apatite deposits constitute the largest bulk mining in carbonatites and have higher phosphate content than marine phosphorites. Pyrochlore, cubic fergusonite, eschynite, Fe-Nb rutile, monazite apatite, bastnaesite and allanite are the rare earth minerals that are enriched in Tamil Nadu carbonatites. Such enrichment of above rare earths is typical of undersaturated alkaline complexes. The lanthanides are seen associated with these minerals, mainly the light lanthanides are predominant than heavier ones. Thus the carbonatite complexes provide the locus for several metal deposits that are presently of strategic importance, containing elements, which are otherwise largely dispersed in earth crust.

The satellite data is available in raster format. Raster data consists of two – dimensional array of pixels or grids which stores the values representing features. All the pixels are of same size and shape with their particular coordinate location. A raster data format is shown below.

The calculation of raster data statistics is very essential before performing some geoprocessing operations. Raster data statistics involve knowing the distribution of pixel values in a band, comparing the pixel values of two bands, extracting values of all bands for a particular geographical location or point, and computing statistics like mean, median, standard deviation, etc. at pixel level across all bands of raster dataset.

In R, codes to perform raster data statistics are present in raster package. The visualisation of raster data statistics can be done by rasterVis package. So, we need to import these packages in R in order to perform this exercise.

Abstract

The Rawana landslide, located in Sirmuar district of the Shimla Himalayas, Himachal Pradesh is repeatedly active in the recent years. It is a NE-SW oriented slide with the crown in the southwest and the wider toe in the northeast resting in Giri River. During some of the sliding events emanations of heat and gases were also inferred. In order to understand the landslide phenomenon and the causative factors, and there from to evolve mitigation measures, detailed studies of the slides were under taken. The Landslide hazard zonation mapping carried out in Rawana landslide using LHEF rating based BIS method indicates that it is located in high hazard zone. The detailed studies show the complex geological, structural, morphotectonic and hydrological setting. From the studies it is surmised that the toe erosion by Giri river and the rainfall infiltration in the mid slope region are responsible for the slide. Remedial measures have been accordingly evolved.

The chemistry of humic substances is the least comprehended in the field of Soil Science. The many important functions of humus will remain obscure if the structural chemistry of the humic and fulvic acids is not known. A variety of functional groups have been reported in humic substances. However, considerable disagreement still exists in respect of the exact amounts present and, in some cases, proof of existence is lacking.

Some important structural groups of organic molecules are given below:

Real-time crop monitoring for efficient climate guidance extends beyond monsoon-dependent regions and holds significant importance in a global agricultural context. While the fundamental technologies and principles remain similar, the specific applications and benefits are tailored to the diverse agricultural systems and climates worldwide.
10.1. Global Applicability Across Diverse Agricultural Systems
• Rain-fed Agriculture (Beyond Monsoons): In semi-arid and arid regions globally, where rainfall is scarce and unpredictable, real-time monitoring of soil moisture and plant stress through remote sensing and ground sensors is crucial for optimizing the limited water resources and implementing drought management strategies (Fig.10.1).
• Irrigated Agriculture: Even in systems relying on irrigation, real-time monitoring helps optimize water usage based on actual crop needs and prevailing weather conditions, preventing over-irrigation and conserving water, a critical resource globally.
• Temperate and High-Latitude Agriculture: In these regions, real-time monitoring can track temperature fluctuations, frost risks (as you researched previously), and the impact of shorter growing seasons on crop development, allowing for timely interventions like frost protection or adjustments to planting schedules.
• Tropical Agriculture: Beyond monsoons, tropical regions often face challenges like high humidity and pest/disease pressure. Real-time monitoring of leaf wetness and other microclimate factors aids in targeted pest and disease management, reducing the need for broad-spectrum applications.

Introduction
World population is increasing and currently stands at 8.2 Billion as on 2025. Food security of population of any country is becoming a challenging task and the entire population depends on the available national resources. The importance of scientific community in securing foods for everybody was felt necessary and it was expressed that there is a huge herculean task to ensure food for everybody. Farming community and fruit growers across the globe were engaged in serious efforts to produce fruits of good quality. The necessity to develop advanced technologies for nutritious foods was thus given national importance not only for food security but also of nutritional security. The sincere scientific efforts to develop recent innovative technologies to support fruit production even at harsh soils and environmental conditions are praiseworthy. Farmers, stakeholders, policy planners and technology developers have been devoted to achieve the target of Sustainable Developmental Goals. The target of United Nation’s 2030 to eradicate poverty and eradication of malnutrition should be achieved sustainably. People across nations are working devotedly to achieve the target. However, climatic changes have been significantlyaffecting the food production to food security across nations. Decadal information suggested the adverse impact of climates on the fruit production. Recent changes in weather extremisms had also affect harshly on the food production to supply chain. Thus, the role of scientific community to coup up the environmental hazards and to sustain fruit production becomes a reality. In this context, agroadvisory services plays significant role to support farming community and fruit growers to adopt time bound managemental practices. The ultimate aim of these services is to improve the orchard soil and tree health condition, enhance factor productivity vis-à-vis profitability and precise use of available natural resources. Quantification of variability in environmental indicators, soil and tree interactions were felt necessary for formulating effective policy plan (Malhotra, 2017). Adak et al. (2022) advocated for foliage spraying of 1 per cent zinc sulphate on mango cv. Dashehari to enhance yield and nutrient richness in fruit pulp.

Abstract

Recycling of organic wastes by chemical amendments and bio-inoculants are the recent developments in the technology for composting to manage voluminous wastes with economic advantages as well as environmental and social perspectives. Various composting technologies such as vermicomposting, P-enriched vermicompost, phospho-sulpho-nitro compost, phosphocompost and microbial enriched compost have been developed utilizing agro-industrial wastes, municipal solid wastes, distillery effluents and press mud, amended with certain mining waste materials such as rock phosphate and pyrites for increasing the nutrient supplying potential of the compost. It was observed that matured enriched compost (after 110 days of composting) contains 3.2 to 4.2% P and 1.5 to 2.3% N. In vermicomposting, earth worms helps in accelerating the decomposition processes and bringing down the composting period from six to eight months to around 2-3 months. Thus, enriched compost helps to produce higher yields of crops and also improve soil physical, chemical and biological conditions, thereby, enhancing productivity and sustainability of agriculture.