eChapters

General Introduction 
Growing populations and industrialisation around the world are driving up energy demand, which increases reliance on fossil fuels. The World Energy Forum projects that global stocks of fossil fuels like coal, natural gas, and oil will run out in less than ten years and decades [1]. Fossil fuels account for 88.1% of total energy consumption; they include coal (43%), oil and other liquids (23%), waste (6%), natural gas (6%), and biomass (24%). Hydroelectricity, and nuclear energy, on the other hand, share relatively small percentages of energy (1% and 2%, respectively) [2]. Petro-diesel, also known as petroleum diesel, is currently utilized as a fossil fuel and is created when crude oil is fractionally distilled at temperatures between 250°C and 350°C under atmospheric pressure. Once heated to a certain degree, the different types of diesel fuel are formed via the vaporization of hydrocarbon chains and the isolation and blending of constituents in a prescribed ratio. Typically, 25% of the petrodiesel’s composition consists of aromatic hydrocarbons and 75% of saturated hydrocarbons. The combustion of diesel fuel releases sulfur, nitrogen, and particulate matter into the environment, which are all present in significant concentrations in petro-diesel. Moreover, burning fossil fuels has resulted in several environmental problems, such as greenhouse gas emissions (GHG), which have a major impact on global warming, climate change, and a host of other chronic illnesses [3]. India is ranked as the fourth-biggest importer and user of petroleum products and crude oil. With demand for oil reaching about 4.1 million gallons per day in 2015, there is a growing disparity between India’s oil supplies and supply. The IEA analysis predicts that beyond 2050, there won’t be any oil reserves and that India’s oil consumption will increase by 6.0 million barrels per day to 9.8 mg/d in 2040 [4]. Two-thirds of the growth in oil demand and 16% of the increase in

Agriculture 4.0, otherwise called “Digital Agricultural Revolution”, addresses a change in outlook in agriculture, utilizing state of the art innovations to improve different parts of cultivating tasks. These innovations include the Internet of Things (IoT), Artificial brainpower (Artificial intelligence), Huge Information, distributed computing, Cloud computing, Decision Support System (DSS), high level detecting innovation, and independent robots. Sensors and mechanical technology assume a urgent part in gathering fundamental field information, which is then sent to a neighborhood or cloud server by means of IoT innovation for capacity, handling, and examination. Large information and Artificial intelligence-based strategies can be utilized to change over this information into significant experiences. To work with client connection and informed independent direction, a DSS outfits clients with the fundamental devices to improve the agricultural framework and embrace proper activities.
AI (ML), a subset of Artificial intelligence, has shown extraordinary potential in upgrading different parts of agriculture 4.0. It very well may be characterized as a PC program or framework that can learn explicit errands without being expressly modified to do so. An interaction includes the utilization of a PC to go with choices in light of various information inputs. For this situation, information means a bunch of models. Marked information is frequently utilized for managed learning undertakings (where the model gains from named models), and unlabeled information may be utilized for solo learning assignments (where the model tracks down examples and designs in the information).
ML for sure advantage from a lot of information to accomplish significant exactness in their errands. With regards to farming, acquiring immense and various information can be at times testing yet crucial for the outcome of ML models. IoT sensors are instrumental in gathering a different scope of farming information as they can be decisively sent across fields to catch pertinent data with respect to, for example, soil conditions, Climate factors, crop wellbeing, and animals’ measurements. The inescapable reception of IoT innovation works with constant and continuous information procurement, empowering

Major International Treaties Related to IPR & TRIPS

There are different forms of intellectual property like Patents, Copyright, Trademarks, Industrial design, Plant Varieties etc. Various meeting and conventions were also convened for the protection in these intellectual properties at international level from time to time and to bring uniformity and coordination among member countries. These were reflected in different treaties, which are mentioned below. Among all these treaties/conventions the agreement on Trade related aspects of intellectual property rights (TRIPS), which runs under aegis of World Trade Organization is most influential, comprehensive and inclusive of all.

“Necessity is the mother of invention”, all of us must have heard this statement at some juncture in our lives. Most of us may even have even gone through the motion of inventing something when needed. However, more and more inventions happening today may not necessarily be necessities. These inventions definitely perform the task of improvingand making convenient our overall living environment. Past few years have seen an increasing awareness and understanding in the field of intellectual property. Among all aspects, one aspect of intellectual property that is gaining increasing attention of intellectual property owners is management of the intellectual property rights.

This brings to our minds one question, how was intellectual property management practised by early mankind? We all do know that early mankind has left no stone unturned to make theabove statement”Necessity is the mother of invention”, a reality. Mankind prospered by leaps and bounds on account of sharing their various discoveries and inventions. Way back then knowledge was meant to be shared, as aptly captured in the Sanskrit Sloka:

Q. 1 The high moisture grain should be kept in
(A) Air tight structure     (B) Aerated structure
(C) Pucca kothi             (D) Gunny bags in closed room

7.1 Introduction

This chapter describes the development of data logger of agricultural field parameter monitoring system with MATLAB. The system comprises of Arduino, water level sensor, humidity sensor, light sensor, soil moisture sensor, temperature sensor, smoke detector, power supply, PC with MATLAB. The system is designed to monitor the environment and agriculture field parameters. The field device is designed to collect all physical parameters and same is communicated serially to MATLAB with I/O package. Fig.7.1 shows block diagram of the system. Table.7.1 shows the component list required to develop the system.

Eigen values of the matrix are

(A) 1 and 2             (B) 1 and 3

(C) 1 and 4            (D) 2 and 3

Aim

To measure horizontal distance on the level ground using chain

Materials required

Chain

Ranging rods

Chain pins

Field note book

Aim

To measure irrigation water by area-velocity method by using (i) float and (ii) current meter

Apparatus required

Float

Current meter

Theory

The rate of flow of water in open channel can be determined by multiplying the cross sectional area of the flow section at right angles to the direction of flow by the average velocity of water. In area-velocity method, the water can be measured at motion. The water is measured in motion by means of rate of flow or discharge and is expressed in litre per second (lps), litre per minute (lpm), cubic metre per second (m³/s), etc. Litre per second: A continuous flow amounting to 1 litre passing through a point each second. Cubic metre per second: A flow of water equivalent to a stream of 1 m long, 1 m wide and 1 m deep flowing at a velocity of 1 metre per second. In area-velocity method, the velocity of water is measured either by float or current-meter

Aim

To measure the irrigation water by using parshall flume

Construction of Parshall flume

Parshall flume is a water measuring device that can be used to measure water flowing in an open channel and intended primarily for use in irrigation. The flume consists of a converging inlet section, a throat section with straight parallel sides, and a diverging outlet section (Fig.61.1). The floor of the converging section is level with walls which converge in the direction of flow, towards the throat. The throat section constitutes the middle portion of the Parshall flume. The floor of the throat section is dips downward in the direction of flow, but the walls are parallel. The throat width specifies the dimensions of the parshall flume. The diverging outlet section of the flume has a floor which rises in the direction of flow. The walls become further separated in the direction of flow (diverge).The parshall flume can be constructed by G.I. sheet, aluminum sheet, M.S. sheet, brick masonry, reinforced concrete or timber. Flumes made of G.I. or aluminum sheets are easily portable. Brick masonry and concrete flumes are permanently constructed in the channels. Stilling wells should be constructed at the side to take measurements.

Aim

To measure the irrigation water by using orifice

Orifices

An orifice is an opening in a bulk head with closed perimeter usually circular or rectangular cross-section through which water flows. For measurement of water, orifices are fabricated by making an accurate cut of proper size and shape in a mild steel sheet, aluminum plate etc. Proper machining is done to have a sharp edge through which water flows (Fig.60.1).

Free discharge

If the downstream water level is lower than the bottom of the orifice opening, the water jet discharges freely into the air and then it is said to be free discharge. The depth of water on the upstream side of the orifice that causes the flow is called the head. The orifice flow formulae can be applied only when the orifice flows fully.

Aim

To measure the irrigation water by using weirs

a) Weirs

A weir is a notch or opening of some definite shape installed on a channel or a stream through which waterfalls (Fig.59.1). Materials like wood, concrete, mild steel, rigid PVC etc. can be used for construction of a weir. Mainly a cut on a sheet metal is used for fabrication of weirs, to be installed at various locations in a channel. Advantages of weirs are (i) capable of accurately measuring a wide range of flows (ii) easy to construct, portable and adjustable (iii) tends to provide more accurate discharge rating than flumes and orifices.

Aim

To measure irrigation water by volumetric method

Apparatus required

Siphon tube

Stop watch

Measuring bucket

Aim

To measure the irrigation water flowing through a pipe by using Venturimeter

Theory

A venturimeter is a device used to measure the rate of flow of a fluid through a pipe and is often fixed permanently at different sections of the pipeline to know the discharge there. Venturimeter consists of three parts: (i) a short converging part (ii) a throat (iii) a diverging part (Fig.62.1). In the venturimeter, the fluid is accelerated through a converging cone of angle 15-20° and the pressure difference between the upstream side of the cone and the throat is measured, and provides the signal for the rate of flow. Due to the constriction there is an increase in the flow velocity and hence an increase in the kinetic energy. The fluid slows down in a cone with smaller angle (5-7°) where most of the kinetic energy is converted back to pressure energy. Because of the cone and the gradual reduction in the area there is no “vena contracta”. The flow area is at minimum at the throat.

Introduction

Measurement of pH of a solution and preparation of different types/strength of buffers are common practices in a laboratory, particularly in the Biochemistry and Molecular Biology laboratories. Therefore, in this chapter you will be acquainted with the procedures of measuring pH of a solution as well as preparation of some of the commonly used buffers in a laboratory.

Potential or Power of Hydrogen Ion (pH)

Measurement of pH of a solution is measuring the molar concentration of hydrogen ion [H+] in the solution, which is an indication of the acidity or basicity of the solution. The symbol pH stands for “power of hydrogen” and numerical value for pH is just the negative logarithm of the molar concentration of hydrogen ions [H+]. The ionic product of water (Kw ) is the basis for the pH scale. The total hydrogen ion concentration from all the sources and it can be experimentally measured.

The pH scale designates the concentration of H+ (and thus of OH−) in an aqueous solution, which ranges between 1.0 M H+ and 1.0 M OH−. The term pH is defined by the expression

Thus, the ionic product of water makes it possible to calculate the concentration of H+, with given concentration of OH−, and vice versa. The value of 7 for pH of a neutral solution is not an arbitrarily chosen figure; it is derived from the absolute value of the ionic product of water. A solution having pH greater than 7 is basic, and the concentration of OH− is greater than that of H+. A solution having a pH less than 7 is acidic.

5.1 Introduction

Phosphorus fertilization is a problem in acid soils due to the high fixation characteristics of these soils. Soluble phosphorus carriers such as triple super phosphate tend to get reverted into insoluble and slowly soluble forms, for e.g. iron and aluminium phosphates.  Some soils in Mauritius have been shown to fix up to 90% of applied phosphorus. The fixation characteristics as related to soil properties have been studied for some soils of Mauritius. Rock phosphate offers a good alternative or complement to triple super phosphate.  In volcanic soils of Chile it is recommended to apply rock phosphate in combination with triple super phosphate because of the high phosphorus-retention capacity of these soils.  However, in Western Australia it has been shown that rock phosphate response is low. Possible explanations are slow dissolution of rock phosphate due to the moderately acid pH (5.5 -6.5), low pH-buffering capacity, low calcium absorption in soil, which increases concentration of calcium in soil solution, and poor water holding capacity of these soils.

Surface-Enhanced Raman Spectroscopy (SERS) may detect and identify chemical and biological species ultrasensitively. Through localized surface plasmon resonance (LSPR) effects, metal nanostructures boost analyte Raman signals. This chapter covers current advances and essential principles in metal nanostructures for SERS chemical detection. It discusses SERS fundamentals and enhancing processes, such as metal nanostructure size, shape, and composition. Top-down and bottom-up processes including lithography, chemical synthesis, and self-assembly are used to create repeatable and controllable metal nanostructures. The complex interactions between light, metal nanostructures, and analyte molecules are best understood by combining theoretical modeling and experimental observations. 

Atoms and molecules are the essential building blocks of every object. The manner in which things are constructed with these basic units is vitally important to understand their properties and their reciprocal interactions. An efficient control of the synthetic pathways is essential during the preparation of nanobuilding blocks with different sizes and shapes that can lead to the creation of new devices and technologies with improved performances. Traditionally nanoparticles were produced only by physical and chemical methods. Some of the commonly used physical and chemical methods are ion sputtering, solvothermal synthesis, reduction and sol gel technique

Basically there are two approaches for nanoparticle synthesis namely the Bottom up approach and the Top down approach. In the Top down approach, scientists try to formulate nanoparticles using larger ones to direct their assembly. The Bottom up approach is a process that builds towards larger and more complex systems by starting at the molecular level and maintaining precise control of molecular structure.

These two different methods highlight the organization level of nanosystems as the crossing point hanging between the worlds of molecular objects and bulk materials.

The top-down approach has been advanced by Richard Feynman in his often-cited 1959 lecture stating that “there is plenty of room at the bottom” and it is ideal for obtaining structures with long-range order and for making connections with macroscopic world. Conversely, the bottom-up approach was pioneered by Jean-Marie Lehn (revealing that “there is plenty of room at the top”) and it is best suited for assembly and establishing short-range order at the nanoscale. The integration of the two techniques is expected to provide, atleast in principle, thewidest combination of tools for nanofabrication.

Introduction 
Fossil Fuels like Coal, Coal product, Natural Gas, Petroleum, Crude Oil provide 80% of the world’s energy. However, burning them releases harmful pollutants, including carbon dioxide, nitrogen oxides and the sulfur oxides, contributing to global warming. To combat this, the World is shifting towards cleaner, renewable energy sources called biofuels. Biofuels are made from organic materials like plants and waste, offering several benefits: Renewable and Sustainable, Less greenhouse gas emissions, non-toxic [6]. Common biofuels include are: Biodiesel, Biogas, Bioethanol. These alternative fuels help reduce our reliance on fossil fuels, mitigating climate change and promoting a healthier environment. Biodiesel replaces fossil-based diesel/petrol made through Trans-esterifi cation process. The benefi ts include clean energy, renewable resources and the domestic production. Generations of biodiesel are: First Generation include Edible crops (Soybean, Corn, Sugarcane). Second Generation includes Non-edible biomass(Straw, Hay). Third Generation include Microalgae (70% yield). Fourth Generation include the genetically modifi ed algae and electro-biofuel. [2] Biodiesel production has changed over time. Initially, edible vegetable oils like soybean, corn, sunfl ower and palm oil were used. However this raised concerns: using valuable farmland for fuel instead of food, competing with food production, weather and soil quality affecting the crop yield , fertilizer use releasing harmful nitrous oxide greenhouse gas. To address these issues, focus shifted to non-edible oils and now Microalgae, offering; sustainable, climate-resilient production, no competition with the food crops, reduced greenhouse gas emission, higher oil yield. Microalgae -based biodiesel is the future providing a cleaner, more effi cient alternative.[4]

Introduction 
Fuels are essential to human existence and account for 70% of the world’s energy use. The demand for fossil fuels is rising daily due to the ongoing global population boom and has now reached a crisis point. The world’s current reserves cannot keep up with the projected 40% rise in demand between 2010 and 2040 [1]. According to Energy Information Administration (EIA) statistics, the world’s fossil fuel sources will run out in fewer than 50 years [2]. In addition, burning fossil fuels and living in an industrialised environment have released large amounts of carbon dioxide (CO2), carbon monoxide (CO), sulphur dioxide (SO2), nitrogen oxides (NOx), as well as a significant number of potentially toxic compounds into the atmosphere. This has severely degraded the natural resources that are currently available, including fossil fuels. The human and natural ecology have suffered significant damages as a result of the effects of global warming in recent years [3]. As a result, cutting CO2 emissions is crucial to preventing the negative effects of global warming. Therefore, there has been a greater focus on the improvement of CO2 capture and sequestration systems to significantly lower CO2 emissions from a variety of sources, including vehicle exhaust emissions and industrial flue gas [4] . Fuel production needs to be sustainable in terms of the environment and the economy, meaning it needs to be able to reduce CO2. It is critical to find inexpensive, sustainable, and clean energy options in order to handle the current circumstances. Currently, several traditional renewable energy sources, such as solar, biofuels, hydroelectric, geothermal, or wind are being used with varying degrees of success and detriment. Biofuels are sustainable and renewable energy sources that have emerged as a superior alternative to traditional fossil fuels in energy production. Biofuels have a lot of potential because they are abundant environmentally favourable renewable resources and their production is expanding globally, even though they are still more expensive than fossil fuels [5]. Researchers are actively investigating biomasses as a means of obtaining energy from renewable sources. It is commonly known that through a process called photosynthesis, plants can transform sun energy into chemical forms. Microalgae are fast-growing microorganisms that develop 100 times quicker than terrestrial plants. Their photosynthetic efficiency is also higher (10–50 times greater than terrestrial plants) among biomasses [6]. In less than a day, they can double their biomass. Unicellular microalgae, in contrast to plants, do not divide substantial amounts of biomass into supporting structures like stems or roots, which are costly to create energetically and frequently challenging for harvesting and processing to produce biofuel. Furthermore, they have the ability to adapt to harsh aquatic environments and economically absorb helpful substances. Moreover, 1 kg of microalgae biomass is produced by microalgae cells that fix 1.8 kg of CO2 and have a 50% carbon content [7]. Microalgae can be grown on terrain that is inappropriate for food production because of their high total yield and hence small land use footprint [8]. Microalgal species including Scenedemus sp., Chlorella sp., and Botryococcus sp.; are common, easier to grow than other species and may have higher lipid contents [9].