eChapters

We all are familiar with the word “quality”. If we bring some fruits or vegetables from the market, the other family members will reflect on their quality by making observations such as: fresh or stale, good or bad quality or inferior product, etc. These observations are perceptions of consumers based on the sensory attributes of the fruit or vegetable colour, appearance, touch, smell or taste.

The quality characteristics of food that are acceptable to consumers are comprehended under the term “Food Quality. It includes external factors such as appearance (size, shape, colour, gloss, and consistency); internal factors (chemical, physical, microbiological) and characteristics/ specifications prescribed under the Government laws/standards. If consumer’s perceptions regarding quality of food are not positive he or she either will not purchase the material or will be paying less compared to when the consumer has positive perception about the quality.

The relationship between quality, profitability and market share has been well established. In the quest of quality, the dairy business is passing through revolutionary changes and the need for such changes has been very well realized. The leaders have initiated the process of setting vision and are working hard to provide the basic infrastructure with necessary resources. This has become a point of vital importance as the nation has now captured the first rank in milk production globally and is now ready and set to march ahead in the global race for dairy products market. Our country has great potential to export the dairy products such as cheese particularly Mozzarella, Feta, and indigenous products such as ghee, khoa, chhana, paneer, and array of sweets. Food items or dairy products to be traded in the international markets should be manufactured in accordance with global accepted norms and standards. In order to improve the quality of milk and milk products the Government of India is focusing on “Clean Milk Production”. As a dairy technologists and entrepreneurs, we must ensure production of quality products.

4.1 Introduction

The purpose of processing the food is to make it safe and healthy for human consumption. The term food processing refers technologically anything, which transforms raw ingredients into consumer ready products, with the aim of stabilizing food products by preventing or reducing deteriorative changes in quality. The objective of food manufacturers is to develop, modify and employ those processing technologies that retain or create desirable sensory qualities in food and eliminate or reduce undesirable changes due to processing.

The purpose of food processing is to increase the shelf life of food before spoiling (preservation); to remove, destroy or inhibit pathogens and toxins (food safety); to change flavor, texture, aroma, color or form (variety); to reduce preparation times and make food more portable (convenience); to restore and/or raise nutrient levels in food (nutrition).The various food processing methods used extensively in food industry include physical (high temperature, freezing, chilling, dehydration, packaging), chemical (control of storage gases, reduction of water activity, pH, addition of chemical additives or spices) preservation methods.

Traditionally, food preservation has been associated with thermal treatments alone or in combination with biochemical or chemical methods. For example, the thermal processing of milk is done various thermal treatments viz. at 63^oC for 30 min for low temperature long time (LTLT), 72^oC for 15 seconds for high temperature short time (HTST) pasteurisations and up to 140^oC for a few seconds for ultra high temperature (UHT) treatment. However, such thermal treatments effectively reduce level of microorganisms but in long-term preservation, it may lead to losses of desired organoleptic attributes and destruction of temperature liable nutrients and vitamins. The limitations involved with thermal processing has been overcome by employing chemical preservation, cool chain management and process hygiene in the formulation and production of food products.

Milk may be concentrated as a necessary initial step in drying operation or as concentrating step in the manufacture of sweetened condensed milk or evaporated milk or the preparation of infant formulae. In order to preserve the milk constituents in a concentrated form, condensed milk/concentrated milk is manufactured from whole skim milk by removing or evaporating part of the water under vacuum. But this form of milk still has limited shelf life. Attempts to prolong the shelf life of this product have been made through the addition of bacterial growth inhibitor like sugar (sweetened condensed milk) or by heat processing (evaporated milk) to destroy the microorganisms.

Concentrated milk industry is an important segment of dairy industry. It plays an important role in the economy of industry. It serves as a balanced economy. It utilizes surplus milk in the flush season. It utilizes abundant milk production in certain localized area. It makes use of surplus milk below excellent grade. By either concentrating or drying less space is needed to store and it becomes less bulky and therefore it can be transported to any part of the world. The keeping quality of milk is increased. The concentrated products give considerable saving in the cost of packaging, storage and transportation. Milk concentrates can be easily reconstituted with required amount of water corresponding to that removed by evaporation to yield a product having normal consistency of milk. It is estimated that nearly two per cent of the world’s milk production is converted into different types of condensed or concentrated milks.

Brief history and developments: The present day concept of preservation of milk by concentration and by application of heat had the beginning with the pioneering work of French man Nicholas Appert around 1793. Gail Bordon of USA was first to commercially exploit the method of concentration of milk under vacuum. He was awarded U.S. Patent in the year 1856 for processing milk in a semi-fluid state after evaporating under vacuum. Commercial production of sweetened condensed milk by Gail Bordon started in 1856.

The method to preserve foods in sealed glass bottles by heat in boiling water was developed by one among the following scientist?

a) Edward Jenner (1798) b) Francois Nicolas Appert (1804)

c) Lazzaro spallanzani (1765) d) None of the above

10.1 Introduction

Edible oil production is a separate sector of the food processing industry. There are several species of plants in the world whose oil can be utilized for human consumption for edible and non-edible uses. Though around 40 oilseeds are known, only around a dozen oilseed crops have become commercially important including ten seed crops and three tree crops. These oil seed crops (mostly annual) of commercial importance are groundnut, rapeseed-mustard, sesame, soybean, sunflower, cottonseed, safflower, niger, castor and linseed. The three major tree oil crops are palm, olive and coconut [63]. Besides these, the kernels of some other tree crops i.e. apricot, almond, walnut, hazelnut, olive (fruits are used), peach, can also be utilized for oil extraction purposes for edible and non-edible uses. Besides oil of the oilseed crops, the oils of tree fruits and kernels are also becoming popular very fast for various food, pharmaceutical and cosmetic industries.

Large scale requirement and local shortages of oils for various edible and non-edible uses have prompted the identification of many new sources of oil during the last few decades. They are ricebran, corn, sal, mahua, jatropha, kokum, melia, rubber, mango kernel, kusum, simarouba, neem, karanj, crambe, moringa, tumba, jojoba and tobacco seed etc. Most of these oilseeds and their products have wide utility in the specialty oils sector and are mostly used for non-edible purposes. Soaps and detergents, paint and varnish, lubricants, pesticides and medicines, cosmetics, bio-diesel fuel industry are the major consumers of these non-traditional oilseeds. All the oil crops will gain greater attention in future as they are renewable and biodegradable in nature [63]. List of oil crops have been given in Table 1.

19.1 Introduction

Food safety is one of the important factor for food industry, regulatory agencies and consumers. Nowadays consumers are demanding food which is safe and of high quality in terms of nutrition due to a healthier life style. Food safety refers to all those hazards, that make food injurious to the health of the consumer and it is not negotiable. Food may be contaminated physically, chemically or microbiologically, mainly microbial contamination is of high concern in the food industries. Various pathogenic and spoilage causing microorganisms, viruses, insects can deteriorate the food products and cause food borne illnesses. Therefore, there is a need to eliminate these undesirable microorganisms from the food industries to ensure food safety to the consumer. Various methods are available to eliminate these undesirable microorganisms such as thermal technologies like pasteurization, dehydration, retort processing, freezing etc. and non thermal technologies like microwave heating, Pulsed Electric Field (PEF), High Pressure Processing (HPP), Pulsed Light Technology, Ohmic Heating, Ultra sonics, Pulsed X-Rays. But these technologies have certain disadvantages like thermal technologies lowers the nutritional value and leads to unwanted changes in the foods' sensory attributes of the food products whereas non thermal technologies retain better nutritional and sensory quality of food than thermal technologies but they are cost effective, required specialised equipments and trained personnel. Cold plasma technology (CPT) is a non-thermal green technology used now-a-days for variety of application in various industries especially in food industry. It is proposed to be an alternative method for eliminating microorganism from the fresh produce. This technology does not require extreme process conditions and can be used as a good alternative source for food preservation without affecting its nutritional and sensory attributes. Plasma is an ionized gas, consisting of active species like positively and negatively charged ions, electrons, free radicals, and gas atoms, metastable and quanta of electromagnetic radiation (photons). When the energy source is turned off, active species used to disappear immediately, therefore cold plasma technology is environmental friendly and fulfilling all ecological standards. Based on the properties of plasma, it can be applied in various fields like electronics, life sciences, textile, packaging and food industries. In food industries, it is showing promising application by retaining the nutritional, functional, and sensory characteristics thus ensuring the fresh appearance of the food product and satisfying the consumer need.

    1.    Cereals are grown over 73% of the total world harvested area and contribute over 60% of the world food production providing dietary fibre, proteins, energy, minerals,  vitamins, b-glucans , Oligosaccharides, such as lactulose, fructo-oligosaccharides, transgalacto-oligosaccharides

    2.    Finger millet is a potent source of antioxidants and has potent radical-scavenging activity that is higher than that of wheat, rice, and other millets; these results corresponded to their phenolic content

    3.    The brown or red variety of finger millet, which is commonly available, had higher activity (94%) than the white variety (4%) using the DPPH method.

    4.    Most of the herbal plant polyphenols are known to have multi functional properties such as reducing agents, hydrogen donating antioxidants and singlet oxygen quenchers and flavonoids and their derivatives are the largest and most important group of polyphenols.

    5.    Phytosterols are found in plant foods and are structurally and functionally analogous to cholesterol in vertebrate animals. a-sitosterol, campesterol and stigmasterol are the most commonly occurring phytosterols and constitute 95% of total phytosterols in the diet.

Introduction

Food grains have been the key component of the human diet for thousands of years and have played a vital role in framing human civilization. Rice, wheat, and maize, and to a lesser extent, coarse grains are major staples, crucial to the daily endurance of billions of people around the world. Cereal grains are consumed by more than 50% of world population to meet daily calorie requirements. Most grains undergo a milling process that ideally removes the outer bran (pericarp) and germ layers; catering to consumer market requirements. To a farmer, yield is the most prominent aspect. As the grain moves along the supply chain, and as the product reaches the market, quality becomes the key determinant of its sale-ability and economic value. Grain quality is defined by a range of physical and compositional properties where threshold necessities are set according to end consumer use requirements. Most industries and consumer markets have become habituated over the years to demand grain with specific attributes. Where consumers are close to the source of grain production (e.g. in local markets), their own preferences and the laws of supply and demand control the grain quality. However, where grain is traded over large distances, particularly internationally, consumers almost have no direct influence on quality, requiring regulatory standards to be established and imposed to protect consumer rights. Therefore in the grain supply chain, all points have effects with respect to grain quality.

INTRODUCTION

Radiation processing is a promising technology for improving hygiene and increasing storage and distribution life of food products. Ionizing radiation can be used to bring about beneficial changes in food stuffs (Urbain 1995) and it has been suggested as a method of ensuring safety of meat products (Patterson and Stevenson 1995). Ionizing radiation interacts with an irradiated material by transferring energy to electrons and ionizing molecules by creating positive and negativities (Moseley 1989).

Meat processing is the set of methods and techniques used to bring substantial chemical and physical changes in the natural state of meat. These are the methods which are used for making meat and their products attractive, nutritious and marketable as well as for the prolongation of shelf-life. In processing techniques, grinding, chopping, addition of seasoning, alteration techniques for colour, heat treatments etc. are included but cutting, trimming and deboning are not included in processing operations.

History

Meat processing dates back to the prehistoric ages and probably the first processed meat product was sundried meat. Lator it turns to burning of meat over wood fire while salting and smoking of meat was practiced first time in the time of Homer, 850 B.C. In 63B.C.-14 A.D. at the reign of Augustus honey was tried for preservation of meat. Lator various types of cooking such as roasting, smoking, steaming and oven baking came in existance. Salt-preservation was especially common for foods including meat and meat products for warrior and sailor’s diets, until the introduction of canning methods.

Modern food processing technology in the 19th and 20th century was largely developed to serve military needs. In 1809 Nicolus Appert invented a vacuum bottling technique that would supply food for French troops and this contributed to the development of tinning and then canning by Peter Durand in 1810. Although initially expensive and somewhat hazardous due to the lead used in cans. Canned goods would later become a staple around the world. Pasturization discovered by Louis Pasteur in 1862 was a significant advance in ensuring the micro-biological safety of food. In 20^th century, food processing advances with the development of spray drying, freeze drying and the introduction of artificial sweeteners, colouring agents and preservatives such as sodium benzoate. In late 20^th century ready to eat meat food products were introduced to cater the need of consumers.

Introduction

A biopolymer is defined as a polymeric substance obtained from any living organism (plant or animal) [1]. These polymers are organic compounds where simpler molecules are covalently bonded with each other [2]. Although biopolymers are strictly synthesized naturally by living cells but some of them are also synthesized from non-biomaterial as well. Natural biopolymers are of different types based on their chemical nature like carbohydrate based, protein based or lipid based. Biopolymers can be broken down by the action of naturally-occurring organisms which leaves organic non-harming by-products like water and carbon dioxide in the environment[3].

Bio polymers are gaining importance in the field of food packaging, medical application, commodity packaging etc. because of their have specific physical, chemical, biological, biomechanical and degradation properties. Wide ranges of natural or synthetic biopolymers capable of undergoing degradation hydrolytically or enzymatically are being investigated for many applications[1]. Bio polymers are mainly based on two properties: a) Biological origin b) Biodegradability.

Earlier natural biopolymers such as cellulose, protein, starch have been used extensively for food applications. Recently, synthetic biopolymers such as polylactic acid (PLA), polycaprolactone (PCL), polyglycolic acid (PGA), polyvinyl alcohol (PVOH), and polybutylene succinate (PBS) are gaining more attention[4] for various applications. Natural biopolymers are more stereospecific and mostly hydrophilic having complex 3D structures as compared to the synthetic polymers[2]. Among the synthetic biopolymers some are microbiologically degradable in the environment whereas some are recyclable[1].

1.    In milk and milk products, non bacterial ropiness or sliminess may be due to the stringiness/sliminess caused/resulted

(a) Due to thin film formation of proteins, when cooled

(b) From cream thickness

(c) By mastitis, fibrin and leucocytes from the milch animal’s blood

(d) All of the above

2.    In milk, bacterial ropiness is caused by slimy capsular material from the cells usually

(a) Lipids

(b) Proteins

(c) Gums or mucins

(d) Polysaccharides

1. Introduction

At present there is an increasing demand for colourants from natural sources. Since there is a possibility of banning of synthetic colours in view of their carcinogenic properties and already a reduction in number of permitted synthetic colours from 13 to 8 numbers in our legislation (PFA, 2005), the demand for natural colours is evident. In Japan and European countries because of the green movement, the demand for synthetic colours has been reduced. Synthetic colours in global market account for 400 million dollars. Despite processing limitations and higher costs, the global market for natural colours is estimated to be more than 939 million dollars (Espszezola, 1998). Color is recognized as a major factor affecting food acceptance. The consumer expects a specific food to possess a well defined colour and rejects any appreciable deviation from the normal. The change in colour during the preparation of food is a useful guide to quality control and is used by many food processors as the criterion for selecting raw materials. The characteristic colour of raw food is due to the natural pigments present in the plant and animal material. These can be enhanced in processed food products through the addition of food colourants. Addition of colour can make up for the colour losses during processing. Some of the major groups of colours are anthocyanins, carotenoids, betalains, chlorophylls, flavones and chalcones. Some of the plant sources of pigments are kokum, roscelle, chilli, marigold, beetroot, grapes and safflower. Sources of natural colours can be plants, animals or microbes. Fruits and vegetables form one of the main plant sources of pigments. Some of the plant materials rich in colours viz., alfalfa, marigold, safflower, strawberry, aronia fruits, grapes, red cherries have been exploited for pigment extraction and the results have shown positive effects. Some of the interesting features of the work carried out by researchers in this area are presented in the following sections.

1.    What is Surimi?
    
2.    Fisheries Resources for Surimi Production

    
3.    Historical Perspective of the Surimi Industry
    
4.    Present World Scenario of Surimi Industry

5.    Surimi Industry in India
    
6.    Processing Technology for Surimi from Light Muscle Fish 
    6.1     Types of fish used for surimi
    6.2     Heading, gutting, and deboning
    6.3     Mincing
    6.4     Washing and dewatering
    6.5     Stabilizing surimi with cryoprotectants
    6.6      Rapid freezing and packaging
    
7.    Surimi Processing from Dark Muscle Fish
    
8.    Quality Evaluation of Surimi
    
9.    Microbial Quality of Surimi
    
10.    Surimi based Products
    10.1     Fish cakes
    10.2     Fish balls
    10.3     Crab analogs (Crab leg meat analog)
    
11.    Scallop Analogs
    
12.    Moulded Products
    
13.    Important Considerations in Surimi and Surimi based Products
    13.1    Gelation
    
14.    Functional Properties of Surimi

15.    Cryoprotectants in Surimi
    15.1    Mechanism of action of cryoprotectants
    
16.    Future Development in Fish Protein Stabilization
    
References

Introduction

Eradication of malnutrition and hunger (Sustainable Development Goal, SDG-2) are the major challenges to humanity. Availability of sufficient nutritionally balanced food is the prerequisite for ensuring global food security. Food security is also critical for achievement of SDG 1 (poverty eradication) and SDG 3 (health and well-being) (UNDP, 2019). Changing climatic conditions accompanied by global warming not only acts a major threat for achievement of SDGs but could actually lead to the reversal of the progress already made. The escalating global temperature has jeopardized the food security throughout the world. A great decrease in the global crop yield has been suspected even with a 2°C rise in temperature. On field, it is often associated with crop nutrient loss, less accumulation of micronutrients and low availability of micro-minerals like iron and zinc. Additionally, the effect of the rainfall and temperature has also been observed. The global food prices are projected to increase by 3–84% by 2050 due to the fluctuations in rainfall and temperature (Hoegh-Guldberg et al., 2018).

Millets are the small seeded grains which belong to family Grassacae/Poaceae. Traditionally, millets are used for the food and feed purpose and are among the oldest cultivated crops. The millet species of commercial importance are proso (Panicum miliaceum), foxtail (Setaria italica), barnyard (Echinochloa esculenta), finger (Eleusine coracana), little (Panicum sumatrense) and pearl (Pennisetum glaucum) in different regions of the world. In India, foxtail millet (priyangava), barnyard millet (aanava) and black finger millet (shyaamaka) have been mentioned even in the Yajurveda texts of 4500 BC (Morya et al., 2017). The records of consumption of foxtail and proso millet are as old as 2000 to 1000 BC in China. Cultivation of foxtail millet in Korean peninsula is documented around 3,500–2,000 BC. Foxtail millet is the oldest of all the cultivated millets and is believed to be originated in Southern Asia. From there, it was spread to Europian nations. In the west, cultivation of millets majorly started after 1850 (ICRISAT, 2019)

1.1 Importance of Food Process Engineering

Food occupies the first position among the hierarchal needs of human beings. It is more important than shelter and clothing. After production and be forec on sumpti on, food commodities are subjected to nume rous unfavourable physical, chemical, microbial or parasitic factors which may cause their spoilage or disease when consumed. To prevent such spoilage, a process engineer has to understand these and provide remedial measures. The two primary goals of processing operation are first to minimize post harvest losses and second value addition of raw food commodities through preservation and processing.

Present level of production of different types of food commodities and their estimated post-harvest losses along with monetary values are given in Table 1.1. It shows that various food items get lost, to the tune of 65 million tonnes, worth Rs. 76,000 crores per annum, during post-harvest phase. A substantial amount of these losses could be prevented if appropriate agro processing centers, having backward linkage with farmers to ensure constant supply of quality raw food materials, are established and operated. Profit generated through value addition must also be shared with farmers, who are only people in the world to create wealth every year, in the form of food, fiber and other commodities necessary for human survival. It can bring sea change in rural areas, where 65-70% population live, in respect of economy, health and happiness.

It sounds simple, but the above process is fairly complex and requires lot of coordination in order to succeed. The major challenge is to minimize the losses during the various post harvest operations and keep the food as fresh as possible. In order to do so, one must first try to understand the various causes of post harvest losses of food commodities and the various factors that influence theses causes. Secondly, we must use those food processing operations that will not only extend the shelf life of the produce but also convert the raw food commodities to more acceptable product to the consumer.

3.1 Introduction

The subject of heat transfer is firmly grounded in the sciences of thermodynamics and fluid mechanics. It has become exceedingly important for engineers to possess a clear understanding of the principles of heat transfer and its application to a large number of problems. In view of process engineering, the knowledge of heat transfer and its application is most important, because heat transfer is one of the basic unit operations in the agricultural processing activities. The design of process equipments, refrigerators, boilers or type of heat exchangers, thermal treatment of food grains, cooling of perishables, pasteurizations, sterilizations, freezing of milk and fruit juices and a large number of similar applications involve consideration of heat transfer rates. There may be other situations where heat is being generated during a certain operation, and may be detrimental to the equipment and the food product. In such cases we are often faced with the task of removing the undesirable amount of heat as far as possible.

Membrane technology is a proven separation method used on the molecular and ionic levels. Since the beginning of the 1970s, this technique has been adopted by the dairy industry. Membrane separation is widely used in dairy processing plants to perform an ever-increasing range of duties, e.g. pre-concentration, partial demineralization, protein separation, bacteria removal, brine clarification and waste water recycling. Representing one of the great technological developments occurring within the dairy industry during the second half of the twentieth century, progress was driven initially by the transfer of know-how gleaned from the application of cellulose acetate-based reverse osmosis (RO) and ultrafiltration (UF) membranes in other industrial sectors to whey processing. Later, new membrane materials and engineering designs were built on this initial achievement and opened up further opportunities for the application of the full spectrum of membrane separation systems that also includes Nan filtration (NF) and cross-flow microfiltration The integration of these unit operations into traditional dairy processes has led to the development of innovative ingredients as well as improvements in yield, efficiency and product quality. R & D work indicates potential RO application for concentration of milk for products like khoa, condensed and dried milk products and of UF application for the manufacture of shrikhand, paneer, chana and cheese. Application of these processes permits higher energy saving, higher yields and superior product quality compared to traditional processes of thermal evaporation.

HISTORICAL DEVELOPMENTS

Food Preservation 1782 ó Canning of vinegar was introduced by a Swedish chemist.

1810 ó Preservation of food by canning was patented by Appert in France. ó Peter Durand was issued a British patent to preserve food in ìglass, pottery, tin or other metals or fit materials.î The patent was later acquired by Hall, Gamble, and Donkin, possibly from Appert.

Plant hormone ethylene is involved in a number of physiological activities within the plant system, ranging from seed germination to fruit development. Ethylene acts as a key player in accelerating fruit ripening by regulating the activities of different enzymes, and is responsible for shortening the shelf life and associated post-harvest losses during the storage of fruit crops. However, all fruit crops have different ethylene production capacities and vary in their response to ethylene. Hence, effective management of post-harvest ethylene is imperative for addressing the global challenge of reducing fruit losses after harvesting. In recent periods, numerous technologies and compounds have been developed for the suppression of ethylene and for enhancing in-situ oxidation of ethylene or inhibiting its production at a receptor level. Among these emerging techniques, the use of sachets, fumigating agents, catalysis and composite films embedded with nanoparticles has been found to be trending, but the use of some of compounds has been limited due to health risks or consumer unacceptance. However, most of these technologies are very costly and are not affordable for marginal farmers and developing nations. In order to address these issues, long term breeding approaches for shelf-life improvement, targeting the tfs, ERFs have been involved. This manuscript fills the knowledge gap by encompassing all the recent progress made in enhancing the shelf life of fruits by managing ethylene during storage.