eChapters

pH is important as a measure of active acidity which influences the flavour and palatability of the product and affects the processing requirements. This is an indicator of the acidity or alkalinity of the solution. It is also taken as the measure of the sourness or tartness of the given sample. The pH of a solution varies from 0 to 14. Solutions having a value of pH ranging from 0 to 7 on the pH scale are termed as acidic and the value of pH ranging from 7 to 14 on the pH scale are known as basic solutions. While, solutions with a pH value equal to 7 on the pH scale are known as neutral solutions. Samples with a pH value equal to 0 are known to be strongly acidic. Further, the acidity decreases as the value of pH increases from 0 to 7 whereas, solutions with the value of pH equal to 14 are termed as strongly basic solutions.
Most fruits have a pH value ranging between 3-4, with citrus fruits exhibiting a pH of up to 2.0. Vegetables may exhibit a pH of up to 6.0, as such they are classified as non-acid or low-acid foods. Based on pH value, most fruits, vegetables, and their products are classified into four arbitrary groups such as low acid (5.3 and higher); medium acid (5.3-4.5), acidic (4.5-3.7), and high acid (3.7 and lower). pH value of some fruits, vegetables, and their products is given as under:

4.1 Phases of technology transfer
To translate laboratory research into market ready product, it is important to understand steps or phases involved in this technology transfer process. The process typically includes six main phases, each with a different role (figure 9).
4.1.1 Research
Technology transfer begins with research, the critical stage of exploring and discovering novel knowledge, technologies, or innovations that may have potential commercial applications. The research phase can occur in academic institutions, research organizations, or private sector companies, often funded by public or private sources. Thorough research ensures that the technologies being transitioned are scientifically and technically robust, thereby increasing their potential for market success. Therefore, the research phase involves creating and evaluating new ideas, confirming their feasibility, and identifying IP prospects, all of which are key components of TT success.
4.1.2 Innovation disclosure
Innovation disclosure is the first formal step where the innovation is reported to the appropriate TTO or IP management team. This process ensures that the institution or organization recognizes the innovation and evaluates its potential for protection and commercialization. It includes following information:

Introduction Solid–liquid extraction process, has been extensively used for extraction of bioactive compounds from plant food matrices by using appropriate solvent, which can be used as functional ingredients and additives in food processing, pharmaceutical sectors, and others industries. Usually this extraction/recovery process is based on unsteady diffusion of compounds targeted for extraction, through the matrices followed by the dissolution of the extractable compounds in the bulk of the used solvent (Milic, Rajkovic, Stamenkovic, & Veljkovic, 2013). The concentrations of bioactive compounds in food matrices as well as in the extracts are generally low in percent, so extra energies are required to improve the yield of the extraction process while minimizing the overall cost. From the technological approach, extraction process is mainly associated with the operating variables such as solvent used, extraction technique, operating temperature, concentration of solid in solvent, and extraction time, and by optimizing these parameters extraction yield could be enhanced (Milic et al., 2013; Orphanides, Goulas, & Gekas, 2014).

Physical Chemistry of Foods

    1.    Thermodynamics is primarily concerned with energy and entropy. Energy, also called internal energy (U), comprises heat and work; it is measured in joules (J).

    2.    Energy may be recalled that work generally equals force times distance (in N_·m = J) and that force equals mass times acceleration (in kg ·m· s^-2 = N).

    3.    According to the first law of thermodynamics, the quantity of energy, i.e., heat (q) work (p) potential energy, is always preserved.

    4.    Entropy (S)  is a measure of disorder; it is given by   
        S = K_B ln Ω
        Where K_B is the Boltzmann constant (1.38 ×10^-23 J × K^-1) and W is the number of  ways in which the system can be arranged, also called the number of degrees of freedom.

    5.    Colligative solution properties : The lowering of the chemical potential of a solvent by the presence of a solute causes changes in a number of physical properties: vapor pressure, boiling point, freezing point, osmotic pressure, etc. (the magnitudes of these changes all are proportional to the mole fraction of solute).

In the physical methods of preservation, fruits and vegetables are preserved by (i) adding heat, (ii) removing moisture content of produce to prevent spoilage and (iii) irradiated by Gama rays which kill the microorganisms responsible for spoilage of foods. These methods are described below.

Processing and Preservation by Adding Heat or Heating

In this method, heat treatment is given to destroy the microorganisms which are responsible for spoilage of the produce. Heat treatment is given by many methods.

Snack foods have become an essential part of the diet throughout the World and they are prepared from natural ingredients or components to yield products with specified functional properties. Extrusion cooking technology getting more popularity over other traditional processing technologies because extrusion shows continuous efficient cooking, mixing and forming process.

Physico-chemical and microbiological quality of meat and aquatic food and food products gives its overall safety and quality status as a food. The physico-chemical and microbiological qualities of raw material have great importance on the product development. It also affects the shelf life of the raw material as well as final product.

Fresh meat is a type of meat which has not been subjected to any processing whereas raw meat is a fresh meat which has undergone freezing. The qualities of fresh meat are important as far as merchandiser, purchaser and consumers are concerned and it is also important for adaptability in further processing. The important quality parameters of fresh meat are:

Abstract

Four bread wheat varieties (PBW-138, PBW-299, PBW-343 and PBW-373), two of durum wheat (PDW-215 and PDW-233) and two of triticale (TL-419 and TL-1210) were milled to obtain 70 percent extraction flour.  The grains and the flour samples of all the varieties were evaluated for proximate composition, rheological properties and pretzel making. Physical properties of durum wheat were better followed by bread wheat and triticale. Durum wheat were harder, had higher grain weight than bread wheat and triticale.  Protein, ash, fat, total sugars and enzyme activity were higher in triticale flour than bread and durum wheat flours while durum flour had higher pigments (ppm, b-carotene). Bread wheat flour was intermediate between durum and triticale flours with respect to fineness. Rheological studies revealed triticale flour to be the weakest flour. Pretzels prepared by using optimized recipe and method revealed PBW-343 and PBW-373 best for pretzel making.

The physio-chemical properties of ice cream strongly influence its processing behaviour, texture, stability, and consumer acceptance. This chapter examines ice cream as a complex multiphase system and discusses important properties including overrun, density, viscosity, freezing behaviour, hardness, scoopability, meltdown, and fat destabilization. It explains how formulation and processing conditions influence these properties and how they relate to sensory quality. The chapter also considers quality-control tests used in industrial ice cream plants and identifies defects associated with physio-chemical imbalance. Understanding these relationships enables manufacturers to establish suitable product targets, diagnose quality problems, optimize formulations, and maintain consistency across different ice cream products.

Fruits, the vivid and delightful offerings of the nature, undergo remarkable transformations as they travel from the orchard to our dining tables. These changes indicate the significance of post-harvest physiology, which is the scientific study that reveals the secrets of how fruits behave after they are picked, including the mechanisms that affect fruit quality and how long it may be stored. The next section provides definitions of the various stages and key players involved in the processes of fruit maturity, ripening, and post harvest physiology. These topics will be further explored in the subsequent sub-sections of this chapter.

Fruit developmental physiology

The life cycle of horticultural commodities (fruits and vegetables) can be effectively categorized into three primary physiological stages after fruit set or initiation, namely growth, maturation, and senescence. Still, a lack of obvious differentiation exists among the several stages. Growth encompasses the process of cell division followed by cell enlargement, which determines the ultimate size of the product. Maturation typically begins prior to the cessation of growth and involves various activities across different commodities. The stages of growth and maturity are commonly denoted as the developmental phase. Senescence can be described as the phase in which anabolic biochemical processes transition into catabolic processes, resulting in the ageing and eventual demise of the tissue. Ripening, a term specifically used for fruit, is typically regarded as the initial phase of senescence that occurs during the later phases of development. Defining the transition from growth to senescence is rather straightforward.

Physiological disorders refer to non-parasitic or inanimate disease of fruit crops, or it is the breakdown of tissue that is not caused by either invasion by pathogens or by mechanical damage. They may develop in response to an adverse environment, especially temperature or to a nutritional deficiency during growth and development. Physiological disorder is broadly classified into two broad categories. They are:

The production of fruit crops is largely dependent on the environmental conditions and nutritional status of the plants. Any alteration in the environmental conditions and nutritional status may results in different physiological disorders which affect the growth of the plants and also the quantity as well as quality of the fruits. The precise and early recognition of physiological disorders is important for the timely adaptation of remedial strategies to reduce the crop loss. Physiological disorders in fruits crops may be due to single factors or multiple factors may be involved in the appearance of physiological disorders. A sound knowledge about the cause of physiological disorder is useful to adopt suitable remedy for the disorder.

Introduction

The abnormal growth behavior or unusual external and/or internal conditions of fruits which results due to adverse environmental conditions and nutritional imbalances are considered as physiological disorders. Physiological disorder is best defined as external or internal malfunctioning resulting from improper environmental or cultural conditions before and/or after harvest. Variation from normal temperature, light, moisture, nutrient, harmful gases, insufficient supply of growth regulators, deficiencies or excesses of nutrient etc. are some of the important environmental and cultural factors of physiological disorders (Fig. 1). Physiological disorders affect the quality as well as quantity of the fruit crops. Detection of precise physiological disorders is not easy and requires a strong knowledge regarding them.

Pineapple, are well adapted crops for the farmers towards water economy due to its morphological, anatomical, and physiological characteristics. However, the plant contains rosette leaf structure can able to channels the light rainfalls and dew through stem and finally into the soil. It also have the ability to absorb water and nutrients through their waxy leaves and aerial roots and can capable to store water in specialized aquiferous leaf tissue; multicellular trichomes that cover the leaves and protect the plant from excessive transpiration by reflecting radiation; a thick cuticle covering the leaf epidermis that restricts water loss by evaporation, location of the stomata in furrows at the lower leaf surface where they also are covered by trichomes, limiting evapotranspiration; and its nocturnal carbon dioxide fixation via the crassulacean acid metabolism (CAM) carbon assimilation pathway, which results in stomatal opening primarily at night when evaporative demand is lowest (Reinhardt et al., 2018). The most common propagating material of pineapple is suckers or slips. Suckers are used to arise from the underground parts of the plant are used for propagation. Slips arise from the fruiting stem and the crown region on top of the fruit.

In this context, it is important to know the nutritional aspects of pineapples which are as attractive as their unique anatomy. “Pineapples contain high amounts of vitamin C and manganese,” said San Diego-based nutritionist Laura Flores. These tropical fruits are also important for the dietary fiber and bromelain (an enzyme). “As well as having high amounts of manganese, which is important for antioxidant defenses, pineapples also contain high amounts of thiamin, A, B vitamin that is involved in energy production,” Flores said. Pineapples are fat-free, cholesterol-free and low in sodium (Arpaia et al., 2004; De Costa, 2010). Side by side they contain sugars of about 14 grams per cup (www.livescience.com, 2019). In continuation with this, the chapter was focused on physiological disorder of pineapple caused by various reasons.

Basically, non-pathological conditions are the reasons of physiological disorders of any kind of crop plants; it includes poor light, adverse weather, water-logging, phytotoxic compounds or a lack of nutrients, which affects the normal functioning of the plant system. Sometimes physiological disorders may be initiated before harvest, continue their development after harvest, or appear after harvest. In was observed several times that physiological disorders are causative agent for the deterioration of horticultural commodities which leads to economic losses. An important commercialized fruit i.e., pineapple is also facing the same problem of different kind of physiological disorders; it includes multiple crowns, fruit and crown fasciation, collar of slips, dry fruit and bottle neck, sun-scald/ sunburn, blackheart etc.

Fruit ripening is a phenomena during which horticulture produce undergoes a series of complex physical and biochemical changes initiated through a series of hormones (Ethylene, auxin, abscisic acid (ABA), gibberellins, jasmonic acid, etc.) to attain maximum physiological maturity and favourable organoleptic properties. These changes lead to alterations in colour, texture, aroma, flavour and nutrient composition. In a nut shell, ripening involves increase in pulp to peel ratio, solubilisation of pectic substances, degradation of complex carbohydrates, organic acids and chlorophyll, accumulation sugars, flavour volatiles, polyphenolic compounds and pigments (carotenoids, xanthophylls and anthocynanins). The extent of these changes guide harvesting, readiness for processing and consumption decisions, with physic-chemical alterations serving as indicators of optimum ripeness. Respiration rate, ethylene and ABA are key regulators of fruit ripening in climacteric and non-climacteric fruits, respectively. In climacteric fruits, ABA interacts with ethylene, influencing the synthesis of ethylene itself. Although there is ample documentation on the involvement of hormones in fruit development and ripening, our understanding of the functions of various hormones throughout growth, maturation, and specific ripening processes remains incomplete.

Abstract

Upcoming era of functional foods has led food scientists and food processors to deeply understand the role of phytochemicals in promoting human health. Phytochemicals are the secondary metabolites produced by plants and are commonly found in our daily food. Natural food products seem to be good substitute for pharmaceutical supplements to improve health status of people. Therefore, consumer's interest is growing in the food items naturally containing phytochemicals, each having there own functional and health aspects. Most discussed phytochemicals in the present paper are carotenoids such as lycopene, beta-carotene, lutein and, polyphenols such as phenolic acids, flavonoids, anthocyanins and isoflavones. Major dietary source for carotenoids include orange and yellow fruits and vegetables as well as green leafy vegetables whereas polyphenols are found abundantly in green tea, wine, berries, cocoa, broccoli. Carotenoids can also be used as colorants in foods during processing. The role of polyphenols as an antioxidant is well characterized because of there ability to scavenge free radicals or bind pro-oxidant metal ions by means of their hydroxyl group. Carotenoids also play an important role in protection against photooxidative processes by acting as singlet molecular oxygen as well as peroxyl radical scavengers, thus acting as potent antioxidant. Apart from antioxidative properties multitude of health benefits are associated with carotenoids and polyphenols such as reduced risk of age-related macular degeneration, certain cancers such as prostate, lung and colon, prevention of cardiovascular disease and enhancing immunity towards infection. Hence, continuous developments are being made to combine phytochemicals to avoid improper combinations that may nullify the effect of supplements and cause lower absorbance.

11.1 Introduction

Phytosterols or plant sterols are bioactive plant constituents having similar chemical structure and biological functions as cholesterol (cholest-5-en-3b-ol), but differ in their side chain configuration. They are non-nutritive compounds with chemical structure differing from that of cholesterol only by minor modifications like in the structure of their side chain by a methyl or ethyl group at C-24. Sitosterol and campesterol have an ethyl and a methyl group at C-24, respectively (Fig. 11.1). Phytosterols present a tetracyclic ring and side chains linked to C-17 that differ according to sterol compound same as cholesterol, to which they resemble structurally as well as biosynthetically. Saturated form of sterols referred to as stands, occurring in small amounts, mainly in cereals are represented by the absence of the double bond at the D5 position. Phytosterols represent a part of the broad group of isoprenoides and are 28- and 29-carbon atom steroid alcohols naturally occurring in plants. Phytosterols and phytostanols are triterpene compounds, found ubiquitously in plants which can only be synthesized by plants, whereas humans and animals obtain them from their diet.

The preservation of food in common salt or in vinegar is known as pickling. It is one of the most ancient methods of preserving fruits and vegetables. Pickles are good appetizers and add to the palatability of a meal. They stimulate the flow of gastric juice and thus help in digestion. They are prepared with salt, vinegar, oil or with a mixture of salt, oil, spices and vinegar.

Pickles known to be good appetizers, aid digestion and pallate are edible products preserved and flavoured in a solution of common salt and vinegar. Spices and oil may also be added. There are a number of pickles very popular in India i.e. mango pickle, cauliflower pickle, lime and lemon pickles, ginger chilli pickle etc. But, some pickles like Sauerkraut are not very common in India but are very popular in European countries.

1. Introduction

At present there is an increasing demand for colourants from natural sources. Since there is a possibility of banning of synthetic colours in view of their carcinogenic properties and already a reduction in number of permitted synthetic colours from 13 to 8 numbers in our legislation (PFA, 2005), the demand for natural colours is evident. In Japan and European countries because of the green movement, the demand for synthetic colours has been reduced. Synthetic colours in global market account for 400 million dollars. Despite processing limitations and higher costs, the global market for natural colours is estimated to be more than 939 million dollars (Espszezola, 1998). Color is recognized as a major factor affecting food acceptance. The consumer expects a specific food to possess a well defined colour and rejects any appreciable deviation from the normal. The change in colour during the preparation of food is a useful guide to quality control and is used by many food processors as the criterion for selecting raw materials. The characteristic colour of raw food is due to the natural pigments present in the plant and animal material. These can be enhanced in processed food products through the addition of food colourants. Addition of colour can make up for the colour losses during processing. Some of the major groups of colours are anthocyanins, carotenoids, betalains, chlorophylls, flavones and chalcones. Some of the plant sources of pigments are kokum, roscelle, chilli, marigold, beetroot, grapes and safflower. Sources of natural colours can be plants, animals or microbes. Fruits and vegetables form one of the main plant sources of pigments. Some of the plant materials rich in colours viz., alfalfa, marigold, safflower, strawberry, aronia fruits, grapes, red cherries have been exploited for pigment extraction and the results have shown positive effects. Some of the interesting features of the work carried out by researchers in this area are presented in the following sections.

Before beginning the actual work on the establishment of a Fruit and Vegetable Processing Industry the following points should be considered:

Availability and possibilities of obtaining Funds: Investment of own money or obtaining loans from banks etc.

The scale of industry (Large, Small, Cottage or Home): Has to be decided based on availability of raw material, funds availability, land, labour and other resources.

The location: The processing unit should be located near to the actual production site of raw material so that the transportation costs of high bulk raw materials is reduced. There is no fun or justification of establishing apple processing industry in Lucknow or Bangalore and mango processing industry in Shimla as the related raw materials would have to be transported through long distances.

Site: Site selected in the location should be sunny area free from dampness and sufficient space for waste disposal should be ensured.