eChapters

Introduction

The town Paithan is famous by it’s name Dakshin Kashi. Godavari river has pristine glory and great significance for Hindus.

Nath temple is situated on the bank of Godavari river. It is a holy place and that’s why it becomes a place of public gathering on Ekadashi, Aashadi Ekadashi, Poornima, Deepawali, Dasera etc. Every year during Chaitra lakhs of people gather.

But at the time of Sheshti, which occurs once in a year is a special event. Hence many fold increase of congregation compared to other melas. The particular small stretch of river near temple was highly polluted, due to mass bathing and other polluting activities. The warm weather shall alter the photosynthesis rates, biodegradation and affect BOD, DO, pH etc. Recent Nath Sheshti at Paithan during 20^th March to 22^nd March 2006, drew about one lakh of pilgrims and had a few special aspects of interests from an environmental point of view.

Considering all the above aspects, it was decided to assess the changes in quality of river Godavari during Nath Sheshti.

Sustainable Development
Although the term “sustainable development” is frequently overused, it is essential to addressing a multitude of interconnected global concerns, including hunger, poverty, inequality, and environmental degradation.
Several environmental movements from previous decades gave rise to the concept of sustainable development. Major international gatherings, like the 1992 Rio Earth Summit, were crucial in advancing the cause of sustainable development. But it seems that progress toward sustainability has not been great up to this point.
Definition
A key objective of sustainable development is to achieve a reasonable and equitable distributed level of economic well-being that can be continuously perpetuated for many human generations. Sustainable development is defined as a pattern of social and
structured economic transmissions (i.e., development) that optimizes the economic and societal benefits available in the present without jeopardizing the likely potential for similar benefits in the future.
“Development that meets present needs without compromising the ability of future generations to meet their own needs” is another definition of it.
Salient Aspects of Ecological Development
1. It takes equity into account between nations and continents, racial and socioeconomic groups, gender, and age.
2. It encompasses environmental requirements as well as social development and economic opportunities.

Introduction

India is having very rich sources of inland water bodies in the form of river, lakes and reservoirs. The reservoirs are constructed by impounding the river system. The reservoirs are constructed for effective utilisation of water for irrigation, power generation and flood control. Reservoir fishery in India is also important from socio-economic point of view as it has the potential of providing employment to about two million people, Kaushal and Sharma (2001). Total area under the reservoirs in India is 3:1 million ha and it is expected to double by 2020. This includes 19,000 small reservoirs with a total water surface area of 14,85,557 ha and about 180 medium and 56 large reservoirs of 5,27,541 and 11,40, 268 ha area respectively.

The Maharashtra is endowed with an area of 1,79,430 ha under reservoir and the Maharashtra produces 516 tonnes of fish through reservoirs. The state fisheries corporation was operating in 6,272 ha of reservoirs and marketing the catches.

Introduction

Disaster is defined as a serious disruption of the functioning of a community or a society causing widespread human, material, economic or environmental losses, which exceed the ability of the affected community or society to cope using its own resources (ISDR 2002).

Disaster in Global context - The impact of natural disasters in terms of human and economic losses has risen in recent years, society in general has become more vulnerable to natural disasters. Those usually most affected by natural and other disasters are the poor and socially disadvantaged groups in developing countries as they are least equipped to cope with them (IFRC 2001).

India is a geologically diverse country with a wide variety of rock types. The major rock types found in India can be broadly classified into the following categories:

Igneous Rocks: These rocks are formed from the solidification of molten magma. They can be further divided into two types:

1. Plutonic (Intrusive) Igneous Rocks: Examples include granite, diorite, and gabbro. These rocks are formed deep within the Earth's crust and have a coarse-grained texture.
2. Volcanic (Extrusive) Igneous Rocks: Examples include basalt, andesite, and rhyolite. These rocks are formed on the Earth's surface from volcanic eruptions and have a fine-grained texture.

Sedimentary Rocks: These rocks are formed by the deposition and consolidation of sediments over time. They can be further divided into various types based on their composition and mode of formation:

1. Clastic Sedimentary Rocks: Examples include sandstone, shale, and conglomerate. These rocks are formed from the accumulation and lithification of fragments of pre-existing rocks.
2. Chemical Sedimentary Rocks: Examples include limestone, dolomite, and rock salt. These rocks are formed from the precipitation of minerals from water bodies.

Structural landforms are landforms that are created due to the underlying geological structures of the earth's crust. These structures can include folds, faults, and other features that have been formed due to the tectonic forces that have shaped the earth's surface over millions of years.

Examples of structural landforms include mountain ranges, plateaus, and rift valleys. Mountain ranges are formed due to the upliftment of the earth's crust along a fault line or due to the folding of the earth's crust. Plateaus are flat-topped landforms that are formed due to the upliftment of a large area of the earth's crust. Rift valleys are formed due to the stretching and pulling apart of the earth's crust along a fault line.

Denudational landforms, on the other hand, are landforms that are created due to the process of erosion and weathering. These landforms are formed due to the gradual wearing down of the earth's surface by natural forces such as wind, water, and ice.

Rock

A rock is a solid, naturally occurring substance composed of minerals or mineraloids. It is typically formed through geological processes, such as cooling and solidification of molten lava or magma, or by the deposition and compaction of sediment over time. Rocks are classified into three main types based on their origin: igneous, sedimentary, and metamorphic.

Igneous rocks: Formed from the cooling and solidification of molten lava or magma. Examples include granite, basalt, and obsidian.

Sedimentary rocks: Formed from the accumulation and compaction of sediment, such as sand, mud, or organic matter, over long periods. Examples include sandstone, limestone, and shale.

Metamorphic rocks: Formed from the transformation of existing rocks under high temperature and pressure conditions. They undergo changes in mineral composition, texture, and structure. Examples include marble, slate, and gneiss.

Rocks serve as the building blocks of the Earth's crust and are an essential part of the geological processes that shape the planet. They can provide valuable information about Earth's history, including the formation of mountains, the movement of continents, and the presence of ancient life forms. Rocks are also used in various practical applications, such as construction, road building, and the production of minerals and resources.

Geomorphological mapping is the process of creating detailed maps that illustrate the physical features of the Earth's surface, including landforms, soil types, vegetation, and water resources. These maps can be used to better understand the underlying geology and topography of a region, and can be used for a variety of purposes, such as land-use planning, environmental management, and geological hazard assessment.

Geomorphological maps are typically created using a combination of field observations, aerial photography, and remote sensing data. Field observations involve physically visiting a site and making detailed observations of the landforms, soil types, and vegetation. Aerial photography involves taking high-resolution photographs of the Earth's surface from an airplane or satellite, which can be used to create detailed maps of the area. Remote sensing data can also be used to create geomorphological maps, including data from satellites, radar, and LiDAR (Light Detection and Ranging) systems. These technologies allow scientists to gather data about the Earth's surface without physically visiting the site, and can provide highly accurate information about the topography, geology, and vegetation of an area. The resulting maps can be used for a variety of purposes, including land-use planning, natural resource management, and hazard assessment. For example, geomorphological maps can be used to identify areas of high risk for landslides, floods, or earthquakes, and can be used to develop strategies for managing these hazards.

For the protection of all the factors of environment, laws were formed and amended from time to time as per the requirement. There are many acts according to the main factors and separate laws, for the enforcement. Also, the are some control acts, which can be implemented by states for the local environmental problems.

The major source of water supply on the earth is precipitation. The water received at the earth’s surface from the atmosphere either in solid or liquid form is called precipitation. The water received in solid form may be snow or hail. The precipitation is seasonal in character in many parts of the world. The precipitation may occur due to –
• Conventional physical process
• Orographic effect and
• Convergence of air masses
3.1. Conventional Physical Process
It occurs when the air on the surface of the earth and few metres above the surface of the earth is heated by absorbing long wave radiation emitted by the earth’s surface. As the air is heated, it becomes lighter. The water vapour formed due to evaporation from the soil surface or water bodies will mix with the air and the air will be moist. When the moist air gets heated it becomes lighter and rises vertically upwards. After reaching certain height, the air gets cooled enough to get saturated with water vapour. The moisture in the saturated air will condense on small solid particles to form tiny drops. These solid particles may be dust or smoke or solid particles suspended in the atmosphere and are called aerosols.

It is estimated that the world requires nearly 70 per cent increase in agriculture production to meet the demand for food by the year 2050 based on current trends in population growth it can be achieved either by increasing land under cultivation (which is not possible), increasing the availability of more water for agriculture and efficient utilisation of available land and water resources. The best available option is to increase in productivity of unit of land for unit water. However, the availability of water for agriculture production cannot be presumed to be same year after year as the major source of water is precipitation more known for its uncertainty due to change in weather patterns from season to season and year to year all over the world. The element of uncertainty is increasing since the beginning of the present century due to climate change under the present circumstance, the crop production is practiced -
• In Irrigated Areas
• In Rainfed Areas
• Under Conserved Moisture Condition Without Any Source Of Irrigation
For increasing crop production under irrigated condition, it is necessary to identify crops and varieties that can produce more yield per unit of water even when there is some decrease in availability of water through irrigation. Therefore, the concept of water production function is used for evaluation of water use efficiency of the crops.

Stress is force per unit area. When matter is subjected to stress; it may undergo changes in size, shape and displacement. Plants are grown in open environment and are likely to experience stress due to environmental conditions or when subjected to pests and diseases. The stress experienced by plants due to environmental conditions is called abiotic stresses. These include stresses caused by weather factors and climatic conditions and include moisture stress and thermal stress. The plants may also experience stress due to strong winds, dryness and as well as humid conditions (Fig.8.1).
The plants are generally classified into three types depending upon the ability to cope up with moisture stress as exhibited by-
• Drought resistance
• Drought tolerance
• Drought adaptations
The moisture stress may be to shortage of Water Compared to its requirements for evapotranspiration and metabolic activities. The plants may also suffer moisture

Remote sensing involves measurement of the physical properties of a body without actual contact with it. It is based on the reflectance when the electromagnetic radiation is incident upon a body or surface. The spectral characteristics of the reflected radiation vary depending upon the nature and condition of the surface. In case of vegetation, it absorbs light and can reflect light in the visible range. The leaf pigments dominate the reflectance properties (Fig.9.1). The radiation bands within which the reflectance of electromagnetic radiation takes place are classified as follows-
Spectrum Wave Length (nm)
Visible 400-700
Near Infrared 701-1300
Middle infrared 1301-2500
Far infrared >3000

9.1. Vegetation Indices
The vegetation index is a mathematical expression that uses spectral imaging data to characterize the health and growth of the vegetation indices are calculated using data collected by remote sensors like Satellites. The vegetation indices have wide range of applications in agriculture and hydrology including
• Classification of vegetation
• Apex health of vegetation
• Changes in land cover
• Drought monitoring
• Estimation of soil moisture
• Evaluate crop growth, vigour, biomass and chlorophyll content
• Irrigation scheduling

The purpose of irrigation scheduling is to decide upon the amount of water to be applied for irrigation and timing of irrigation in order to avoid wastage of precious water. The irrigation scheduling is also used to determine the number of irrigations required for a crop during its growth cycle and judicious use of water depending upon the weather forecasts issued from time to time. The irrigation scheduling has to be planned for either full irrigation or supplementary irrigation depending upon the availability of water resources and the season during which crops are grown. Crops grown during the dry season requires full irrigation and crops grown during the rainy season require supplementary irrigation. The third category of irrigation is protective irrigation which is practiced in dryland areas. The protective irrigation is given when the crops are experiencing severe moisture stress due to prolonged dry spells wherever the farmers has access to small ponds and tanks developed within his own field as water harvesting structures.
10.1. Full Irrigation
Under full irrigation, the crops are provided with irrigation right from land preparation till the crop is getting ready for harvest maturity. The full irrigation will be usually planned for maximum yields of the crop (Fig.10.1).

A watershed is an area that provides pathway to the surface or sub surface water flow to a given drainage system. The watershed is a hydrological unit. The area of watershed may vary from few hectares to thousands of square kilometres. The watershed development involves effective management of land and vegetation in order to conserve and improve the quantity of water. The watershed development is a comprehensive and sustainable solution to water conservation (Fig.13.1).
The watershed development has several advantages. It helps in
• Conservation, upgradation and utilization of natural resources particularly land, water and vegetation
• Minimise the inequalities between rainfed and irrigated areas
• Promoting cost effective adoptable simple technologies
• Supply water for domestic ,agricultural and industrial use
• Poverty alleviation and employment generation
• Reducing chemical pollution
• Adopting flood control measures by constructing water storage or impounding structures

Hydrometeorology forecasting is limited to forecasting of occurrence of rainfall to a greater extent. Although several countries all over the world have developed and established hydrometorological forecasting with focus on occurrence of floods and droughts, still there is very limited success. Floods are associated with occurrence of continuous heavy rainfall due to movement of low-pressure systems like cyclones and depression overflow into rivers, reservoirs and breaching of bunds. In countries like India, the floods occur on the average in 70 lakh hectors of area and the economic loss due to floods and expenditure on relief operations mounting year after year besides loss of life. Foods occur at all of a sudden leaving little time for planning mitigation or rescue operation. Flood forecasting in based on impact assessment of heavy rainfall assessments to identify the exact area that is likely to be affected. It requires more intensive research. Forecasting of droughts is still an area of serious concern. There is need to strengthen regional capabilities to develop forecasting techniques for occurrence of flood and droughts through proper analysis of historical data in conjunction with meteorological forecasts and remote sensing data. Though flood alerts are issued, the identification of exact area and the extent to which flood impacts are not very clear most of the times heavy rainfall warnings are not just sufficient until and unless the vulnerable areas can be clearly specified. The medium range forecasting will be extremely useful for issuing flood alerts.
14.1. Forecasting Droughts
Long range forecasting of seasonal rainfall can indicate the possibility of receiving excess or deficit rainfall over larger regions. In India, there is considerable progress in development of long range forecast of Southwest monsoon rainfall. This forecast also indicating the regions which may get surplus or deficit rainfall and for indifferent parts of a given region as well. However, there is serious dearth of local expertise to further analyse and interpret the long-range forecast for a given area on the basis of local climate data. The advantages of reliable long-range forecast are still unexpected. Almost one fifth of the area in India gets affected by draught most of the years. The drought affects are more severe in arid and semi arid regions. Prediction of occurrence of drought and its intensity, period of occurrence and the areas to be affected by drought is very important. During recent years, there is considerable increase in the occurrence of droughts due to climate change which is attributed mainly to atmospheric pollution. The physics of the pollution is consistent and not the policies support in handling hydrometerological disasters. There are instances where in flood and droughts occurred in the same

Analytical chemistry is a branch of chemistry dealing with the determination of constituents of a substance or mixture of substances.

1.1 Qualitative Analysis

Qualitative analysis deals with the identification of the constituents of a substance, mixture of substances, or solutions and the way in which component element or a group of elements are constituted.

1.2 Quantitative Analysis

Quantitative analysis is concerned with the determination of quantitative contents of individual element or group of elements or compound present in the substances. This branch of analytical chemistry is of enormous scope and importance in science, industry and agriculture. The quantitative analysis can be divided into several categories based on the different methods employed for their quantitative measurements such as:

2.1 Beakers

Beakers are the one of most important vessels used in laboratory which is made up of heat resistant glass.

They are available in various capacities ranging from 10 to 3000 mL.

For convenience of pouring solution, spout is provided in the beaker.

They are used to perform titrations & for boiling solutions, etc.,

Beakers are constructed in tall and low forms.

(International/Robinson’s Pipette Method)

Principle

This method is based on Stoke’s law. According to this law, the rate of fall of a particle in liquid is directly proportional to the square of its radius.

The great Indian epic ‘Ramayana’ says that ‘Lord Rama’ has tried to cross over the Bay of Bengal so as to reach Sri Lanka from India from three points along the southeastern fringe of the Indian coast. Firstly, he is said to have tried to cross from Vedaranniyam which is mythologically called as ‘Kodiyakkarai’ Secondly from Manamelkudi and finally crossed over to Sri Lanka from Rameswaram Island (Fig.1), as the former two coastal locations were widely separated from Sri Lanka by Bay of Bengal and the Rameswaram Island was nearer to Sri Lanka during that period. But, the recently acquired satellite data shows the huge accretion of sediments and rapid land building activity off Vedaranniyam coast (Fig. 2 and 3). The geomorphic interpretations carried out using IRS 1A imagery and 14^C archaeological dating of such geomorphic features have shown that such ongoing sediment accretion phenomena off vedaranniyam nose might in future connect the Vedaranniyam part of Indian Peninsula with Jaffna Peninsula of Sri Lanka if the sediment accumulation continues unabated. The sediment accretion in this area, therefore, requires detailed studies particularly in the context of the coastal ecosystem (Fig. 1).